The superb mechanical and physical properties of individual carbon nanotubes (CNTs) have provided the impetus for researchers in developing high-performance continuous fibers based upon CNTs. The reported high specific strength, specific stiffness and electrical conductivity of CNT fibers demonstrate the potential of their wide application in many fields. In this review paper, we assess the state of the art advances in CNT-based continuous fibers in terms of their fabrication methods, characterization and modeling of mechanical and physical properties, and applications. The opportunities and challenges in CNT fiber research are also discussed.
Many species in nature have evolved remarkable strategies to visually adapt to the surroundings for the purpose of protection and predation. Similarly, acquiring the capabilities of adaptively camouflaging in the infrared (IR) spectrum has emerged as an intriguing but highly challenging technology in recent years. Here, we report adaptive thermal camouflage devices by bridging the optical and radiative properties of nanoscopic platinum (Pt) films and silver (Ag) electrodeposited Pt films. Specifically, these metal-based devices have large, uniform, and consistent IR tunabilities in mid-wave IR (MWIR) and long-wave IR (LWIR) atmospheric transmission windows (ATWs). Furthermore, these devices can be easily multiplexed, enlarged, applied to rough and flexible substrates, or colored, demonstrating their multiple adaptive camouflaging capabilities. We believe that this technology will be advantageous not only in various adaptive camouflage platforms but also in many thermal radiation management–related technologies.
Engineering the radiation characteristics for the design of selective thermal emitters has been a hot topic for decades and is of great value in the fields of thermophotovoltaic systems, radiative cooling, and infrared stealth. In this paper, a Ag/Ge multilayer film based selective emitter for infrared stealth is demonstrated using an ultrathin metal film and impedance matching to tune the radiation characteristics. Herein, a novel approach for infrared stealth that relies on the combination of emissivity (ε) reduction in the atmospheric windows (3–5 and 8–14 µm) and radiative cooling in a nonatmospheric window (5–8 µm) is proposed. The fabricated selective emitter has low emissivity (ε3‐5 µm = 0.18; ε8‐14 µm = 0.31) in the atmospheric windows for infrared “invisibility” and high emissivity (ε5‐8 µm = 0.82) outside the atmospheric window for radiative cooling and functions from ambient temperature to 200 °C. Compared with low‐emissivity materials, the selective emitter exhibits higher radiative cooling efficiency in vacuum and practical environments and presents lower apparent temperatures on infrared cameras. Moreover, the proposed selective emitter, with a planar and simple structure, is scalable, allowing flexible large‐area fabrication. The work demonstrates that selective emissive materials have promising applications in infrared stealth technology.
A stretchable fiber supercapacitor (SC) based on buckled MnO /oxidized carbon nanotube (CNT) fiber electrode is fabricated by a simple prestraining-then-buckling method. The prepared stretchable fiber SC has a specific volumetric capacitance up to 409.4 F cm , which is 33 times that of the pristine CNT fiber based SC, and shows the outstanding stability and repeatability in performance as a stretchable SC.
Carbon nanotube (CNT) based continuous fiber, a CNT assembly that could potentially retain the superb properties of individual CNTs on a macroscopic scale, belongs to a fascinating new class of electronic materials with potential applications in electronics, sensing, and conducting wires. Here, the fabrication of CNT fiber based stretchable conductors by a simple prestraining‐then‐buckling approach is reported. To enhance the interfacial bonding between the fibers and the poly(dimethylsiloxane) (PDMS) substrate and thus facilitate the buckling formation, CNT fibers are first coated with a thin layer of liquid PDMS before being transferred to the prestrained substrate. The CNT fibers are deformed into massive buckles, resulting from the compressive force generated upon releasing the fiber/substrate assembly from prestrain. This buckling shape is quite different from the sinusoidal shape observed previously in otherwise analogous systems. Similar experiments performed on carbon fiber/PDMS composite film, on the other hand, result in extensive fiber fracture due to the higher fiber flexural modulus. Furthermore, the CNT fiber/PDMS composite film shows very little variation in resistance (≈1%) under multiple stretching‐and‐releasing cycles up to a prestrain level of 40%, indicating the outstanding stability and repeatability in performance as stretchable conductors.
The tensile properties of carbon nanotube (CNT) fibers have been widely studied. However, the knowledge of their compressive properties is still lacking. In this work, the compressive properties of both pure CNT fibers and epoxy infiltrated CNT fibers were studied using the tensile recoil measurement. The compressive strengths were obtained as 416 and 573 MPa for pure CNT fibers and CNT-epoxy composite fibers, respectively. In addition, microscopic analysis of the fiber surface morphologies revealed that the principal recoil compressive failure mode of pure CNT fiber was kinking, while the CNT-epoxy composite fibers exhibited a failure mode in bending with combined tensile and compressive failure morphologies. The effect of resin infiltration on CNT fiber compressive properties, including the compressive strength and the deformation mode, is discussed. This work expands the knowledge base of the overall mechanical properties of CNT fibers, which are essential for their application in multifunctional composites.
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