The anticorrosion activity of biferrocenyl Schiff bases on AA2219-T6 in acidic medium were studied using Tafel polarization, electrochemical impedance spectroscopy, weight loss analysis, FT-IR spectroscopy and scanning electron microscopic technique.
Electrochemical sensors are gaining significant demand
for real-time
monitoring of health-related parameters such as temperature, heart
rate, and blood glucose level. A fiber-like microelectrode composed
of copper oxide-modified carbon nanotubes (CuO@CNTFs) has been developed
as a flexible and wearable glucose sensor with remarkable catalytic
activity. The unidimensional structure of CNT fibers displayed efficient
conductivity with enhanced mechanical strength, which makes these
fibers far superior as compared to other fibrous-like materials. Copper
oxide (CuO) nanoparticles were deposited over the surface of CNT fibers
by a binder-free facile electrodeposition approach followed by thermal
treatment that enhanced the performance of non-enzymatic glucose sensors.
Scanning electron microscopy and energy-dispersive X-ray analysis
confirmed the successful deposition of CuO nanoparticles over the
fiber surface. Amperometric and voltammetric studies of fiber-based
microelectrodes (CuO@CNTFs) toward glucose sensing showed an excellent
sensitivity of ∼3000 μA/mM cm2, a low detection
limit of 1.4 μM, and a wide linear range of up to 13 mM. The
superior performance of the microelectrode is attributed to the synergistic
effect of the electrocatalytic activity of CuO nanoparticles and the
excellent conductivity of CNT fibers. A lower charge transfer resistance
value obtained via electrochemical impedance spectroscopy (EIS) also
demonstrated the superior electrode performance. This work demonstrates
a facile approach for developing CNT fiber-based microelectrodes as
a promising solution for flexible and disposable non-enzymatic glucose
sensors.
Production of hydrogen through water splitting is one of the green and the most practical solutions to cope with the energy crisis and greenhouse effect. However, oxygen evolution reaction (OER) being a sluggish step, the use of precious metalbased catalysts is the main impediment toward the viability of water splitting. In this work, amorphous copper oxide and doped binary-and ternary-metal oxides (containing Co II , Ni II , and Cu II ) have been prepared on the surface of fluorine-doped tin oxide by a facile electrodeposition route followed by thermal treatment. The fabricated electrodes have been employed as efficient binder-free OER electrocatalysts possessing a high electrochemical surface area due to their amorphous nature. The cobalt−nickel-doped copper oxide (ternary-metal oxide)-based electrode showed promising OER activity with a high current density of 100 mA cm −2 at 1.65 V versus RHE that escalates to 313 mA cm −2 at 1.76 V in alkaline media at pH 14. The high activity of the ternary-metal oxide-based electrode was further supported by a smaller semicircle in the Nyquist plot. Furthermore, all metal-oxide-based electrodes offered high stability when tested for continuous production of oxygen for 50 h. This work highlights the synthesis of efficient and costeffective amorphous metal-based oxide catalysts to execute electrocatalytic OER employing an electrodeposition approach.
Polyoxometalates (POMs), as carbon-free metal-oxo-clusters with unique structural properties, are emerging water-splitting electrocatalysts. Herein, we explore the development of cobalt-containing polyoxometalate immobilized over the carbon nanotube fiber (CNTF) (Co4POM@CNTF) towards efficient electrochemical oxygen evolution reaction (OER). CNTF serves as an excellent electron mediator and highly conductive support, while the self-activation of the part of Co4POM through restructuring in basic media generates cobalt oxides and/or hydroxides that serve as catalytic sites for OER. A modified electrode fabricated through the drop-casting method followed by thermal treatment showed higher OER activity and enhanced stability in alkaline media. Furthermore, advanced physical characterization and electrochemical results demonstrate efficient charge transfer kinetics and high OER performance in terms of low overpotential, small Tafel slope, and good stability over an extended reaction time. The significantly high activity and stability achieved can be ascribed to the efficient electron transfer and highly electrochemically active surface area (ECSA) of the self-activated electrocatalyst immobilized over the highly conductive CNTF. This research is expected to pave the way for developing POM-based electrocatalysts for oxygen electrocatalysis.
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