The high quantum efficiency of light emission from GaInN/GaN quantum wells despite the typically large defect density still lacks a quantitative explanation. From a detailed analysis of the efficiency of highly efficient samples we find that a reduction of the radiative probability due to free exciton dissociation is the dominant mechanism limiting the quantum efficiency. Random exciton localization is shown to be only a minor contribution. (© 2004 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)
The size and number of utility-scale bifacial photovoltaic (PV) installations has proliferated in recent years but concerns over modeling accuracy remain. The aim of this work is to provide the PV community with a validation study of eight tools used to simulate bifacial PV performance. We simulate real 26 kilowatt-peak (kWp) bifacial arrays within a 420-kWp site located in northern Europe (55.6° N, 12.1° E). The substructures investigated include horizontal single-axis trackers (HSATs) and fixed tilt racks that have dimensions analogous to those found in utility-scale PV installations. Each bifacial system has a monofacial reference system with similar front side power. We use on-site solar radiation (global, diffuse, and beam) and albedo measurements from spectrally flat class A sensors as inputs to the simulation tools, and compare the modeled values to field measurements of string level power, rear and front plane of array irradiance, and module temperature. Our results show that state-of-the-art bifacial performance models add ~0.5% uncertainty to the PV modeling chain. For the site investigated, 2-D view factor fixed tilt simulations are within ±1% of the measured monthly bifacial gain. However, simulations of single-axis tracker systems are less accurate, wherein 2-D view factor and 3-D ray tracing are within approximately 2% and 1% of the measured bifacial gain, respectively.
Electroluminescence (EL) imaging is a PV module characterization technique, which provides high accuracy in detecting defects and faults such as cracks, broken cells interconnections, shunts, among many others; furthermore, the EL technique is used extensively due to a high level of detail and direct relationship to injected carrier density. However, this technique is commonly practiced only indoors-or outdoors from dusk to dawn-because the crystalline silicon luminescence signal is several orders of magnitude lower than sunlight. This limits the potential of such a powerful technique to be used in utility scale inspections, and therefore the interest in the development of electrical biasing tools to make outdoor EL imaging truly fast and efficient. With the focus of quickly acquiring EL images in daylight, we present in this article a drone-based system capable of acquiring EL images at a framerate of 120 frames per second. In a single second during high irradiance conditions, this system can capture enough EL and background image pairs to create an EL PV module image that has sufficient diagnostic information to identify faults associated with power loss. The final EL images shown in this work reached representative quality SNRAVG of 4.6, obtained with algorithms developed in previous works. These drone-based EL images were acquired with global horizontal solar irradiance close to one sun in the plane of the array.
Titanium and titanium alloys are currently being used for clinical biomedical applications due to their high strength, corrosion resistance and elastic modulus. The Ti-30Ta alloy has gotten extensive application as the important biomedical materials. The substrate surface of the Ti-30Ta alloy was altered either by chemical or topographical surface modification. The biocompatibility of an implant is closely related to its surface properties. Thus surface modification is one of effective methods for improving the biocompatibility of implants. The development status of biomedical materials has been summarized firstly, the biomedical application. In this study Ti-30Ta alloy surface was investigate as-casting (Group 1) modified with alkaline and heat-treatments in NaOH with 1.5M at 60°C for 24 hrs (Group 2), alkaline and heat-treatments with SBF-coatings by immersion in NaOH and SBFX5 for 24hrs (Group 3), anodization process was performed in an electrolyte solution containing HF (48%) and H2SO4 (98%) with the addition of 5% dimethyl sulfoxide (DMSO) 35V for 40 min (Group 4) and ion beam etching with 1200 eV ions with a beam current of 200 mA for a 3 hrs etch (Group 5). SEM was used to investigate the topography, EDS the chemical composition, and surface energy was evaluate with water contact angle measurement. SEM results show different structure on the surface for each group. EDS spectra identified similarity on Group 1, 4 and 5. The results indicate for group 2 an amorphous sodium tantalate hydrogel layer on the substrate surface and for group 3 the apatite nucleation on substrate surface. The Group 4 shows unorganized and vertically nanotubes and Group 5 shows a little alteration in the topography on the substrate surfaces. Overall the contact angle shows Group 5 the most hydrophobic and Group 4 the most hydrophilic. The study indicates Group 3 and 4 with potential for biomedical application. The next step the authors need to spend more time to study group 3 and 4 in the biomedical sciences.
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