Here, we report on the dual functionality of tungsten oxide for application as an efficient electron and hole injection/transport layer in organic light‐emitting diodes (OLEDs). We demonstrate hybrid polymer light‐emitting diodes (Hy‐PLEDs), based on a polyfluorene copolymer, by inserting a very thin layer of a partially reduced tungsten oxide, WO2.5, at the polymer/Al cathode interface to serve as an electron injection and transport layer. Significantly improved current densities, luminances, and luminous efficiencies were achieved, primarily as a result of improved electron injection at the interface with Al and transport to the lowest unoccupied molecular orbital (LUMO) of the polymer, with a corresponding lowering of the device driving voltage. Using a combination of optical absorption, ultraviolet spectoscopy, X‐ray photoelectron spectroscopy, and photovoltaic open circuit voltage measurements, we demonstrate that partial reduction of the WO3 to WO2.5 results in the appearance of new gap states just below the conduction band edge in the previously forbidden gap. The new gap states are proposed to act as a reservoir of donor electrons for enhanced injection and transport to the polymer LUMO and decrease the effective cathode workfunction. Moreover, when a thin tungsten oxide film in its fully oxidized state (WO3) is inserted at the ITO anode/polymer interface, further improvement in device characteristics was achieved. Since both fully oxidized and partially reduced tungsten oxide layers can be deposited in the same chamber with well controlled morphology, this work paves the way for the facile fabrication of efficient and stable Hy‐OLEDs with excellent reproducibility.

No abstract

No abstract

Human activities and climate change constitute the contemporary catalyst for natural processes and their impacts, i.e., geo-environmental hazards. Globally, natural catastrophic phenomena and hazards, such as drought, soil erosion, quantitative and qualitative degradation of groundwater, frost, flooding, sea level rise, etc., are intensified by anthropogenic factors. Thus, they present rapid increase in intensity, frequency of occurrence, spatial density, and significant spread of the areas of occurrence. The impact of these phenomena is devastating to human life and to global economies, private holdings, infrastructure, etc., while in a wider context it has a very negative effect on the social, environmental, and economic status of the affected region. Geospatial technologies including Geographic Information Systems, Remote Sensing—Earth Observation as well as related spatial data analysis tools, models, databases, contribute nowadays significantly in predicting, preventing, researching, addressing, rehabilitating, and managing these phenomena and their effects. This review attempts to mark the most devastating geo-hazards from the view of environmental monitoring, covering the state of the art in the use of geospatial technologies in that respect. It also defines the main challenge of this new era which is nothing more than the fictitious exploitation of the information produced by the environmental monitoring so that the necessary policies are taken in the direction of a sustainable future. The review highlights the potential and increasing added value of geographic information as a means to support environmental monitoring in the face of climate change. The growth in geographic information seems to be rapidly accelerated due to the technological and scientific developments that will continue with exponential progress in the years to come. Nonetheless, as it is also highlighted in this review continuous monitoring of the environment is subject to an interdisciplinary approach and contains an amount of actions that cover both the development of natural phenomena and their catastrophic effects mostly due to climate change.

Natural resources are gradually coming under continuous and increasing pressure due to anthropogenic interventions and climate variabilities. The result of these pressures is reflected in the sustainability of natural resources. Significant scientific efforts during the recent years focus on mitigating the effects of these pressures and on increasing the sustainability of natural resources. Hence, there is a need to develop specific indices and indicators that will reveal the areas having the highest risks. The Water and Land Resources Degradation Index (WLDI) was developed for this purpose. WLDI consists of eleven indicators and its outcome results from the spatiotemporal performance of these indicators. The WLDI is based on the Standardized Drought Vulnerability Index (SDVI) and the Environmentally Sensitive Areas Index (ESAI). The WLDI is applied for the period from October 1983 to September 1996, considering Greece as a study area. The results of the application of this index reveal the areas with the highest risks, especially in the agricultural sector, with less than the needed water quantities due to extensive periods of droughts. This index could be used by scientists, but also by policy makers, to better and more sustainably manage environmental pressures.

No abstract

No abstract

No abstract