Negative thermal expansion (NTE) behaviors have been observed in various types of compounds. The achievement in the merits of promising low-cost and facile NTE oxides remains challenging. In the present work, a simple and low-cost Cu 2 P 2 O 7 has been found to exhibit the strongest NTE among the oxides (α V ∼ −27.69 × 10 −6 K −1 , 5−375 K). The complex NTE mechanism has been investigated by the combined methods of high-resolution synchrotron X-ray diffraction, neutron powder diffraction, X-ray pair distribution function, extended X-ray absorption fine structure spectroscopy, and density functional theory calculations. Interesting, the direct experimental evidence reveals that the coupling twist and rotation of PO 4 and CuO 5 polyhedra are the inherent factors for the NTE nature of Cu 2 P 2 O 7 , which is triggered by the transverse vibrations of oxygen atoms. The present new NTE material of Cu 2 P 2 O 7 also has been verified for the practical application.
The understanding of the negative thermal expansion (NTE) mechanism is vital not only for the development of new NTE compounds but also for effectively controlling thermal expansion. Here, we report an interesting isotropic NTE property in cubic GaFe(CN) Prussian blue analogues (α = -3.95 × 10 K, 100-475 K), which is a new example to understand the complex NTE mechanism. A combined study of synchrotron X-ray diffraction, X-ray total scattering, X-ray absorption fine structure, neutron powder diffraction, and density functional theory calculations shows that the NTE of GaFe(CN) originates from the low-frequency phonons (< ∼100 cm), which are directly related to the transverse vibrations of the atomic -Ga-N≡C-Fe- chains. Both the Ga-N and Fe-C chemical bonds are much softer to bend than to stretch. The direct evidence that transverse vibrational contribution to the NTE of GaFe(CN) is dominated by N, instead of C atoms, is illustrated. It is interesting to find that the polyhedra of GaFe(CN) are not rigid, which is a starting assumption in some models describing the NTE properties of other systems. The NTE mechanism can be vividly described by the "guitar-string" effect, which would be the common feature for the NTE property of many open-framework functional materials, such as Prussian blue analogues, oxides, cyanides, metal-organic frameworks, and zeolites.
The achievement of controlling thermal expansion is important for open-framework structures. The present work proposes a feasible way to adjust the coefficient of thermal expansion continuously from negative to positive via inserting guest Na + ions or H 2 O molecules into a GaFe(CN) 6 framework. The guest ions or molecules have an intense dampening effect on the transverse vibrations of CN atoms in the −Ga−NC− Fe− linkage, especially for the N atoms. This study demonstrates that electrochemical or redox intercalation of guest ions will be an effective way to tune thermal expansion in those negative thermal expansion openframework materials induced by low-frequency phonons.
A new isotropic negative thermal expansion compound of FeFe(CN)6 has been found, in which the transverse vibrations of N atoms dominate in its NTE behavior.
Negative or zero thermal expansion (NTE, ZTE) of materials is intriguing for the controllable thermal expansion. We report a series of orthorhombic α-Cu2-xZnxV2O7 (x = 0, 0.1, 0.2), in which...
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