The surface morphology of viscoelastic-sensitive films significantly affects sensing characteristics of surface acoustic wave (SAW) sensors. Uniformity and compactness of the film surface directly influences detectability of the SAW sensor toward target gases. Viscoelastic fluoroalcoholpolysiloxane (SXFA) was prepared in this work using spin coating technology on an SAW delay line of 200 MHz and then used as coating for detection of dimethyl methylphosphonate (DMMP). Polarizing, atomic force, and scanning electron microscopies confirmed the uniformity of the SXFA surface. The particle diameter in the cluster region was 10−15 μm. The contact angle (5.72−26.69°), surface tension (21.053−29.155 mN/m), Gibbs free energy (−160.68 to −153.45 J/m 2 ), and spreading coefficient (0.3028−6.9453 J/m 2 ) of different concentrations of SXFA were obtained through experiments, and their relation was analyzed using the Young T equation and Gibbs adsorption isotherm. The glass transition temperature (−19.7 °C) and elasticity of SXFA were also discussed. The consistency of sensor preparation was confirmed by detecting DMMP with five SAW sensors prepared simultaneously. Seven consecutive tests showed that the SAW sensor presents satisfactory repeatability (standard deviation, s, 1.134; coefficient of variance, v, 0.065; and population mean deviation, δ, 0.913) at a concentration of 1.71 mg/m 3 and acceptable linear relationship at a concentration range of 0.058−1.92 mg/m 3 , with a sensitivity of around 1.21 mv/(mg/m 3 ). The sensor exhibited outstanding sensitivity and satisfactory linearity and repeatability to DMMP. Meanwhile, the sensing mechanism in gas adsorption was also discussed in terms of LSER formulation and hydrogen bonding formation between SXFA and DMMP.
Purpose This paper aims to give an overview about the state of wireless passive surface acoustic wave (SAW) gas sensor used in the detection of chemical vapor. It also discusses a variety of different architectures including delay line and array sensor for gas detection, and it is considered that this technology has a good application prospect. Design/methodology/approach The authors state the most of the wireless passive SAW methods used in gas sensing, such as CO2, CO, CH4, C2H4, NH3, NO2, et al., the sensor principles, design procedures and technological issues are discussed in detail; their advantages and disadvantages are also summarized. In conclusion, it gives a prospect of wireless passive SAW sensor applications and proposes the future research field might lie in the studying of many kinds of harmful gases. Findings In this paper, the authors will try to cover most of the important methods used in gas sensing and their recent developments. Although wireless passive SAW sensors have been used successfully in harsh environments for the monitoring of temperature or pressure, the using in chemical gases are seldom reported. This review paper gives a survey of the present state of wireless passive SAW sensor in gas detection and suggests new and exciting perspectives of wireless passive SAW gas sensor technology. Research limitations/implications The authors will review most of the methods used in wireless passive SAW sensor and discuss the current research status and development trend; the potential application in future is also forecasted. Originality/value The authors will review most of the methods used in wireless passive SAW sensor and discuss the current research status and development trend; the potential application in future is also forecasted.
Reliable detection of airborne chemical warfare agents (CWAs) at the site and in real-time remains a challenge due to the rarity of miniaturized analytical tools. Herein, an ocarborane-functionalized benzothiazole derivative (PCBO) with excited-state intramolecular proton transfer (ESIPT) and AIE characteristics was synthesized. The PCBO-based film sensor showed a highly sensitive response to representative simulants of CWAs, and detection limits were found to be 1.0 mg•m −3 for triphosgene, 6.0 mg•m −3 for chloroethyl ethyl sulfide, and 0.2 mg• m −3 for diethyl chlorophosphite. Moreover, the sensor showed great reusability (>100 cycles) and unprecedented response speed (<0.5 s). The excellent sensing performance was ascribed to the microenvironmental sensitivity of the sensing fluorophore, the porous adlayer structure of the film, and the specific binding of the fluorophore to the analytes. Furthermore, discrimination and identification of the examined CWA simulants were realized via the introduction of another fluorophore (HCBO)-based film. Importantly, a portable fluorescent CWA detector was built with the sensor as the key component, and its applicability was demonstrated by the successful detection of a typical CWA sample (Sarin). The present study indicates that fluorescent film sensors could satisfy reliable onsite and real-time detection of harmful chemicals.
Hydrogen-bond acidic polymers are important high affinity materials sensitive to organophosphates in the chemical warfare agent sensor detection process. Interactions between the sensor sensitive materials and chemical warfare agent simulants were studied by inverse gas chromatography. Hydrogen bonded acidic polymers, i.e., BSP3, were prepared for micro-packed columns to examine the interaction. DMMP (a nerve gas simulant) and 2-CEES (a blister agent simulant) were used as probes. Chemical and physical parameters such as heats of absorption and Henry constants of the polymers to DMMP and 2-CEES were determined by inverse gas chromatography. Details concerning absorption performance are also discussed in this paper.
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