Petrographic, geochemical and field studies in low grade metamorphic areas (Ciudad Rodrigo-HurdesSierra de Gata domain, CRHSG, central-western Spain) show that Neoproterozoic-Lowermost Cambrian series in the Central Iberian Zone (CIZ) record two kinds of provenance sources including: (1) detrital material derived from recycled orogens and (2) a Cadomian coeval juvenile contribution that governs their isotopic signature. Evidence of magmatism contemporaneous with Neoproterozoic-Cambrian sedimentation is provided by the presence of coherent, massive volcanic rocks (metabasalts, metaandesites, and metarhyolites), volcaniclastic shales, sandstones, conglomerates and breccias. The appearance of volcanogenic lithic fragments and crystals mixed in different proportions with siliciclastic constituents and also present within calcareous components in the sedimentary succession, reinforces this evidence. Although most of the selected volcanic and volcaniclastic samples appear to show tholeiitic affinity, some of them display calc-alkaline affinity. Different trace element ratios, such as Sm/Nd, Nb/Yb and Ta/Yb, suggest a magmatic evolution in the same tectonic setting. The geochemical results reported here support the existence of an active geodynamic setting as a direct contributor to the synsedimentary and magmatic content of the Neoproterozoic-Lowermost Cambrian successions in the CIZ. In particular, the relatively high Nd (T) values and the high range of f Sm/Nd ratios are consistent with an active margin during the Neoproterozoic-Early Cambrian. The existence of tectonic activity is also confirmed by the presence of synsedimentary deformation and volcanic rocks. All of these traits favour a geodynamic model in which the Iberian Cadomian segment represented in the CIZ would have been part of an active northern margin of Gondwana, with an associated magmatic arc and related basins during Neoproterozoic-Lower Cambrian times. A proposed link between the Ossa Morena and the Central Iberian Zones might account for late Cadomian pull-apart basins developed on both sides of the magmatic arc, sharing the same scenario and involving similar magmatic activity during the Neoproterozoic-Cambrian transition.
Cabo Ortegal is one of the major ultramafic complexes outcropping in Iberia. Most rocks are variably serpentinized, and the characteristics of the process can be traced through the composition of the rocks. The major and trace elements change in the different units of the complex. Together with the wide range of oxygen isotope values (d 18 O from 3.9 up to 6.6‰), these changes lead to the conclusion that several stages of serpentinization took place at Cabo Ortegal. Each stage is characterized by the composition of the fluid that produced the serpentinization. Seawater does not have to be the main fluid in the process; an ultimate stage of serpentinization can mask the characteristics of a previous one.
Many questions arise when considering the appropriate use of building stones such as serpentinites. The commercial names of these rocks, collectively grouped as 'Green marbles', have no correspondence to their actual mineralogy, geochemistry and/or physical characteristics. Serpentinite being the hydrated product of an ultramafic parent rock and not a metamorphic product of limestone as implied by the term 'marble'. However, the serpentinites most widely used for ornamental purposes come from India (e.g. Rajasthan Green, Emerald Green) and in these the original mineralogy has been almost completely converted into carbonates. By contrast, serpenfinites from elsewhere (e.g. Vermont Verde Antique from the USA and Verde Pirineos from Spain) do preserve some of their original mineralogy. The different physical and chemical behaviour of carbonates and serpentine minerals can result in significantly different behaviour of commercial building stones. Thus, carbonates are resistant to weathering but suffer from acidic cleaning agents in interior use; whereas serpentinites, with a high content of talc, used on external faces undergo an increase in volume and a consequent rapid degradation.Accurate and precise characterization of serpentinites, including information on their mineralogy and geochemistry (including major, trace and volatile elements together with oxygen isotopes), in conjunction with their physical properties, would enable architects to select the appropriate interior or exterior use of these handsome building stones.
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