NiS–NiS2/sludge-based biochar/GCE was fabricated by one-step potentiostatic electrodeposition on biochar and used as an interface material for non-enzymatic sensing of glucose with a lower detection limit of 1.5 μM.
Owing to its ubiquity in natural water systems and the high toxicity of its accumulation in the human body, it is essential to develop simple and low-cost electrochemical sensors for the determination of 3,3′,5,5′-tetrabromobisphenol A (TBBPA). In this work, Fe3O4–activated biochar, which is based on excess sludge, was prepared and characterized using scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), Fourier transform infrared spectroscopy (FTIR) and BET analysis to analyze its basic features. Subsequently, it was used to fabricate an electrochemical sensor for the detection of TBBPA. The electrochemical test results revealed that the Fe3O4–activated biochar film exhibited a larger active surface area, a lower charge transfer resistance and a higher accumulation efficiency toward TBBPA. Consequently, the peak current of TBBPA was significantly enhanced on the surface of the Fe3O4–activated biochar. The TBBPA sensing platform developed using the Fe3O4–activated biochar composite film, with relatively a lower detection limit (3.2 nM) and a wider linear range (5–1000 nM), was successfully utilized to determine TBBPA levels in water samples. In summary, the effective application of Fe3O4–activated biochar provided eco-friendly and sustainable materials for the development of a desirable high-sensitivity sensor for TBBPA detection.
Natural organic matters (NOMs) are ubiquitous in the environment, but few systematic studies have examined the influence of NOMs on the sorption ability of magnetic sludge biochar. In this study, magnetic sludge biochar was synthesized, characterized, and used as a sorbent to remove tetracycline (TC) from aqueous solutions. The effects of pH, humic acid (HA), and fulvic acid (FA) on TC adsorption by magnetic sludge biochar were studied using batch experiments. Adding HA and FA can alter the adsorption behavior of TC, except for its pH dependency. The results of this study show that relatively low concentrations of dissolved HA (≤8 ppm) and FA (≤5 ppm) promote the adsorption capacity of TC, but higher concentrations compete against TC for sorption sites on the surface of magnetic sludge biochar. The results of this study promote a better understanding of the application of magnetic sludge biochar in real antibiotic wastewater.
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