A robust NNS-manganese(i) complex has been developed that can efficiently catalyze the dehydrogenation coupling of γ-amino alcohols with ketones or secondary alcohols in a one-step synthesis of quinolines and pyridines with high yields.
The depicted cobalt precatalysts, prepared using a one pot strategy, can form highly active catalysts at temperatures between 50 °C and 60 °C and can mediate the formation of linear PEs displaying high molecular weights and narrow dispersities.
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