Electrostatic dissipative (ESD), anti-static (AS), and electromagnetic interference (EMI) shielding materials are commonly based on commodity fossil-fuel-based plastics. This, in turn, contributes to ever-growing non-biodegradable plastic pollution. Graphene nanoplatelets (GN), multi-walled carbon nanotubes (MWCNT), nanostructured carbon black (NCB), and amorphous carbon black (CB) were utilized as nanofillers to prepare bio-based and biodegradable poly(butylene succinate-co-adipate) (PBSA) nanocomposites. Solvent-cast composites were prepared with 1.1 to 30.0 vol.% nanoparticle loading. The literature mainly focuses on relatively low loadings; therefore, for this research, filler loadings were increased up to 30 vol.% but the maximum loading for NCB and CB loadings only reached 17.4 vol.% due to a lack of dimensional stability at higher loadings. The composites were characterized using tensile testing, volumetric and surface conductivity measurements, thermal conductivity measurements, dielectric spectroscopy in the microwave region, and transmittance in the terahertz range. Tensile tests showed excellent carbon filler compatibility and enhanced tensile strength for loadings up to 5 vol.% (up to 20 vol.% for MWCNT). The highest thermal conductivity values were reached for the MWCNT filler, with the 30.0 vol.% filled composite reaching 0.756 W/mK (262% increase over PBSA). All fillers were able to produce composites that yielded volume conductivities above 10−10 S/m. Composites with MWCNT, GN, and NCB inclusions above the percolation threshold are suitable for EMI applications in the microwave and THz frequency range.
To address the ever-increasing electromagnetic interference (EMI) pollution, a hybrid filler approach for novel composites was chosen, with a focus on EMI absorbance. Carbon nanofiller loading was limited to 0.6 vol.% in order to create a sustainable and affordable solution. Multiwall carbon nanotubes (MWCNT) and iron oxide (Fe3O4) nanoparticles were mixed in nine ratios from 0.1 to 0.6 vol.% and 8.0 to 12.0 vol.%, respectively. With the addition of surfactant, excellent particle dispersion was achieved (examined with SEM micrographs) in a bio-based and biodegradable poly(butylene succinate) (PBS) matrix. Hybrid design synergy was assessed for EMI shielding using dielectric spectroscopy in the microwave region and transmittance in the terahertz range. The shielding effectiveness (20–52 dB) was dominated by very high absorption at 30 GHz, while in the 0.1 to 1.0 THz range, transmittance was reduced by up to 6 orders of magnitude. Frequency-independent AC electrical conductivity (from 10−2 to 107 Hz) was reached upon adding 0.6 vol.% MWCNT and 10 vol.% Fe3O4, with a value of around 3.1 × 10−2 S/m. Electrical and thermal conductivity were mainly affected by the content of MWCNT filler. The thermal conductivity scaled with the filler content and reached the highest value of 0.309 W/(mK) at 25 °C with the loading of 0.6 vol.% MWCNT and 12 vol.% Fe3O4. The surface resistivity showed an incremental decrease with an increase in MWCNT loading and was almost unaffected by an increase in iron oxide loading. Thermal conductivity was almost independent of temperature in the measured range of 25 to 45 °C. The nanocomposites serve as biodegradable alternatives to commodity plastic-based materials and are promising in the field of electromagnetic applications, especially for EMI shielding.
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