¦ van der Waals gap Septuple layer J § J || T 1/2 J 0,1 || J 0,2 || J 0,3 || J 0,4 ||

Feasibility of many emergent phenomena that intrinsic magnetic topological insulators (TIs) may host depends crucially on our ability to engineer and efficiently tune their electronic and magnetic structures. Here we report on a large family of intrinsic magnetic TIs in the homologous series of the van der Waals compounds (MnBi2Te4)(Bi2Te3)m with m = 0, ⋯, 6. Magnetic, electronic and, consequently, topological properties of these materials depend strongly on the m value and are thus highly tunable. The antiferromagnetic (AFM) coupling between the neighboring Mn layers strongly weakens on moving from MnBi2Te4 (m = 0) to MnBi4Te7 (m = 1) and MnBi6Te10 (m = 2). Further increase in m leads to change of the overall magnetic behavior to ferromagnetic (FM) one for (m = 3), while the interlayer coupling almost disappears. In this way, the AFM and FM TI states are, respectively, realized in the m = 0, 1, 2 and m = 3 cases. For large m numbers a hitherto-unknown topologically nontrivial phase can be created, in which below the corresponding critical temperature the magnetizations of the non-interacting 2D ferromagnets, formed by the MnBi2Te4 building blocks, are disordered along the third direction. The variety of intrinsic magnetic TI phases in (MnBi2Te4)(Bi2Te3)m allows efficient engineering of functional van der Waals heterostructures for topological quantum computation, as well as antiferromagnetic and 2D spintronics.

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The South Caspian Basin is believed to contain more than 20 km of Mesozoic and Tertiary sediments deposited on oceanic or thinned continental crust. Mesozoic, Palaeogene and Oligo-Miocene sediments have not been penetrated within the South Caspian Basin itself but are exposed onshore in the basin margins. The Pliocene–Recent sequence has been mapped on a regionally extensive grid of two-dimensional (2D) seismic data and penetrated by recently drilled exploration wells, and is over 7 km thick. Most of this sequence (6 km) is formed of fluvial–lacustrine deltaic sediments of the Pliocene Productive Series that are deposited unconformably above a marine Miocene shale sequence and form the principal hydrocarbon reservoirs in the basin. The Productive Series is overlain by about 1 km of Late Pliocene–Recent marine sedimentsThe thickness of the Pliocene sedimentary sequence implies that relatively rapid, late Tertiary subsidence occurred in the South Caspian Basin; however, there is no geological evidence of a tectonic event capable of generating a major thermal subsidence event at this time. Modelling presented in this paper suggests that it is possible to account for the observed pattern of subsidence and sedimentation in the South Caspian Basin by a process of sediment loading and compaction on a thermally subsiding, late Mesozoic crust without the need for additional Tertiary subsidence mechanisms. Crucially, this model interprets the Pliocene Productive Series to have been deposited in a topographic depression, isolated from the global oceanic system, in which base level was controlled by local factors rather than by global sea level.

We study the surface crystalline and electronic structures of the antiferromagnetic topological insulator MnBi2Te4 using scanning tunneling microscopy/spectroscopy (STM/S), micro(μ)-laser angle-resolved photoemission spectroscopy (ARPES), and density functional theory calculations. Our STM images reveal native point defects at the surface that we identify as BiTe antisites and MnBi substitutions. Bulk X-ray diffraction further evidences the presence of the Mn-Bi intermixing. Overall, our characterizations suggest that the defects concentration is nonuniform within crystals and differs from sample to sample. Consistently, the ARPES and STS experiments reveal that the Dirac point gap of the topological surface state is different for different samples and sample cleavages, respectively. Our calculations show that the antiparallel alignment of the MnBi moments with respect to those of the Mn layer can indeed cause a strong reduction of the Dirac point gap size. The present study provides important insights into a highly debated issue of the MnBi2Te4 Dirac point gap.

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This study summarizes the subsidence history and aspects of the geodynamic evolution of the South Caspian Basin based on the integration of geophysical observations, and subsidence and gravity modelling on selected two-dimensional (2D) profiles. This analysis implies the presence of an attenuated ‘oceanic-type’ crust in the northern portion of the South Caspian Basin, demonstrates characteristics of basin subsidence on variable crustal types and describes sediment-fill evolution in several different parts of the basin. Modelling conducted in this study shows that the observed pattern of subsidence and sedimentation in the South Caspian Basin can be explained by a process of thermal subsidence following Jurassic rifting and further enhanced subsidence that resulted from sediment-induced loading in the Late Tertiary, especially after a large-scale base-level fall after 6 Ma.Variation in crustal type is reflected in differences observed in the degree of subsidence and sediment fill in the overlying stratigraphy. The western part of the South Caspian Basin has subsided differently to the eastern part because of this difference in crustal type. This is also confirmed by gravity modelling, which shows that the South Caspian Basin crustal density is compatible with an oceanic composition in the western part of the South Caspian Basin: the crust in the eastern part of the basin, however, is thicker.

The Oligocene -Miocene Maikop Formation is the key source rock in the South Caspian and Kura Basins. The Maikop is composed of a thick (up to 3 km) succession of clay-rich mudstones containing up to 15% total organic carbon (TOC). Despite decades of study, the mudstones often lack precise age control -Maikop strata rarely contain diagnostic microfaunal assemblages which can be used for dating, stratigraphic correlation, or constraining the depositional setting. Using rhenium-osmium geochronology, this study adds important numerical age data for the Maikop Formation. Of five sample suites analysed from the Kura Basin, eastern Azerbaijan, one Re-Os data-set produced a significant range in 187 Re/ 188 Os versus 187 Os/ 188 Os space to yield an isochron of 17.2 ± 3.2 Ma (Early Miocene). Other sample suites yielded imprecise Re-Os age constraints as a result of variable initial 187 Os/ 188 Os values and a limited range in 187 Re/ 188 Os versus 187 Os/ 188 Os space. The initial 187