We numerically and theoretically investigate a highly sensitive and tunable plasmonic refractive index sensor that is composed of a metal-insulator-metal waveguide with a side-coupled nanoring, containing silver nanorods using the finite element method. Results reveal that the presence of silver nanorods in the nanoring has a significant impact on sensitivity and tunability performance. It gives a flexible way to tune the system response in the proposed structure. Our designed sensor has a sensitivity of 2080 nm/RIU (RIU is the refractive index unit) along with a figure of merit and a quality factor of 29.92 and 29.67, respectively. The adequate refractive index sensitivity can increase by adding the silver nanorods in a nanoring, which can induce new surface plasmon polaritons (SPPs) modes that cannot be found by a regular nanoring. For a practical application, a valid introduction of silver nanorods in the nanoring can dramatically reduce the dimension of the proposed structure without sacrificing performance.
One of the major contaminants of water bodies is dye pollutants that come from textile, paper, and leather industries. In this study, Casuarina equisetifolia needle (CEN) is used to remove methyl violet 2B (MV) from aqueous solutions. Batch experiments were done to investigate the contact time, effect of pH, initial dye concentrations, and temperature. Langmuir and Freundlich isotherm models were used to describe the interaction between the adsorbate and adsorbent. The sorption mechanism was described using Lagergren 1st order, pseudo 2nd order, and Weber-Morris intraparticle diffusion models. FTIR spectroscopy was used to analyze the functional groups of CEN before and after sorption with MV. Optimal conditions were found to be at room temperature with 2 h contact time and no pH adjustment was needed. Experimental data was best fitted onto Langmuir model with maximum adsorption capacity of 164.99 mg/g, while pseudo 2nd order best described the experimental data for the kinetics study. Thermodynamic parameters such as change in Gibbs free energy (Δ 0 ), enthalpy (Δ 0 ), and entropy (Δ 0 ) were also investigated.
A plasmonic metal-insulator-metal waveguide filter consisting of one rectangular cavity and three silver baffles is numerically investigated using the finite element method and theoretically described by the cavity resonance mode theory. The proposed structure shows a simple shape with a small number of structural parameters that can function as a plasmonic sensor with a filter property, high sensitivity and figure of merit, and wide bandgap. Simulation results demonstrate that a cavity with three silver baffles could significantly affect the resonance condition and remarkably enhance the sensor performance compared to its counterpart without baffles. The calculated sensitivity (S) and figure of merit (FOM) in the first mode can reach 3300.00 nm/RIU and 170.00 RIU−1. Besides, S and FOM values can simultaneously get above 2000.00 nm/RIU and 110.00 RIU−1 in the first and second modes by varying a broad range of the structural parameters, which are not attainable in the reported literature. The proposed structure can realize multiple modes operating in a wide wavelength range, which may have potential applications in the on-chip plasmonic sensor, filter, and other optical integrated circuits.
The removal of toxic dye rhodamine B (RB) from aqueous solution was achieved by using Casuarina equisetifolia cone (CEC) as an adsorbent. Batch experiment method was used in order to investigate the effects of contact time, pH, temperature, ionic strength, and dye concentration on the adsorption process. Kinetics and isotherm theoretical models were applied on the experimental data and it was found that the pseudo-2nd-order kinetics and the Langmuir isotherm model best fitted into the data. The Langmuir maximum adsorption capacity for CEC was determined as 49.5 mg g−1. The adsorption of RB onto CEC is thermodynamically favourable, feasible, and endothermic in nature.
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