Perfluorooctanoic
acid (PFOA) persists in the environment for a
long time due to its stable physical and chemical properties, and
it is harmful to the environment and biological system. In order to
effectively remove PFOA from aqueous solution, Cu nanoparticles and
fluorine-modified graphene aerogel (Cu/F-rGA) were fabricated by the
microbubble template method. Compared with unmodified aerogels (rGA),
the adsorption rate of PFOA on Cu/F-rGA was enhanced 2.68-fold. These
significant improvements were assumed to benefit from the ligand exchange
reaction and hydrophobic and F–F interactions. The regeneration
of Cu/F-rGA maintained 73.26% with ethanol as the desorption solvent
after 10 times adsorption–desorption. The fitting results of
the statistical physics model showed that PFOA tended to be parallel
to the adsorption site at low temperature and perpendicular at high
temperature. The number of PFOA molecules connected to each adsorption
site was 0.53 to 1.41, and the number of adsorption layers of PFOA
on the Cu/F-rGA was between 1.63 and 2.51. Compared with the response
surface methodology and artificial neural network, an adaptive neuro-fuzzy
inference system had more accurate analysis and prediction results.
These results provide an effective and alternative strategy to remove
PFOA from aqueous solution with environment-friendly consumption.
Graphene-based composite aerogel doped with other low-cost materials can reduce the cost and promote the use in water treatment. This work prepared ball-milled biochar/reduced graphene oxide aerogel (BC/rGA) using GO and low-cost ball-milled biochar (BC) in a certain proportion with the freeze-thawing technique and sol–gel method, and applied BC/rGA on the Cr(VI) removal from aquatic environments. The characterization results showed that aerogel had a honeycomb briquette three-dimension (3D) and mesoporous structure with interconnected pores, and proved the preparation progress of aerogel in principle. Compared with GO, rGA and BC/rGA had better adsorption performance with 3D structure and well-developed pores, and BC/rGA with the mixture ratio of BC and GO of 1:4 was more appropriate. The adsorption kinetics data of rGA and BC/rGA(1:4) were fitting well with the pseudo-second-order model (R2 > 0.951), and the isotherm adsorption results were fitting the Langmuir model well (R2 > 0.974). The results demonstrated that the adsorption process was monolayer and endothermic adsorption involving chemisorption. Additionally, the adsorption capacities of rGA and BC/rGA(1:4) at solution pH 2 were 3.71 and 3.89 times greater than those at solution pH 8, respectively. High background ion strength and low temperature slightly inhibited the adsorption of Cr(VI) by both rGA and BC/rGA(1:4). The adsorption mechanisms of Cr(VI) on rGA and BC/rGA(1:4) were electrostatic interaction, reduction and ion exchange. The use of BC/rGA could reduce the cost and promote the green reuse of agricultural waste. Overall, BC/rGA could be used as a promising green adsorbent alternative for the feasible treatment of heavy metal contaminated water.
Graphical Abstract
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