A denitrification mathematical model was used to describe the nitrates and organic carbons use by the denitrify biomass in the Moving Bed Biofilm Reactor (MBBR). The model integrates the diffusive mass transfer mechanism as well as double substrates Monod kinetics. Preliminary experiments were realized in order to assess the operating conditions for growth of attached biomass, the determination of the optimal (COD/NO3-N) ratio, moreover the results of the previous study of the residence time distribution in this MBBR established the optimal hydrodynamic operating conditions with a dead volume of 22%. In this reactor, seeded with a mixed liquor from a purification station, kaldnesk1 were used as carriers. A total of 6 kinetic and stoichiometric constants under anoxic conditions were determined by batch-test pulsed respirometry; some parametric have been determined experimentally, such as YHD, YNO,
μ
ˆ
HD
${\widehat{\mu }}_{\text{HD}}$
and KS, and with their values 0.4 mgCOD (mgCOD)−1, 0.6 mg COD (mgCOD)−1,0.864 d−1 and 12.48 mg COD L −1, respectively. The other constants were determined using the model fitting (using MATLAB), such as KNO3 and bHD with its values, 0.25 mg NO3-N. L−1 and 0.061 d−1, respectively. The model was used to simulated different operating condition and the results included the concentration profiles of NO3-N, COD and XBH, which showed good agreement with the experimental ones, mainly by using the effective volume determined experimentally in the hydrodynamic study (RTD test) and which can reach 62% of the total volume under some operating. Additionally, these findings demonstrate that moving bed reactor characterization may be accomplished using in situ pulsed respirometry (MBBR).
A massive use of nitrogen based fertilizers in agriculture is worldwide one of the main causes for nitrate contamination of groundwater. Methods for removing nitrate from aquatic environment through physical and/or chemical processes often turn out to be not applicable because of unaffordable financial resource as well as essential infrastructure lack. On the other hand, biological processes seem to have potentiality to overcome these limitations since they are less expensive and easier to be performed. Accordingly, in the present work, a moving bed biofilm reactor (MBBR) filled with Kaldnes K1 as carrier media was used to remove nitrate from a synthetic groundwater at bench scale. Acetate was used as organic source. Different operational conditions were tested: influent nitrate concentrations of 30, 40, 50 and 60 mg/L; hydraulic retention times of 24, 18, 12 and 8 h; and COD/NO3-N mass ratios of 3.00 and 2.98. Experimental results showed that NO3-N = 60 mg L−1, HRT = 8 h and COD/NO3-N ratio = 2.98 were the optimal operating conditions that allowed achieving a NO3-N removal by 99 % and a COD removal by almost 100 %. Moreover, almost no NO2
−-N accumulation and null COD concentration were observed at the optimal operating conditions. An activated carbon filter was placed downstream to remove residual organic compounds prior to disinfection unit, thus avoiding the potential formation of harmful disinfection by-products (e.g. trihalomethanes (THMs)). The MBBR was able to show a rapid recovery whenever the operating conditions were defined as more severe, thus proving that the operating conditions can vary over a wider range. Furthermore, the results showed that the MBBR system can be used effectively as a biological process to remove nitrate from groundwater.
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