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We successfully demonstrated the performance of novel, one-dimensional electrospun nanofibers as cathode, anode and separator-cum-electrolyte in full-cell Li-ion configuration. The cathode, LiMn2O4 delivered excellent cycle life over 800 cycles at current density of 150 mA g(-1) with capacity retention of ~93% in half-cell assembly (Li/LiMn2O4). Under the same current rate, the anode, anatase phase TiO2, rendered ~77% initial reversible capacity after 500 cycles in half-cell configuration (Li/TiO2). Gelled electrospun PVdF-HFP exhibits liquid-like conductivity of ~3.2 mS cm(-1) at ambient temperature conditions (30 °C). For the first time, a full-cell is fabricated with enitrely electrospun one-dimensional materials by adjusting the mass loading of cathode with respect to anode in the presence of gelled PVdF-HFP membrane as a separator-cum-electrolyte. Full-cell LiMn2O4|gelled PVdF-HFP|TiO2 delivered good capacity characteristics and excellent cyclability with an operating potential of ∼2.2 V at a current density of 150 mA g(-1). Under harsh conditions (16 C rate), the full-cell showed a very stable capacity behavior with good calendar life. This clearly showed that electrospinning is an efficient technique for producing high performance electro-active materials to fabricate a high performance Li-ion assembly for commercialization without compromising the eco-friendliness and raw material cost.

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Review of the research progress in α-Fe2O3/carbon nanocomposites with superior electrochemical performance as promising alternatives to graphite anodes in LIBs.

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