Carbonate apatite/hydroxyapatite (CO3Ap/HAP) additive was obtained by calcination of wasted chicken bones at 900°C. Intermolecular attraction exists between CO3Ap/HAP additive and blended polysulfone (PSF) polymer. Electron dispersive X-ray (EDX) and FTIR analysis were carried out to check the elemental composition and bonding chemistry of prepared additive. The instantaneous demixing process generated consistent finger-like networks in CO3Ap/HAP/PSF-based composite membranes while sponge-like structure was shown by PSF as revealed by SEM images. The increase in weight % of additive loading is also confirmed by EDX analysis. Furthermore, the interaction mechanism of CO3Ap/HAP additive with polysulfone medium was analyzed by FTIR exploration. The water absorption experiment defined a 93% expansion in hydrophilic performance. Change in porosity occurs with additive loading and pure water permeation flux improved up to 11 times. Approximately, antifouling results revealed that 87% of water flux was recovered after treating with a protein solution, whereas a 30% improvement in antifouling capability in case of bovine serum albumin solution occurred. In vitro cytotoxicity, and clotting times study was carried out to evaluate virulent behavior and anticoagulation activity of formulated membranes.
Diclofenac sodium (DCF) is a non-steroidal anti-inflammatory drug mainly used as an analgesic, arthritic and anti-rheumatic. This study deals with the degradation of diclofenac by photo catalytic-based advanced oxidation processes. Artificial UV lamp and solar rays have been applied to activate the ZnO catalyst, thereby generating highly oxidizing species. These species initiate the degradation process of the drug, which results in intermediates that finally dissociate into carbon dioxide and water. The solar reactor system is comprised of quartz and borosilicate tubes alternatively for the absorption and transmission of the solar rays to the pollutant sample. The degradation rate has been analyzed by composition analysis using high performance liquid chromatography. TOC and COD tests have also been conducted for degraded samples. ZnO catalyst loading was tested from 0.1 gm/L to 1 gm/L and the degradation rate showed a rising trend up to 0.250 gm/L, but further increase in loading resulted in a drop in degradation. Similarly, degradation is higher in acidic condition as compared to neutral or basic pH. The results showed a higher degradation rate for UV lamp irradiation as compared to the solar system. Moreover, TOC and COD reduction is also found to be higher for UV lamp photo catalysis.
Recent development shows that carbon-based composites are proving to be the most promising materials in hydrogen energy production, storage and conversion applications. In this study, composites of the copper-based metal-organic framework with different ratios of graphite oxide have been prepared for hydrogen storage application. The developed materials are characterized by X-ray diffraction (XRD), gravimetric thermal analysis (TGA), scanning electron microscopy (SEM) and BET. The newly developed composites have an improved crystalline structure and an increased surface area. The results of the experiment showed that the composite material MOF/GO 20% can store 6.12% of hydrogen at −40 °C.
Diclofenac sodium (DCF) is a non-steroidal anti-inflammatory drug mainly used as an analgesic, arthritic and anti-rheumatic. This study deals with the degradation of diclofenac by photo catalytic-based advanced oxidation processes. The solar reactor system is comprised of quartz and borosilicate tubes for the absorption of the solar rays and transmission to the pollutant sample. Artificial UV lamp and solar rays have been applied to activate the ZnO catalyst, thereby generating highly oxidizing species. These species initiate the degradation process of the drug, which results in intermediates that finally dissociate into carbon dioxide and water. The degradation rate has been analyzed by composition analysis using high performance liquid chromatography. TOC and COD tests have also been conducted for degraded samples. ZnO catalyst loading was tested from 0.1 gm/L to 1 gm/L and the degradation rate showed a rising trend up to 0.250 gm/L, but further increase in loading resulted in a drop in degradation. Similarly, degradation is higher in acidic condition as compared to neutral or basic pH condition. The results showed a higher degradation rate for UV lamp irradiation as compared to the solar system. Moreover, TOC and COD reduction results were also found to be higher for UV lamp photo catalysis.
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