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ABSTRACT:We prepared poly(ethylene glycol dimethacrylate-1-vinyl-1,2,4-triazole) [poly(EGDMA-VTAZ)] beads (average diameter ¼ 150-200 mm) by copolymerizing ethylene glycol dimethacrylate (EGDMA) with 1-vinyl-1,2,4-triazole (VTAZ). The copolymer composition was characterized by elemental analysis and found to contain five EGDMA monomer units for each VTAZ monomer unit. The poly(EGDMA-VTAZ) beads had a specific surface area of 65.8 m 2 /g. Poly(EGDMA-VTAZ) beads were characterized by Fourier transform infrared spectroscopy, elemental analysis, surface area measurements, swelling studies, and scanning electron microscopy. Poly(EGDMA-VTAZ) beads with a swelling ratio of 84% were used for the heavy-metal removal studies. The adsorption capacities of the beads for Cd(II), Hg(II), and Pb(II) were investigated in aqueous media containing different amounts of these ions (5-750 mg/L) and at different pH values (3.0-7.0). The maximum adsorption capacities of the poly(EGDMA-VTAZ) beads were 85.7 mg/g (0.76 mmol/g) for Cd(II), 134.9 mg/g (0.65 mmol/g) for Pb(II), and 186.5 mg/g (0.93 mmol/g) for Hg(II). The affinity order toward triazole groups on a molar basis was observed as follows: Hg(II) > Cd(II) > Pb(II). pH significantly affected the adsorption capacity of the VTAZ-incorporated beads. The equilibrium data were well fitted to the Redlich-Peterson isotherm. Consideration of the kinetic data suggested that chemisorption processes could have been the rate-limiting step in the adsorption process. Regeneration of the chelatingbeads was easily performed with 0.1M HNO 3 .

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The aim of this study was to prepare magnetic beads that could be used for the removal of heavymetal ions from synthetic solutions. . The magnetic beads could be regenerated (up to ca. 97%) by a treatment with 0.1M HNO 3 . These features make mpoly(EGDMA-VTAZ) beads potential supports for heavymetal removal under a magnetic field.

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