The article describes the technologies of recycling polyester–glass waste and the influence of manufacturing technology on the properties of layered composites with polyester–glass recyclate additive. Milled polyester–glass waste was used as the recyclate. Polyester–glass composites with a specific content of recyclate were manufactured by means of manual laminating and vacuum bagging. The influence of the recyclate content and manufacturing method on the mechanical properties of composites was determined with the aid of specimens exposed to static tensile testing. Test results indicated that the composite without recyclate additive manufactured by means of vacuum bagging exhibits higher strength properties than the same composite manufactured by means of manual laminating. Additionally, its plasticity is much higher than that of the composite manufactured by means of manual laminating. The tests indicated that the tensile properties of the composite are, essentially, influenced by the content of recyclate (apart from the manufacturing method). Adding recyclate to the manufactured composite in the amount of 10% and 20% causes a significant decrease in its tensile properties in relation to the composite without the recyclate.
The modification of carbon fibers for improving adhesion between fibers and an epoxy resin in composite materials has become the focus of attention. In this work the carbon fiber coating process has been devised in a way preventing the stiffening and clumping of fibers. To improve interactions between coated fibers and a resin in composites, four types of silica coatings with different organic functional groups (3-aminopropyl–coating 1, 3-mercaptopropyl–coating 2, 2-(3,4-epoxycyclohexyl) ethyl–coating 3, methyl–coating 4) were obtained. Scanning electron microscopy (SEM) and atomic force microscopy (AFM) were used to distinguish the changes of a carbon fibers surface after coating deposition. The thickness of the obtained coatings, including the diversity of thickness, was determined by transmission electron microscopy (TEM). The increase in surface free energy (SFE) of modified fibers, including the distinction between the polar and dispersive parts, was examined by wettability measurements using a tensometric test. The developed coating preparation process allowed to cover fibers separately with nanoscale silica layers, which changed their morphology. The introduction of organic functional groups resulted in surface free energy changes, especially an increase in specific polar surface energy components.
Although cooling at ambient temperature is widely used and is said to be safe and convenient, faster cooling may have an influence not only on the time of the manufacturing process but also on the mechanical response, especially the residual stress. The study aimed to investigate the influence of the cooling rate after curing on the mechanical response of filament-wound thick-walled carbon fiber reinforced polymer (CFRP) rings. Three cooling rates were taking into consideration: cooling with the oven, at room temperature, and in the water at 20 °C. The splitting method was used to examine the residual strains. In the radial compression test, the mechanical response was investigated between the rings with different cooling regimes. The FEM analysis of the compression test in elastic range was also performed. Both the splitting method and the radial compression test showed no significant difference in the mechanical response of the CFRP rings. The presented results showed that the fast-cooling rate slightly decreases the mechanical performance of the filament-wound rings.
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