X-ray diffraction analysis of the Rocknest scoop sample is described in (23); similar analyses were performed for John Klein and Cumberland. John Klein and Cumberland were the first two drill samples collected by Curiosity. All scooped or drilled samples pass through the Collection and Handling for In situ Martian Rock Analysis (CHIMRA) sample collection and processing system (10). All powders for X-ray diffraction are processed through a 150-m sieve before delivering a portion to the CheMin inlet funnel.The sieved drill powders were placed into sample cells with 6 μm thick Mylar® windows. Mylar® contributes a minor, broad scattering signature in diffraction patterns that is generally "swamped" by diffraction from the loaded sample. In addition, an aluminized light shield also contributes "peaks" to the observed diffraction patterns. Only ~10 mm 3 of material is required to fill the active volume of the sample cell, which is a disc-shaped volume 8 mm in diameter and 175 m thick. A collimated ∼70 μm diameter X-ray beam illuminates the center of the sample cell. A piezoelectric vibration system on each cell pair shakes the material during analysis, causing grains in the cell to pass through the X-ray beam in random orientations.CheMin measures XRD and XRF data simultaneously using Co radiation in transmission geometry (11). The instrument operates in single-photon counting mode so that between each readout the majority of CCD pixels are struck by either a single X-ray photon or by no photons. In this way, the system can determine both the energy of the photons striking the CCD (XRF) and the two-dimensional (2-D) position of each photon (XRD). The energy and positional information of detected photons in each frame are summed over repeated 10-sec measurements into a "minor frame" of 30 min of data (180 frames). The 2-D distribution of Co K X-ray intensity represents the XRD pattern of the sample. Circumferential integration of these rings, corrected for arc length, produces a conventional 1-D XRD pattern. For conversion of the 2-D CCD pattern to a 1-D pattern we have used FilmScan © software from Materials Data, Inc.CheMin generally operates for only a few hours each night, when the CCD can be cooled to its lowest temperature, collecting as many minor frames as possible for the available analysis time, usually five to seven per night. XRD data were acquired over multiple nights for the John Klein and Cumberland drill samples to provide acceptable counting statistics. Total data collection times were 33.9 hr for John Klein and 20.2 hr for Cumberland. The data for individual minor frames and for each night's analysis were examined separately, and there was no evidence of any changes in instrumental parameters as a function of time over the duration of these analyses. Before sample delivery and analysis, the empty cell was analyzed to confirm that it was indeed empty before receiving the sample. The flight instrument was calibrated on the ground before flight using a quartz-beryl standard, and measurement of this st...

International audienceA core flow test autoclave has been designed in order to reproduce an injection well at a scale of 1/20. This autoclave allows the CO2 injection into a steel tube cemented to a core sample of red sandstone from the Triassic formations of Lorraine (France). Temperature and pressure gradients can be recorded between the injection point and the confining water phase. Such gradients imply solubility gradients of CO2 and mineral species into the water phase as permeability changes with time. Some chemical reactions can be observed from collected sample at the end of the experiment. Precipitation and dissolution are suspected both into the cement and rock phases. No fracturing is observed. Cement-rock interface is not opened

The Mars Science Laboratory rover Curiosity scooped samples of soil from the Rocknest aeolian bedform in Gale crater. Analysis of the soil with the Chemistry and Mineralogy (CheMin) x-ray diffraction (XRD) instrument revealed plagioclase (~An57), forsteritic olivine (~Fo62), augite, and pigeonite, with minor K-feldspar, magnetite, quartz, anhydrite, hematite, and ilmenite. The minor phases are present at, or near, detection limits. The soil also contains 27 ± 14 weight percent x-ray amorphous material, likely containing multiple Fe(3+)- and volatile-bearing phases, including possibly a substance resembling hisingerite. The crystalline component is similar to the normative mineralogy of certain basaltic rocks from Gusev crater on Mars and of martian basaltic meteorites. The amorphous component is similar to that found on Earth in places such as soils on the Mauna Kea volcano, Hawaii.

Abstract.All potential exogenous pre-biotic matter arrived to Earth by ways of our atmosphere, where much material was ablated during a luminous phase called "meteors" in rarefied flows of high (up to 270) Mach number. The recent Leonid showers offered a first glimpse into the elusive physical conditions of the ablation process and atmospheric chemistry associated with high-speed meteors. Molecular emissions were detected that trace a meteor's brilliant light to a 4,300 K warm wake rather than to the meteor's head. A new theoretical approach using the direct simulation by Monte Carlo technique identified the source-region and demonstrated that the ablation process is critical in the heating of the meteor's wake. In the head of the meteor, organic carbon appears to survive flash heating and rapid cooling. The temperatures in the wake of the meteor are just right for dissociation of CO and the formation of more complex organic compounds. The resulting materials could account for the bulk of pre-biotic organic carbon on the early Earth at the time of the origin of life.

We calculate the position of dust trails from comet 8P/Tuttle, in an effort to explain unusual Ursid meteor shower outbursts that were seen when the comet was near aphelion. Comet 8P/Tuttle is a Halley-type comet in a 13.6-year orbit, passing just outside of Earth's orbit. We find that the meteoroids tend to be trapped in the 12:14 mean motion resonance with Jupiter, while the comet librates in a slightly shorter period orbit around the 13:15 resonance. It takes 6 centuries to decrease the perihelion of the meteoroid orbits enough to intersect Earth's orbit, during which time the meteoroids and comet separate in mean anomaly by 6 years, thus explaining the 6-year lag between the comet's return and Ursid outbursts. The resonances also prevent dispersion along the comet orbit and limit viewing to only one year in each return. We identified past dust trail encounters with dust trails from 1392 (Dec. 1945) and 1378 (Dec. 1986) and predicted another outburst on 2000 December 22 at around 7:29 and 8:35 UT, respectively, from dust trails dating to the 1405 and 1392 returns. This event was observed from California using video and photographic techniques. At the same time, five Global-MS-Net stations in Finland, Japan, and Belgium counted meteors using forward meteor scatter. The outburst peaked at 8:06 ± 07 UT, December 22, at zenith hourly rate ∼90 per hour, and the Ursid rates were above half peak intensity during 4.