We present a new set of clay mineral and grain-size data for the siliciclastic sediment fraction from International Ocean Discovery Program (IODP) Site U1456 located in the eastern Arabian Sea to reconstruct the variabilities in the continental erosion and weathering intensity in the western Himalaya, elucidate the sediment source-to-sink processes and discuss the potential controls underlying these changes since 3.7 Ma. The clay minerals mainly consist of smectite (0–90%, average 44%) and illite (3–90%, average 44%), with chlorite (1–26%, average 7%) and kaolinite (0–19%, average 5%) as minor components. The compositional variations in the clay minerals at IODP Site U1456 suggest four phases of sediment provenance: the Indus River (phase 1, 3.7–3.2 Ma), the Indus River and Deccan Traps (phase 2, 3.2–2.6 Ma), the Indus River (phase 3, 2.6–1.2 Ma) and the Indus River and Deccan Traps (phase 4, 1.2–0 Ma). These provenance changes since 3.7 Ma can be correlated with variations in the Indian summer monsoon intensity. The siliciclastic sediments in the eastern Arabian Sea were mainly derived from the Indus River when the Indian summer monsoon was generally weak. In contrast, when the Indian summer monsoon intensified, the siliciclastic sediment supply from the Deccan Traps increased. In particular, this study shows that the smectite/(illite+chlorite) ratio is a sensitive tool for reconstructing the history of the variation in the Indian summer monsoon intensity over the continents surrounding the Arabian Sea since 3.7 Ma.
We present a multiproxy record of Sr-Nd isotopes and major and trace elements for clay-sized (<2 μm) siliciclastic sediment fractions from the International Ocean Discovery Program Site U1456 in the eastern Arabian Sea to extract reliable chemical indicators not influenced by the grain-size effect, quantitatively estimate detrital provenance, and constrain silicate weathering/erosion in response to the Indian summer monsoon over orbital timescales. A provenance analysis of fine-grained siliciclastic sediments indicates a two end-member mixture from the Indus River (20-90%) and rivers draining the Deccan Traps (10-80%). A prominent increase in terrigenous input from the Indus River occurred at 0.5 Ma, probably resulting from an intensive erosional event in the Himalayan region. Moreover, α Al K at Site U1456, which is calculated as Al/K ratio of the study sample versus Al/K ratio of the upper continental crust, can be generally used to reflect the chemical weathering intensity in the source regions. During most interglacial and even certain glacial periods, the Indian summer monsoon reinforcement is closely coupled with enhanced continental chemical weathering and physical erosion. Wavelet and spectral analyses of the α Al K record display strong 125-, 35-, 29-, and 23-kyr periodicities since 1.2 Ma with significant 100-kyr cycles established at the end of the Mid-Pleistocene Transition (~0.7 Ma), suggesting forcing mechanisms linked with both Northern and Southern Hemispheric processes. Significant fluctuations observed in silicate weathering/erosion during~1.2-0.7 Ma indicate an enhancement of the Indian summer monsoon with increased variability in association with the Mid-Pleistocene Transition.
Systematic variation in elemental and Sr-Nd isotopic compositions of the clay-sized (<2 μm) siliciclastic fraction from the International Ocean Discovery Program (IODP) Site U1456 (Laxmi Basin) provides valuable insights into dynamic changes in continental weathering intensity in the western Himalayas and sediment inputs from the Indus River and Deccan Traps to the eastern Arabian Sea. Long-term, high-resolution proxy records from the sediment core reveal that the main sources (i.e., Indus River and Deccan Trap basalts) of the fine-grained detrital sediments have significantly changed with Indian summer monsoon variation over the studied time interval. During two depositional periods (3.8-3.3 and 2.7-1.2 Ma) corresponding to a weak Indian summer monsoon, the Indus River contributed fine-grained sediments with high K/Al, high 87 Sr/ 86 Sr, and low εNd to the study site. Between 3.3 and 2.7 Ma and between 1.2 and 0 Ma, deposition in the eastern Arabian Sea was governed by large inputs of Deccan Trap-derived basaltic sediments, characterized by high Mg/Al and Fe/Al, low 87 Sr/ 86 Sr and chemical index of alteration values, and high εNd values, associated with a change to a stronger Indian summer monsoon driving stronger chemical weathering. Synchronous changes in the geochemical proxies since 3.8 Ma highlight that variations in the inputs of siliciclastic sediments and Indian summer monsoon development are closely coupled. Plain Language SummaryThe Indian summer monsoon is an extremely important part of the Earth's climate system. Weathering and erosion of sediments are deeply affected by monsoon rainfall. Since 3.8 Ma, the geochemical records suggest that the clay-sized siliciclastic fractions at Site U1456 were mainly derived from the Indus River when the Indian summer monsoon was generally weak. In contrast, the siliciclastic sediment supply from the Deccan Traps increased when the monsoon intensified. In particular, we propose that chemical weathering intensities can be tracked using K/Al ratios and chemical index alteration and the smectite/(illite + chlorite) in the fine fraction of marine sediments from the eastern Arabian Sea since 3.8 Ma. Conducting research in the region is of great importance for understanding past and present climatic conditions.
Based on the broad-spectrum biological activities of echinopsine and acylhydrazones, a series of echinopsine derivatives containing acylhydrazone moieties have been designed, synthesized and their biological activities were evaluated for the first time. The bioassay results indicated that most of the compounds showed moderate to good antiviral activities against tobacco mosaic virus (TMV), among which echinopsine (I) (inactivation activity, 49.5 ± 4.4%; curative activity, 46.1 ± 1.5%; protection activity, 42.6 ± 2.3%) and its derivatives 1 (inactivation activity, 44.9 ± 4.6%; curative activity, 39.8 ± 2.6%; protection activity, 47.3 ± 4.3%), 3 (inactivation activity, 47.9 ± 0.9%; curative activity, 43.7 ± 3.1%; protection activity, 44.6 ± 3.3%), 7 (inactivation activity, 46.2 ± 1.6%; curative activity, 45.0 ± 3.7%; protection activity, 41.7 ± 0.9%) showed higher anti-TMV activity in vivo at 500 mg/L than commercial ribavirin (inactivation activity, 38.9 ± 1.4%; curative activity, 39.2 ± 1.8%; protection activity, 36.4 ± 3.4%). Some compounds exhibited insecticidal activities against Plutella xylostella, Mythimna separate and Spodoptera frugiperda. Especially, compounds 7 and 27 displayed excellent insecticidal activities against Plutella xylostell (mortality 67 ± 6% and 53 ± 6%) even at 0.1 mg/L. Additionally, most echinopsine derivatives exhibited high fungicidal activities against Physalospora piricola and Sclerotinia sclerotiorum.
The Himalayan and Tibetan highlands (mountains), with high rates of physical erosion, are extreme settings for earth surface processes, generating one of the largest recent terrigenous detritus and organic carbon discharges to the ocean. However, their significance with respect to the global carbon and climate cycles during the Quaternary is still unclear, especially in quantitative terms. Here, we present comprehensive records of continental erosion and weathering, terrestrial supply, marine productivity, and organic carbon burial in the distal Arabian Sea, Bay of Bengal, and southern South China Sea since ∼700 ka over orbital timescales. These records exhibit periodicities corresponding to sea level and Indian summer monsoon intensity changes. During glacial periods, the enhanced highland surface erosion and activation of deep-sea channels significantly increased inputs of terrigenous detritus, nutrients, and organic carbon into the Arabian Sea and Bay of Bengal, whereas strengthened continental shelf surface weathering and organic matter preservation occurred in the South China Sea. Conclusively, our integrative proxies in the study area demonstrate, for the first time, pronounced glacial burial pulses of organic carbon (∼1.12 × 10 12 mol/yr), dominantly originating from the highland surface erosion and marine productivity. Together with the increased silicate weathering on the exposed tropical continental shelves and in the tropical volcanic arcs, the enhanced burial flux of organic carbon in the tropical marginal seas, therefore, highlights the large contributions that tropical regions can make within the glacial-interglacial carbon inventory of the ocean and atmosphere and thus cause significant negative feedback on the global climate. Plain Language Summary Anthropogenic emissions of the greenhouse gas CO 2 are significantly changing the global climate and environment, resulting in a warmer state for which there is no historical analog. Marine records hold valuable lessons for the future of our warming world, as marine sediments are an important reservoir of the global organic carbon and then modulate release of CO 2 into the atmosphere. Currently, the major river systems originating from the Himalaya and Tibetan Plateau discharge ∼25% of the global fluvial sediment flux to the ocean, acting as an important source of continental organic carbon at tectonic and current timescales. Our integrative mineralogicalgeochemical study demonstrates the enhanced highland (mountain) erosion and activation of deep-sea channels, increased supplies of the produced materials, strengthened marine productivity, and effective preservation of organic carbon in the deep Arabian Sea and Bay of Bengal during cold periods. In contrast, strengthened chemical decomposition of silicates on the exposed continental shelf was coeval with increased organic carbon storage in the deep South China Sea. The study area contributed ∼1/4 of the current global marine burial flux of organic carbon during sea-level lowstands and thus represents a ...
We investigated the microscopic mineral characteristics of modern eolian dust particulates and the trace-element compositions of the siliciclastic fractions of these samples, collected from the Philippine Sea in 2014 and 2015, and conducted an air mass backwards trajectory analysis of dust particulates in the spring and winter of 2015, to better constrain the provenances and transport dynamics of dust delivered to this region. The microscopic minerals show obvious signatures of dust deposition and physical abrasion, indicating long-distance wind transport from the Asian deserts. The trace-element compositions (Zr–Th–Sc) display a binary mixture of eolian materials derived from the eastern Asian deserts and the central Asian deserts, which is similar to the result of the Sr–Nd isotopic compositions of modern sediment trap sediments collected on the Benham Rise in 2015. We demonstrate that modern dust sediments in the Philippine Sea primarily originate from the Ordos Desert (generally > 80%), while the contributions of the Taklimakan Desert and the Badain Jaran Desert are small. Eolian dust particulates raised from source regions are predominantly transported to the Philippine Sea by the East Asian winter monsoon, but not by the westerlies. In addition, our results indicate that increased precipitation in the source regions can result in relatively low dust fluxes in the Philippine Sea, and there is a period of 6–7 days for eolian dust originating from source areas to be delivered to the Philippine Sea.
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