Silicon nanowire possesses great potential as the material for renewable energy harvesting and conversion. The significantly reduced spectral reflectivity of silicon nanowire to visible light makes it even more attractive in solar energy applications. However, the benefit of its use for solar thermal energy harvesting remains to be investigated and has so far not been clearly reported. The purpose of this study is to provide practical information and insight into the performance of silicon nanowires in solar thermal energy conversion systems. Spectral hemispherical reflectivity and transmissivity of the black silicon nanowire array on silicon wafer substrate were measured. It was observed that the reflectivity is lower in the visible range but higher in the infrared range compared to the plain silicon wafer. A drying experiment and a theoretical calculation were carried out to directly evaluate the effects of the trade-off between scattering properties at different wavelengths. It is clearly seen that silicon nanowires can improve the solar thermal energy harnessing. The results showed that a 17.8 % increase in the harvest and utilization of solar thermal energy could be achieved using a silicon nanowire array on silicon substrate as compared to that obtained with a plain silicon wafer.

Cavitation, known as the formation of vapor bubbles when liquids are under tension, is of great interest both in condensed matter science as well as in diverse applications such as botany, hydraulic engineering, and medicine. Although widely studied in bulk and microscale-confined liquids, cavitation in the nanoscale is generally believed to be energetically unfavorable and has never been experimentally demonstrated. Here we report evaporation-induced cavitation in water-filled hydrophilic nanochannels under enormous negative pressures up to −7 MPa. As opposed to receding menisci observed in microchannel evaporation, the menisci in nanochannels are pinned at the entrance while vapor bubbles form and expand inside. Evaporation in the channels is found to be aided by advective liquid transport, which leads to an evaporation rate that is an order of magnitude higher than that governed by Fickian vapor diffusion in macro-and microscale evaporation. The vapor bubbles also exhibit unusual motion as well as translational stability and symmetry, which occur because of a balance between two competing mass fluxes driven by thermocapillarity and evaporation. Our studies expand our understanding of cavitation and provide new insights for phase-change phenomena at the nanoscale.nanobubbles | confined fluids | confined water | bubble dynamics | bubble formation

Ab!ltraet-A detalled physical model of the Hfe history of a typical �ubble plume, from Its formation by a breakin& wave to its dissipation Into the background bubble population, is set down, and the relation ship between the early, acoustically relevant stages in bubble-plume development and the associat ed, remotely detectable whitecap is de scribed. The manner in which the fraction of the sea snrface covered by Stage A spilling crests and by Stage B mature whitecaps depends upon wind speed and upon wind stress or "friction velocity" is investigated.Formal expressions are given whereby near-surface bubble concentra tions can be estimated from observations of fractional whitecap cover· age or from measurements of tbe 10·m elevation Wind spee d.

Condensation is a common phenomenon and is widely exploited in power generation and refrigeration devices. Although drop‐wise condensation offers high heat and mass transfer rates, it is extremely difficult to maintain and control. In this study, the ability to spatially control heterogeneous nucleation on a superhydrophobic surface by manipulating the free energy barrier to nucleation through parameterizing regional roughness scale on the Si nanowire array‐coated surface is reported. Water vapor preferentially condenses on the designed microgrooves on the Si nanowire surface and continuous shedding of the drop‐wise condensate is observed on the surface. The nucleation site density can also be manipulated by tailoring the density of the microgroove on the surface. Moreover, the cycle time on the Si nanowire array with microgrooves is approximately ten times smaller than that on a plain Si surface. This suggests that potentially high heat and mass transfer rates can be achieved on the surface. The insight from this study has implications in enhancing energy efficiency in a wide range of thermal energy conversion systems.

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Evaporation from nanopores plays an important role in various natural and industrial processes that require efficient heat and mass transfer. The ultimate performance of nanopore-evaporation-based processes is dictated by evaporation kinetics at the liquid–vapor interface, which has yet to be experimentally studied down to the single nanopore level. Here we report unambiguous measurements of kinetically limited intense evaporation from individual hydrophilic nanopores with both hydrophilic and hydrophobic top outer surfaces at 22 °C using nanochannel-connected nanopore devices. Our results show that the evaporation fluxes of nanopores with hydrophilic outer surfaces show a strong diameter dependence with an exponent of nearly −1.5, reaching up to 11-fold of the maximum theoretical predication provided by the classical Hertz–Knudsen relation at a pore diameter of 27 nm. Differently, the evaporation fluxes of nanopores with hydrophobic outer surfaces show a different diameter dependence with an exponent of −0.66, achieving 66% of the maximum theoretical predication at a pore diameter of 28 nm. We discover that the ultrafast diameter-dependent evaporation from nanopores with hydrophilic outer surfaces mainly stems from evaporating water thin films outside of the nanopores. In contrast, the diameter-dependent evaporation from nanopores with hydrophobic outer surfaces is governed by evaporation kinetics inside the nanopores, which indicates that the evaporation coefficient varies in different nanoscale confinements, possibly due to surface-charge-induced concentration changes of hydronium ions. This study enhances our understanding of evaporation at the nanoscale and demonstrates great potential of evaporation from nanopores.

There is no consensus on the effect of nanoparticle (NP) addition on the specific heat capacity (SHC) of fluids. In addition, the predictions from the existing model have a large discrepancy from the measured SHCs in nanofluids. We show that the SHC of the molten salt-based alumina nanofluid decreases with reducing particle size and increasing particle concentration. The NP size-dependent SHC is resulted from an augmentation of the nanolayer effect as particle size reduces. A model considering the nanolayer effect which supports the experimental results was proposed.

Biporous media consisting of microscale pin fins separated by microchannels are examined as candidate structures for the evaporator wick of a vapor chamber heat pipe. The structures are fabricated out of silicon using standard lithography and etching techniques. Pores which separate microscale pin fins are used to generate high capillary suction, while larger microchannels are used to reduce overall flow resistance. The heat transfer coefficient is found to depend on the area coverage of a liquid film with thickness on the order of a few microns near the meniscus of the triple phase contact line. We manipulate the area coverage and film thickness by varying the surface area-to-volume ratio through the use of microstructuring. Experiments are conducted for a heater area of 1 cm2 with the wick in a vertical orientation. Results are presented for structures with approximately same porosities, fixed microchannel widths w ≈ 30 μm and w ≈ 60 μm, and pin fin diameters ranging from d = 3–29 μm. The competing effects of increase in surface area due to microstructuring and the suppression of evaporation due to reduction in pore scale are explored. In some samples, a transition from evaporative heat transfer to nucleate boiling is observed. While it is difficult to identify when the transition occurs, one can identify regimes where evaporation dominates over nucleate boiling and vice versa. Heat transfer coefficients of 20.7 (±2.4) W/cm2-K are attained at heat fluxes of 119.6 (±4.2) W/cm2 until the wick dries out in the evaporation dominated regime. In the nucleate boiling dominated regime, heat fluxes of 277.0 (±9.7) W/cm2 can be dissipated by wicks with heaters of area 1 cm2, while heat fluxes up to 733.1 (±103.4) W/cm2 can be dissipated by wicks with smaller heaters intended to simulate local hot-spots.