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Five supersequences have been revealed by a regional sequence stratigraphic study conducted in the Albian (109 Ma) to Recent section of the Exmouth-Barrow passive margin. The interpretation utilises a new sequence stratigraphic model developed for mixed siliciclasticcarbonate lithofacies. A high degree of resolution is brought to the study by identification of 37 regional sequence boundaries controlled by biostratigraphic, wireline and seismic data. Ditch cutting analysis, integrated into the new chronostratigraphic framework, provided detailed lithofacies maps.The five supersequences, named the Gallic, Senonian, Palaeogene, Middle Neogene and Pliocene, are based upon regional lowstand, transgressive and highstand phases. The Gallic Supersequence (late Tithonian–latest Cenomanian) represents a marine incursion of siliciclastic sediments coincident with the rifting and accelerated movement of India away from Australia. A Senonian Supersequence (latest Cenomanian–middle Maastrichtian) truncates the previous supersequence with incised canyons developed on the outer shelf. The evolution of the Senonian section corresponds to the Australian separation from Antarctica and the first appearance of carbonates.The Palaeogene Supersequence (middle Maastrichtian– late Early Miocene) dominates much of the Tertiary and is identified by a basinward shift of facies following a Maastrichtian–Paleocene sea level fall. Enhanced subsidence on the outer shelf during the Eocene created a forced transgression with carbonate mudstonesiltstone deposition. A highstand during the Oligocene– Early Miocene formed the distinctive prograding carbonate shelf recognised throughout the North West Shelf.A Middle Neogene Supersequence (late Early Miocene– Early Pliocene) is identified by an erosive base and the development of a thin lowstand fan on the outer shelf. The supersequence is largely characterised by backstepping reefs following a Middle Miocene transgression. A Late Miocene eustatic stillstand restricted reef development to the inner shelf, generating coarsegrained carbonate progrades from highstand-shedding. The final Pliocene Supersequence (Pliocene–Recent) was initiated by a eustatic fall during the Early Pliocene and was followed by the development of a transgressive, aggrading shelf.

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A successful approach to basin analysis requires the broad-scale reconstruction of the three dimensional depositional systems in relation to concurrent structural development of the basin. The Gidgealpa-Merrimelia-lnnamincka (GMI) Trend is a prominent, asymmetric, mildly compressional anticlinal trend located in the Late Carboniferous to Triassic Cooper Basin. Its northwest flank is controlled by high angle thrust faults which were reactivated repeatedly throughout geological time. The present study addresses both the structural style and depositional character of the GMI Trend, focusing on selected areas. It is an integrated approach utilising wire-line logs, seismic interpretation, isopach and structural maps and detailed palynology. This approach has produced a detailed chronostratigraphic subdivision of the Permo-Triassic sequence, particularly the Patchawarra Formation, which points to evidence of synsedimentary tectonics. Evidence from crestal unconformities suggests that the GMI Trend was uplifted during at least four distinct structural episodes. These phases of uplift result from the rejuvenation of pre-Permian faults. Regional investigation of chronostratigraphic units incorporating palynological information, clearly demonstrates the palaeogeography and the presence of internal unconformities within the Patchawarra Formation. Subsurface distribution of hydrocarbon pools and improved definition of areas of prospectivity relate to the episodic uplifts. Although known hydrocarbon reserves have largely accumulated in structural traps, additional potential exploration targets in the Permian sequence exist in stratigraphic, combination, pinchout and downflank fault traps as well as onlap plays along the mid flank areas of the GMI Trend.

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The study of natural carbon dioxide (CO2) accumulations, such as those found in the onshore Otway Basin, is necessary for the validation of underground long-term storage technology as an option for decreasing greenhouse gas emissions.The investigation of natural CO2 occurrences is being investigated as part of the Geological Disposal of Carbon Dioxide (GEODISC) research program. This study identifies the effects of CO2 on reservoir rock’s mineralogy through time as well as its porosity and permeability. The Otway Basin CO2 accumulations display variations in reservoir type, CO2 concentration and time of injection. A range of typical reservoirs types for the CO2 accumulations occurs in the Otway Basin, including feldspathic litharenites, subfeldsarenite and quartz arenite. CO2 concentrations in the Otway Basin vary greatly in the accumulations studied, ranging from 10 mol% within the Port Campbell Field to 99 mol % in the Caroline Field. The source of the CO2 is degassing of the deep-seated magmas of the Newer Volcanics, with CO2 influx occurring between ~2 million to as recently as 5,000 years ago. This study investigated three areas of the Otway Basin;Penola Trough—Ladbroke Grove, Katnook (non-CO2)Port Campbell Embayment—Boggy Creek, Langley, Port Campbell; andGambier Sub-Basin—CarolineDue to their close proximity and similar geological history prior to CO2 influx, the Ladbroke Grove-Katnook gas accumulations are particularly useful for examining differences between a CO2-rich (Ladbroke Grove) and a CO2-absent field (Katnook) and for developing a post- CO2 diagenetic history. Variation in grain size and CO2 concentration affects the degree of reaction of CO2 with the reservoir rock. Petrology and formation water chemistry of these fields indicate that CO2 has modified the rock properties. In all CO2-rich reservoirs examined (>10 mol % CO2), dissolution and alteration of lithic and felsic framework grains has occurred (e.g. albite dissolution). Clays and cements throughout most of the Otway Basin CO2 accumulations are modified to minerals more stable in the changed gas compositions (e.g. chlorite to kaolin). The change in mineralogy after the recent CO2 influx shows that the Pretty Hill Formation with high amounts of reactive minerals and smaller grain size is an effective reservoir unit for mineral storage of CO2. Longterm storage in the Waarre Sandstone quartz-rich reservoirs also displays the effectiveness of CO2 storage in pore space.This study of natural accumulations of CO2 has demonstrated that geological storage of CO2 is a viable option. Understanding of the mineral reactions involved with CO2 in reservoir rock is vital for selection of storage sites and modelling the behaviour of CO2 in the subsurface.