Nanotextures play increasingly important roles in nanotechnology. Recent studies revealed that their functionalities can be further enhanced by spatially modulating the height of their nanoscale pixels. Realizing the concept, however, is very challenging as it requires “grayscale” printing of the nanopixels in which their height is controlled within a few nanometers as a micrometric function of position. This work demonstrates such a high vertical and lateral resolution grayscale printing of polymeric nanopixels. We realize the height modulation by exploiting the discovery that the capillary rise of certain photopolymers can be optically controlled to stop at a predetermined height with sub-10-nm accuracy. Microscale spatial patterning of the control light directly extends the height modulation into a two-dimensionally patterned, grayscale nanopixel printing. Its utility is verified through readily reconfigurable, maskless printing of grayscale nanopixel arrays in dielectric and metallo-dielectric forms. This work also reveals the highly nonlinear and unstable nature of the polymeric nanocapillary effect, expanding its understanding and application scope.
Replica molding-based triboelectrification has emerged as a new and facile technique to generate nanopatterned tribocharge on elastomer surfaces. The “mechano-triboelectric charging model” has been developed to explain the mechanism of the charge formation and patterning process. However, this model has not been validated to cover the full variety of nanotexture shapes. Moreover, the experimental estimation of the tribocharge’s surface density is still challenging due to the thick and insulating nature of the elastomeric substrate. In this work, we perform experiments in combination with numerical analysis to complete the mechano-triboelectrification charging model. By utilizing Kelvin probe force microscopy (KPFM) and finite element analysis, we reveal that the mechano-triboelectric charging model works for replica molding of both recessed and protruding nanotextures. In addition, by combining KPFM with numerical electrostatic modeling, we improve the accuracy of the surface charge density estimation and cross-calibrate the result against that of electrostatic force microscopy. Overall, the regions which underwent strong interfacial friction during the replica molding exhibited high surface potential and charge density, while those suffering from weak interfacial friction exhibited low values on both. These multi-physical approaches provide useful and important tools for comprehensive analysis of triboelectrification and generation of nanopatterned tribocharge. The results will widen our fundamental understanding of nanoscale triboelectricity and advance the nanopatterned charge generation process for future applications.
Nanolenses are gaining importance in nanotechnology, but their challenging fabrication is thwarting their wider adoption. Of particular challenge is facile control of the lens’ curvature. In this work, we demonstrate a new nanoimprinting technique capable of realizing polymeric nanolenses in which the nanolens’ curvature is optically controlled by the ultraviolet (UV) dose at the pre-curing step. Our results reveal a regime in which the nanolens’ height changes linearly with the UV dose. Computational modeling further uncovers that the polymer undergoes highly nonlinear dynamics during the UV-controlled nanoimprinting process. Both the technique and the process model will greatly advance nanoscale science and manufacturing technology.
Soft material-based pneumatic microtube actuators are attracting intense interest, since their bending motion is potentially useful for the safe manipulation of delicate biological objects. To increase their utility in biomedicine, researchers have begun to apply shape-engineering to the microtubes to diversify their bending patterns. However, design and analysis of such microtube actuators are challenging in general, due to their continuum natures and small dimensions. In this paper, we establish two methods for rapid design, analysis, and optimization of such complex, shape-engineered microtube actuators that are based on the line-segment model and the multi-segment Euler–Bernoulli’s beam model, respectively, and are less computation-intensive than the more conventional method based on finite element analysis. To validate the models, we first realized multi-segment microtube actuators physically, then compared their experimentally observed motions against those obtained from the models. We obtained good agreements between the three sets of results with their maximum bending-angle errors falling within ±11%. In terms of computational efficiency, our models decreased the simulation time significantly, down to a few seconds, in contrast with the finite element analysis that sometimes can take hours. The models reported in this paper exhibit great potential for rapid and facile design and optimization of shape-engineered soft actuators.
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