This paper reviews the research work carried out in bio-hydrogen generation from a renewable source, namely biomass. Bio-hydrogen production has several advantages when compared to photoelectrochemical or thermo-chemical processes due to the low energy requirement and investment cost. Hydrogen seems to be the future energy carrier by the virtue of renewable. Bio-hydrogen production processes also involve the production of CO 2 . However, this CO 2 was released from biomass, in which it was recently taken up, which is in contrast to fossil fuels, where the carbon dioxide has taken millions of years to build up, while the release takes only decades. So the duration of the carbon cycle is very important in view of sustainability.
Solute runoff and leaching are two direct pathways of nutrient pollution from paddy fields into water systems. Due to the dynamic nature of paddy fields, solute transport and transformation processes are complex and difficult to understand. Therefore, in this study, nitrogen (N) transport in flooded paddy rice fields with conventional irrigation (flooding irrigation) in the Tanjung Karang Rice Irrigation Scheme (TAKRIS), Sawah Sempadan, were observed and modelled using the Hydrus-1D numerical model during two consecutive rice growing seasons. Based on solute transport analysis results, it was observed that 50.3% to 48% of percolated N was accumulated in the top 40-cm soil layer, while 49.7% to 52% of leachate N was lost below the 40-cm soil layer (40-100 cm) during the off and main seasons, respectively. About 85% of N leaching loss was in the form of NO 3 −. NO 3 − was absorbed by rice roots within 0-40 cm and the denitrified root zone; however, there was still a large quantity of NO 3 − which remained below the root zone, which was quickly transported downward along with the leachate water. The NH 4 + concentration in subsurface water was lower than the NO 3 − concentration due to various processes that removed NH 4 + from the topsoil layer (0-40 cm), such as ammonium volatilisation, nitrification, and plant uptake. The total leaching loss of N was 34.9 and 27.9 kg/ha during the off and main seasons, respectively. The simulated and observed water flow and nutrient leaching were in a good agreement (R 2 = 0.98, RMSE = 0.24). The results showed that Hydrus-1D successfully simulated the solute movement under different soil depths during the study period.
Trend analyses of monthly, seasonal and annual rainfall, air temperature, and streamflow were performed using Mann‐Kendall test within the Langat River basin to identify gradual trends and abrupt shifts for 1980 − 2010. Annual rainfall showed an increasing trend in upstream flow, a combination of decreasing and increasing trends in middle stream flow, and a decreasing trend in downstream flow. Monthly rainfall in most months displayed an insignificant increasing trend upstream. Stations with significant increasing trends showed larger trends in summer than those of other seasons. However, they were similar to the trends observed in annual rainfall. Annual minimum air temperature showed a significant decreasing trend upstream and significant increasing trends in the middle stream and downstream areas. Annual maximum air temperature portrayed increasing trends in both upstream and middle stream areas, and a decreasing trend for the downstream area. Both monthly and seasonal maximum air temperatures exhibited an increasing trend midstream, whereas they demonstrated trends of both decreasing and/or increasing temperatures at upstream and downstream areas. Annual streamflow in upper, middle and lower catchment areas exhibited significant increasing trend at the rates of 0.036, 0.023 and 0.001 × 103 m3/y at α = 0.01, respectively. Seasonal streamflow in the upstream, midstream and downstream areas displayed an increasing trend for spring (0.55, 0.33 and 0.013 m3/y respectively) and summer (0.51, 0.37, 0.018 m3/y respectively). The greatest magnitude of increased streamflow occurred in the spring (0.54 m3/y). Significant increasing trends of monthly streamflow were noticed in January and August, but insignificant trends were found in May, September and November at all stations. Annual streamflow records at the outlet of the basin were positively correlated with the annual rainfall variable. This study concludes that the climate of the Langat River basin has been getting wetter and warmer during 1980‐2010.
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