We demonstrate the controlled incorporation of P dopant atoms in Si (001) presenting a new path toward the creation of atomic-scale electronic devices. We present a detailed study of the interaction of PH3 with Si (001) and show that it is possible to thermally incorporate P atoms into Si (001) below the H desorption temperature. Control over the precise spatial location at which P atoms are incorporated was achieved using STM H-lithography. We demonstrate the positioning of single P atoms in Si with ∼ 1 nm accuracy and the creation of nanometer wide lines of incorporated P atoms.PACS numbers: 03.67. Lx, 68.37.Ef, The ability to control the location of individual dopant atoms within a semiconductor has enormous potential for the creation of atomic-scale electronic devices, including recent proposals for quantum cellular automata [1], single electron transistors [2] and solid-state quantum computers [3]. Current techniques for controlling the spatial extent of dopant atoms in Si rely on either ion implantation techniques, or dopant diffusion through optical or electron-beam patterned mask layers. While the resolution of these techniques continues to improve they have inherent resolution limits as we approach the atomicscale [4]. The work presented here looks beyond conventional techniques to position P dopant atoms with atomic-precision by using scanning tunneling microscopy (STM) based lithography on H passivated Si (001) surfaces [5,6] to control the adsorption and subsequent incorporation of single P dopant atoms into the Si (001) surface.First, we show the controlled adsorption of PH 3 molecules to STM-patterned areas of H-terminated Si (001) surfaces. In these studies, we have used the H-terminated surface as a reference where the intrinsic surface periodicity can be observed to identify both adsorbed PH 3 molecules [7] and the previously unobserved room temperature dissociation product, PH 2 . We then show, using low PH 3 dosed clean Si (001) surfaces, that both of these room temperature adsorbates can be completely dissociated using a critical anneal, and more importantly, that this results in the substitutional incorporation of individual P atoms into the top layer of the substrate. Finally, we combine these two results to demonstrate the spatially controlled incorporation of individual P dopant atoms into the Si (001) surface with atomicscale precision. Of crucial importance to this final result is that the anneal temperature for P atom incorporation lies below the H-desorption temperature, so that the Hresist layer effectively blocks any surface diffusion of P atoms before their incorporation into the substrate surface.Figures 1(a) -1(c) demonstrate the flexibility of STM H-lithography to create different sized regions of bare Si (001) surface. As we will show, these regions can be used not only as a template for dopant incorporation but also to aid in fundamental studies of surface reactions. Figures 1(a) and 1(b) show the creation of both large areas (200 × 30 nm 2 ) and parallel, nanometer-wide lines...
Individual atoms and ions are now routinely manipulated using scanning tunnelling microscopes or electromagnetic traps for the creation and control of artificial quantum states. For applications such as quantum information processing, the ability to introduce multiple atomic-scale defects deterministically in a semiconductor is highly desirable. Here we use a scanning tunnelling microscope to fabricate interacting chains of dangling bond defects on the hydrogen-passivated silicon (001) surface. We image both the ground-state and the excited-state probability distributions of the resulting artificial molecular orbitals, using the scanning tunnelling microscope tip bias and tip-sample separation as gates to control which states contribute to the image. Our results demonstrate that atomically precise quantum states can be fabricated on silicon, and suggest a general model of quantum-state fabrication using other chemically passivated semiconductor surfaces where single-atom depassivation can be achieved using scanning tunnelling microscopy.
The quest to build a quantum computer has been inspired by the recognition of the formidable computational power such a device could offer. In particular silicon-based proposals, using the nuclear or electron spin of dopants as qubits, are attractive due to the long spin relaxation times involved, their scalability, and the ease of integration with existing silicon technology. Fabrication of such devices however requires atomic scale manipulation -an immense technological challenge. We demonstrate that it is possible to fabricate an atomically-precise linear array of single phosphorus bearing molecules on a silicon surface with the required dimensions for the fabrication of a siliconbased quantum computer. We also discuss strategies for the encapsulation of these phosphorus atoms by subsequent silicon crystal growth. (To appear in Phys. Rev. B Rapid Comm.) 03.67. Lx, 68.37.Ef, A quantum bit (or qubit) is a two level quantum system that is the building block of a quantum computer. To date the most advanced realisations of a quantum computer are qubit ion trap 1 and nuclear magnetic resonance 2-4 systems. However scaling these systems to large numbers of qubits will be difficult 5 , making solidstate architectures 6 , with their promise of scalability, important. In 1998 Kane proposed a novel solid state quantum computer design 7 using phosphorus 31 P nuclei (nuclear spin I = 1/2) as the qubits in isotopically-pure silicon 28 Si (I = 0). The device architecture is shown in Fig. 1a, with phosphorus qubits embedded in silicon approximately 20 nm apart. This separation allows the donor electron wavefunctions to overlap, whilst an insulating barrier isolates them from the surface control A and J gates. These A and J gates control the hyperfine interaction between the nuclear and electron spins and the coupling between adjacent donor electrons respectively. For a detailed description of the computer operation refer to Kane 7 . An alternative strategy using the electron spins of the phosphorus donors as qubits has also been proposed 8 .One of the major challenges of this design is to reliably fabricate an atomically-precise array of phosphorus nuclei in silicon -a feat that has yet to be achieved in a semiconductor system. Whilst a scanning tunnelling microscope (STM) tip has been used for atomic scale arrangement of metal atoms on metal surfaces 9 , rearrangement of individual atoms in a semiconductor system is not straightforward due to the strong covalent bonds involved. As a result, we have employed a hydrogen resist strategy outlined in Fig. 1b. Here the array is fabricated using a resist technology, much like in conventional lithography, where the resist is a layer of hydrogen atoms that terminate the silicon surface. An STM tip is used to selectively desorb individual hydrogen atoms, exposing the underlying silicon surface in the required array. STM induced hydrogen desorption has been developed and refined over the past ten years 10 and has been proposed 11 for the assembly of atomically-ordered device structure...
The incorporation of phosphorus in silicon is studied by analyzing phosphorus δ-doped layers using a combination of scanning tunneling microscopy, secondary ion mass spectrometry and Hall effect measurements. The samples are prepared by phosphine saturation dosing of a Si(100) surface at room temperature, a critical annealing step to incorporate phosphorus atoms, and subsequent epitaxial silicon overgrowth. We observe minimal dopant segregation (~5 nm), complete electrical activation at a silicon growth temperature of 250 °C and a high two-dimensional electron mobility of ~10 2 cm 2 /Vs at a temperature of 4.2 K. These results, along with preliminary studies aimed at further minimizing dopant diffusion, bode well for the fabrication of atomically precise dopant arrays in silicon such as those found in recent solid-state quantum computer architectures. From Moore's Law it is well-known that the number of transistors on a chip doubles approximately every 18 months.1 In order to maintain this trend alternative means of fabricating devices are actively being pursued 2 and it is clear that the ability to fabricate atomically precise structures in silicon is becoming increasingly important. It is also important to characterize the spatial and electrical distribution of the dopant atoms. This is especially the case for a number of proposals to fabricate atomically precise dopant arrays in silicon for the fabrication of silicon based quantum computers. [3][4][5] In these architectures the dopant atom is required to be electrically active. The free electron of each dopant can then either act directly as the quantum bit 5 or mediate the coupling between quantum bits. 3,4Recent results have demonstrated that a precise array of phosphorus bearing molecules can be fabricated on a silicon surface using a hydrogen resist based strategy. 6 The next important step for creating ordered dopant arrays in silicon devices, which has not yet been demonstrated, is to encapsulate the dopants in high quality epitaxial silicon without disturbing the array. This step must aim at choosing an optimal substrate temperature to minimize dopant diffusion and surface segregation during growth, while maintaining a high structural quality of the epitaxial layer.While numerous publications exist on B and Sb δ-doping in Si, 7,8 P δ-doping has been applied only recently to the fabrication of SiGe tunneling diodes.9,10 These devices are of great interest for digital and high frequency applications due to their negative differential resistance. However, high peak to valley current ratios of about 5 have to be achieved for realistic applications, which requires minimal diffusion of the dopants in the device.9 This has only recently been demonstrated in the fabrication of SiGe tunneling diodes, where P δ-doped layers are fabricated with a GaP solid dopant source. 9,10 This Letter describes recent progress in the low temperature encapsulation of phosphorus dopants in silicon and represents one of the first demonstrations of P δ-doping using phosphine gas a...
We present a complete fabrication process for the creation of robust nano-and atomic-scale devices in silicon using a scanning tunneling microscope (STM). In particular we develop registration markers which, in combination with a custom-designed STM-scanning electron microscope (SEM) system, solve one of the key fabrication problems − connecting the STM-patterned buried phosphorus-doped devices, fabricated in the ultrahigh vacuum environment, to the outside world. The first devices demonstrate the feasibility of this technology and confirm the presence of quantum confinement in devices as electron propagation is laterally constricted by STM patterning.
Density functional calculations are performed to identify features observed in STM experiments after phosphine (PH3) dosing of the Si(001) surface. On the basis of a comprehensive survey of possible structures, energetics, and simulated STM images, three prominent STM features are assigned to structures containing surface bound PH2, PH, and P, respectively. Collectively, the assigned features outline for the first time a detailed mechanism of PH3 dissociation and P incorporation on Si(001).
Using density functional theory and guided by extensive scanning tunneling microscopy (STM) image data, we formulate a detailed mechanism for the dissociation of phosphine (PH3) molecules on the Si(001) surface at room temperature. We distinguish between a main sequence of dissociation that involves PH2+H, PH+2H, and P+3H as observable intermediates, and a secondary sequence that gives rise to PH+H, P+2H, and isolated phosphorus adatoms. The latter sequence arises because PH2 fragments are surprisingly mobile on Si(001) and can diffuse away from the third hydrogen atom that makes up the PH3 stoichiometry. Our calculated activation energies describe the competition between diffusion and dissociation pathways and hence provide a comprehensive model for the numerous adsorbate species observed in STM experiments.
We report a comprehensive ab initio survey of possible dissociation intermediates of phosphine ͑PH 3 ͒ on the Si͑001͒ surface. We assign three scanning tunneling microscopy ͑STM͒ features, commonly observed in room-temperature dosing experiments, to PH 2 + H, PH+ 2H, and P + 3H species, respectively, on the basis of calculated energetics and STM simulation. These assignments and a time series of STM images which shows these three STM features converting into another, allow us to outline a mechanism for the complete dissociation of phosphine on the Si͑001͒ surface. This mechanism closes an important gap in the understanding of the doping process of semiconductor devices.
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