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The authors studied the effect of vanadium addition on the microstructure and properties of Al 0.5 CoCrCuFeNi high-entropy alloy. The microstructure of Al 0.5 CoCrCuFeNiV x (x 5 0 to 2.0 in molar ratio) alloys was investigated by scanning electron microscopy, energy dispersive spectrometry, and X-ray diffraction. With little vanadium addition, the alloys are composed of a simple fcc solidsolution structure. As the vanadium content reaches 0.4, a BCC structure appears with spinodal decomposition and envelops the FCC dendrites. From x 5 0.4 to 1.0, the volume fraction of bcc structure phase increases with the vanadium content increase. When x 5 1.0, fcc dendrites become completely replaced by bcc dendrites. Needle-like s-phase forms in bcc spinodal structure and increases from x 5 0.6 to 1.0 but disappears from x 5 1.2 to 2.0. The hardness and wear resistance of the alloys were measured and explained with the evolution of the microstructure. The hardness values of the alloys increase when the vanadium content increases from 0.4 to 1.0 and peak (640 HV) at a vanadium content of 1.0. The wear resistance increases by around 20 pct as the content of vanadium increases from x 5 0.6 to 1.2 and levels off beyond x 5 1.2. The optimal vanadium addition is between x 5 1.0 and 1.2. Compared with the previous investigation of Al 0.5 CoCrCuFeNi alloy, the vanadium addition to the alloy promotes the alloy properties.

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