The fusion of 6 He with a 209 Bi target has been studied at energies near to and below the Coulomb barrier. Despite the weak binding of the valence neutrons in 6 He, little evidence is found for suppression of fusion due to projectile breakup. Instead, a large enhancement of sub-barrier fusion is observed. It is suggested that this enhancement may arise from coupling to positive Q value neutron transfer channels, resulting in "neutron flow" between the projectile and the target. [S0031-9007 (98)07674-1] PACS numbers: 25.60.Pj, 25.70.JjRecent theoretical studies of near-barrier and subbarrier fusion of the exotic "neutron halo" system 11 Li with 208 Pb (see, e.g., [1][2][3][4][5]) have generated a considerable amount of interest and controversy. The 11 Li nucleus contains two valence neutrons that are only very weakly coupled to a relatively tightly bound 9 Li core. This unusual composition manifests itself in both the structure of the nucleus, as in the existence of the neutron halo and of low-lying E1 modes [6], and also in reactions with other nuclei. Furthermore, neither the n-9 Li nor the n-n subsystems of 11 Li are bound, so that particle stability in this nucleus is achieved via three-body interactions. Systems of this kind, referred to as "Borromean" nuclei [7], provide an unusual opportunity to study three-body interactions in the nucleus.It has been known for some time that sub-barrier fusion of stable nuclei can be enhanced by several orders of magnitude beyond expectations from simple one-dimensional barrier penetration calculations. A qualitative understanding of this phenomenon has been achieved in terms of couplings to internal degrees of freedom of the target and projectile [8], resulting in a lowering of the effective fusion barrier. This dynamical effect is a very sensitive probe of the nuclear structure of the colliding partners. A lowering of the barrier, by 20% or more, is also a general feature in the results for 11 Li 1 208 Pb fusion presented in [1][2][3][4][5], but the leading effect that was calculated in this case is a static one, resulting from the larger radius of the 11 Li "halo" wave function which allows the attractive nuclear force to act at longer distances. However, additional dynamical enhancement was obtained from the coupling to the soft E1 mode [1,2]. The role played by projectile breakup channels, which are possibly important due to the weak binding of the valence neutrons, is considerably more controversial. Several groups [2][3][4] have reported that coupling to these channels reduces the fusion cross section near the barrier, leading to intriguing structure in the excitation function in this region. However, this point of view has been criticized by Dasso and Vitturi [5] who suggest that it results from a misunderstanding of the nature of multidimensional quantum-mechanical tunneling processes. They report only enhancement of the fusion yield, even in the presence of strong breakup channels. It is important to resolve this controversy since the competition between project...

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In this work, we demonstrate that high solid-state conductivities of simply spin-coated poly­(3-hexylthiophene) (P3HT) films can be obtained by means of an ex situ electrochemical doping strategy using 4-line electrodes. With increasing electrochemical doping potential, we find an increase in conductivity over 6 orders of magnitude, giving a maximum conductivity up to 224 S cm–1 with maximum hole densities of 1021 holes per cm3. Most intriguingly, highly conducting states are achieved over a very broad potential range from 0.4 to 0.8 V versus Fc/Fc+ in the doped state. The experiments are complemented by UV–vis–NIR absorption and electron paramagnetic resonance spectroscopy in the solid state as well as with in situ electrochemical measurements which confirm that the electrochemically generated doped species can be successfully transferred into the solid state. Our results suggest that for reaching high conducting states, P3HT has to be present in different redox states and that the plateau conductivity region should arise from the coexistence of overlapping polaron and bipolaron states. Comparisons to films of regiorandom P3HT and pure redox polymer systems based on diphenyl-3,3′-bicarbazyl are further presented, which highlight the role of mixed valence states in conducting polymers. Last but not least, the highly conducting films are simply spin-coated and therefore rather disordered, adding new aspects to the discussion whether high crystallinity is a prerequisite for achieving high conductivities in conjugated polymers.

The magnetic properties of the title complexes were studied by EPR spectroscopy, magnetometry and ab initio calculations.

Electron paramagnetic resonance (EPR) is a powerful technique to investigate the electronic and magnetic properties of a wide range of materials. We present the first combined terahertz (THz) field and frequency domain electron paramagnetic resonance (HFEPR/FDMR) spectrometer designed to investigate the electronic structure and magnetic properties of molecular systems, thin films and solid state materials in a very broad frequency range of 85-1100 GHz. In this paper, we show high resolution frequency-field (Zeeman) maps (170-380 GHz by 0-15 T) recorded on two single-molecule magnets, [Mn2(saltmen)2(ReO4)2] and [Mn2(salpn)2(H2O)2](ClO4)2, which give direct access to the field-dependence of the energy level diagram. Furthermore, supression of standing waves in the described system and the sensitivity in field and frequency domain operations is evaluated and discussed.