Natural gas use in electricity generation in Texas was estimated, for gas prices ranging from $1.89 to $7.74 per MMBTU, using an optimal power flow model. Hourly estimates of electricity generation, for individual electricity generation units, from the model were used to estimate spatially resolved hourly emissions from electricity generation. Emissions from natural gas production activities in the Barnett Shale region were also estimated, with emissions scaled up or down to match demand in electricity generation as natural gas prices changed. As natural gas use increased, emissions decreased from electricity generation and increased from natural gas production. Overall, NOx and SO2 emissions decreased, while VOC emissions increased as natural gas use increased. To assess the effects of these changes in emissions on ozone and particulate matter concentrations, spatially and temporally resolved emissions were used in a month-long photochemical modeling episode. Over the month-long photochemical modeling episode, decreases in natural gas prices typical of those experienced from 2006 to 2012 led to net regional decreases in ozone (0.2-0.7 ppb) and fine particulate matter (PM) (0.1-0.7 μg/m(3)). Changes in PM were predominantly due to changes in regional PM sulfate formation. Changes in regional PM and ozone formation are primarily due to decreases in emissions from electricity generation. Increases in emissions from increased natural gas production were offset by decreasing emissions from electricity generation for all the scenarios considered.
The feasibility, cost, and air quality impacts of using electrical grids to shift water use from drought-stricken regions to areas with more water availability were examined. Power plant cooling represents a large portion of freshwater withdrawals in the United States, and shifting where electricity generation occurs can allow the grid to act as a virtual water pipeline, increasing water availability in regions with drought by reducing water consumption and withdrawals for power generation. During a 2006 drought, shifting electricity generation out of the most impacted areas of South Texas (∼10% of base case generation) to other parts of the grid would have been feasible using transmission and power generation available at the time, and some areas would experience changes in air quality. Although expensive, drought-based electricity dispatch is a potential parallel strategy that can be faster to implement than other infrastructure changes, such as air cooling or water pipelines.
The world is experiencing an energy crisis and environmental issues due to the depletion of fossil fuels and the continuous increase in carbon dioxide concentrations. Microalgal biofuels are produced using sunlight, water, and simple salt minerals. Their high growth rate, photosynthesis, and carbon dioxide sequestration capacity make them one of the most important biorefinery platforms. Furthermore, microalgae's ability to alter their metabolism in response to environmental stresses to produce relatively high levels of high-value compounds makes them a promising alternative to fossil fuels. As a result, microalgae can significantly contribute to long-term solutions to critical global issues such as the energy crisis and climate change. The environmental benefits of algal biofuel have been demonstrated by significant reductions in carbon dioxide, nitrogen oxide, and sulfur oxide emissions. Microalgae-derived biomass has the potential to generate a wide range of commercially important high-value compounds, novel materials, and feedstock for a variety of industries, including cosmetics, food, and feed. This review evaluates the potential of using microalgal biomass to produce a variety of bioenergy carriers, including biodiesel from stored lipids, alcohols from reserved carbohydrate fermentation, and hydrogen, syngas, methane, biochar and bio-oils via anaerobic digestion, pyrolysis, and gasification. Furthermore, the potential use of microalgal biomass in carbon sequestration routes as an atmospheric carbon removal approach is being evaluated. The cost of algal biofuel production is primarily determined by culturing (77%), harvesting (12%), and lipid extraction (7.9%). As a result, the choice of microalgal species and cultivation mode (autotrophic, heterotrophic, and mixotrophic) are important factors in controlling biomass and bioenergy production, as well as fuel properties. The simultaneous production of microalgal biomass in agricultural, municipal, or industrial wastewater is a low-cost option that could significantly reduce economic and environmental costs while also providing a valuable remediation service. Microalgae have also been proposed as a viable candidate for carbon dioxide capture from the atmosphere or an industrial point source. Microalgae can sequester 1.3 kg of carbon dioxide to produce 1 kg of biomass. Using potent microalgal strains in efficient design bioreactors for carbon dioxide sequestration is thus a challenge. Microalgae can theoretically use up to 9% of light energy to capture and convert 513 tons of carbon dioxide into 280 tons of dry biomass per hectare per year in open and closed cultures. Using an integrated microalgal bio-refinery to recover high-value-added products could reduce waste and create efficient biomass processing into bioenergy. To design an efficient atmospheric carbon removal system, algal biomass cultivation should be coupled with thermochemical technologies, such as pyrolysis.
Solid wastes from domestic, industrial and agricultural sectors cause acute economic and environmental problems. These issues can be partly solved by anaerobic digestion of wastes, yet this process is incomplete and generates abundant byproducts as digestate. Therefore, cultivating mixotrophic algae on anaerobic digestate appears as a promising solution for nutrient recovery, pollutant removal and biofuel production. Here we review mixotrophic algal cultivation on anaerobic waste digestate with focus on digestate types and characterization, issues of recycling digestate in agriculture, removal of contaminants, and production of biofuels such as biogas, bioethanol, biodiesel and dihydrogen. We also discuss applications in cosmetics and economical aspects. Mixotrophic algal cultivation completely removes ammonium, phosphorus, 17β-estradiol from diluted digestate, and removes 62% of zinc, 84% of manganese, 74% of cadmium and 99% of copper.
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