The 211~212 transition of acetaldehyde at 3195·167 MHz has been observed in emission in SgrB2 with the Parkes 64 m telescope. Comparison of the intensities of the llO~ 111 and 211 ~212 emission lines suggests that both transitions may be inverted.
The 211 +-212 transition of thioformaldehyde (HCHS) has been observed in absorption in the direction of SagittariusB2. For a rest frequency of 3139· 38 MHz the peak absorption occurs at a radial velocity of 60 ± 4 km s -1. The half-width of the absorption profile is equivalent to 20 kms-1 and the column density of HCHS is greater than 10 16 molecules cm -2. Comparison with the 211 +-212 absorption of formaldehyde (HCHO) at 15 GHz allows the relative abundance of the two molecular species to be computed as a function of the rotational excitation temperature. For thermal equilibrium the strength of the 110-111 absorption in SgrB2 by thioformaldehyde predicted from the 211+-212 HCHS observations is considerably greater than the limits set by a number of observers for the 110-111 transition at 1046 MHz.
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