Molecular semiconductors may exhibit antiferromagnetic correlations well below room temperature. Although inorganic antiferromagnetic layers may exchange bias single-molecule magnets, the reciprocal effect of an antiferromagnetic molecular layer magnetically pinning an inorganic ferromagnetic layer through exchange bias has so far not been observed. We report on the magnetic interplay, extending beyond the interface, between a cobalt ferromagnetic layer and a paramagnetic organic manganese phthalocyanine (MnPc) layer. These ferromagnetic/organic interfaces are called spinterfaces because spin polarization arises on them. The robust magnetism of the Co/MnPc spinterface stabilizes antiferromagnetic ordering at room temperature within subsequent MnPc monolayers away from the interface. The inferred magnetic coupling strength is much larger than that found in similar bulk, thin or ultrathin systems. In addition, at lower temperature, the antiferromagnetic MnPc layer induces an exchange bias on the Co film, which is magnetically pinned. These findings create new routes towards designing organic spintronic devices.
We experimentally and theoretically show that the magnetic coupling at room temperature between paramagnetic Mn within manganese phthalocyanine molecules and a Co layer persists when separated by a Cu spacer. The molecule's magnetization amplitude and direction can be tuned by varying the Cu-spacer thickness and evolves according to an interlayer exchange coupling mechanism. Ab initio calculations predict a highly spin-polarized density of states at the Fermi level of this metal-molecule interface, thereby strengthening prospective spintronics applications.
We report on an easy method to calibrate the transmission of radio-frequency (rf) voltages to the tunneling junction of a scanning tunneling microscope. The transmission strongly depends on frequency, as the cabling shows frequency dependent damping and the impedance mismatch between the cable and the tunneling junction induces reflections. To first order, the current-voltage characteristic of the junction induces a rf tunneling current of the same frequency as the rf voltage. Omnipresent non-linearities of the current-voltage characteristic of the junction to second order, however, generate an additional rectified DC. A direct comparison between this current and the second derivative of the current-voltage curve allows to determine the rf transmission to the tunneling junction. The transmission data up to 2 GHz were used to compensate the rf damping such that at every frequency a constant amplitude at the tunneling junction could be realized expanding the bandwidth of the experiment from less then 100 MHz to 2 GHz.
We used a homodyne detection to investigate the gyration of magnetic vortex cores in Fe islands on W(110) with spin-polarized scanning tunneling microscopy at liquid helium temperatures. The technique aims at local detection of the spin precession as a function of frequency using a radio-frequency (rf) modulation of the tunneling bias voltage. The gyration was excited by the resulting spin-polarized rf current in the tunneling junction. A theoretical analysis of different contributions to the frequency-dependent signals expected in this technique is given. These include, besides the ferromagnetic resonance signal, also signals caused by the non-linearity of the I ( U ) characteristics. The vortex gyration was modeled with micromagnetic finite element methods using realistic parameters for the tunneling current, its spin polarization, and the island shape, and simulations were compared with the experimental results. The observed signals are presented and critically analyzed.
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