In this study, different methods are compared in order to quantitate individual sugars extracted from apple samples using methanol and water. Glucose, fructose, and sucrose are separated in 20 min using an amino-bonded carbohydrate column and a 75:25 acetonitrile-water mobile phase, followed by UV (190 nm) and refractive index detection. Variations in the sugar profiles are observed using different extraction or detection methods (or both) at a 1.4-mL/min flow rate. The data obtained show differences (p < 0.01) from both extraction or detection methods. The highest contents of free sugars studied occur in samples extracted with water.
We investigated potential effects of the fish farms on water column and sediment around Salih Island in the Gulluk Bay (Aegean Sea, Turkey) where four seasonal samplings were performed from October 2001 to August 2002. One measured physicochemical variables in water column including dissolved oxygen, nutrients (nitrite, nitrate, ammonium, phosphate and silicate), particulate organic carbon (POC) and chlorophyll a. Organic matter, total organic carbon (TOC) and heavy metals (Zn, Cu and Fe) were measured in sediment samples. Although occasional increases in ammonium and chlorophyll a concentrations were observed at the cage stations as compared to the control one, no statistically significant differences were detected among the stations in terms of nutrients, chlorophyll a and POC. On the other hand, significant differences were found in organic matter, TOC and heavy metals (Zn and Fe) of the sediments among the sampling stations. Despite these differences, our results indicate that concentrations of physicochemical variables and heavy metals were within the range of tolerable levels for the marine ecosystem, and the oligotrophic nature of the water column in the study area was able to assimilate organic and inorganic loads caused by the fish farms.
Total mass transfer coefficients of soluble solids (SS) and total phenolic compounds (TPC) were determined during carob extraction. The Arrhenius equation was applied to determine the efficiency of process temperature, as an alternative approach to Fick's second law. Carob pod, cut into small pieces (internal diameter: 5–7 mm), was contacted with water in batch system to extract SS by continuous circulation of water at different temperatures (20, 50 and 85C). The process was also performed at 85C using an industrial‐scale extractor. Activation energies for both SS and TPC diffusions were calculated as 5.84 and 0.072 × 10−3 kJ/mol, respectively. As expected, higher extract concentrations were achieved with higher temperatures. In contrast, high extraction temperature, even at 85C, did not cause hydroxymethylfurfural (HMF) formation. As the increase in temperature does not affect formation of HMF during carob pod extraction, higher operational temperatures such as 80–90C may be applied to obtain higher solute concentrations.
Ascorbic acid loss in thermally treated rose hip pulp was modeled mathematically. Isothermal experiments in the temperature range of 70-95C were utilized to determine the kinetics of ascorbic acid loss in the pulp during heating under anaerobic circumstances. Changes in ascorbic acid decomposition followed a first-order reaction. Temperature dependence of the rate constant during thermal processing of rose hip pulp obeyed the Arrhenius relationship with an activation energy of 47.5 kJ/mole.
Capture-based aquaculture of Atlantic bluefin tuna in the Mediterranean has been expanding rapidly but little is known about its environmental impact. In order to understand the consequences of this new sector, long-term monitoring is needed. For this purpose, we investigated the impact of a capture-based tuna farm located in the Gerence Bay (Aegean Sea) on the water column on a seasonal basis from 2005 to 2008, where in the water column, temperature, salinity, pH, dissolved oxygen, nutrients (nitrite, nitrate, ammonium, and phosphate), and chlorophyll a, in the sediment organic carbon variables were measured. Although highest nutrient concentrations were observed at the cage station as compared to the two controls in the production period, differences were not statistically significant between stations. Monitoring of physico-chemical parameters, nutrients, and chlorophyll a in water column together with organic carbon in sediment did not show detectable impact of fattening of Atlantic bluefin tuna. This was probably caused by strong currents present in the area, location of the cages away from the coast, hence high water depth, controlled feeding, and periodic presence of tuna farming activity in the study area.
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