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Submicron Raman spectroscopy mapping is able to unambiguously distinguish the main serpentine minerals within their in situ microstructural context. The high spatial resolution (~370 nm), large‐area coverage (up to hundreds of micrometres in each dimension), and ability to map directly on polished thin sections allows novel interpretations to be made regarding the nature and evolution of serpentinite fault rock textures. The potential of this method is illustrated by examining submicron‐scale textures of scaly serpentinites (e.g., dissolution seams, mineral growth in pressure shadows, distribution, and intergrowth of serpentine minerals) from a lithospheric‐scale shear zone in New Zealand and a subduction‐related serpentinite body in California, USA.

Serpentinites play a key role in controlling fault rheology in a wide range of geodynamic settings, from oceanic and continental rift zones to subduction zones. In this paper, we provide a summary of the most common deformation mechanisms and frictional strengths of serpentine minerals and serpentinites. We focus on deformation mechanisms in retrograde serpentinites, which show a progressive evolution from undeformed mesh and bastite pseudomorphic textures to foliated, ribbon-like textures formed by lizardite with strong crystallographic and shape preferred orientations. We also discuss the possible mechanical significance of anastomosing slickenfibre veins containing ultraweak fibrous serpentines or relatively strong splintery antigorite. Our review and new observations indicate that pressure solution and frictional sliding are the most important deformation mechanisms in retrograde serpentinite, and that they are frictionally weak (µ~0.3). The mineralogical and microstructural evolution of retrograde serpentinites during shearing suggests that a further reduction of the friction coefficient to µ of 0.15 or less may occur during deformation, resulting in a sort of continuous feedback weakening mechanism.

Positively identifying serpentine mineral types is important for a wide range of disciplines in the Earth sciences and health sciences. Although Raman spectroscopy has been widely applied as a tool to distinguish four of the main serpentine minerals (i.e., antigorite, lizardite, chrysotile, and polygonal serpentine), some uncertainty remains as to whether all four varieties have unique Raman spectra. In this paper, submicron Raman spectroscopy mapping was performed directly on electron‐transparent regions of serpentine samples that were unambiguously identified by transmission electron microscopy (TEM). The increased spatial resolution of the Raman mapping technique (~370 nm), combined with the detailed characterization provided by TEM, indicates that polygonal serpentine has the same Raman spectrum as lizardite and therefore cannot be spectrally distinguished from lizardite. Furthermore, the Raman spectral profile that has previously been reported as unique to polygonal serpentine is likely to represent a mixture of chrysotile and polygonal serpentine/lizardite. To positively discriminate between lizardite and polygonal serpentine requires TEM investigation.

Recent earthquakes have demonstrated that rupture may propagate through geometrically complex networks of faults. Ancient exhumed faults have the potential to reveal the details of complex rupture at seismogenic depths. We present a new set of field observational criteria for determining which of a population of pseudotachylyte fault veins formed in the same earthquake and apply it to map rupture networks representing single earthquakes. An exceptional exposure of an exhumed ancient strand of the Norumbega Shear Zone preserves evidence of multistranded earthquake rupture in the deep seismogenic zone of a continental transform fault. Individual fault strands slipped at least 2–18 cm, so significant slip is represented by each rupture network. Our data show that synchronously slipped faults intersect at angles of 0 to ∼55°, with the opening angles of fault intersections directed toward the dilational quadrants for dextral slip. Multistranded rupture on a fault network instead of rupture of a single fault may result in greater and/or more variable slip and cause slip rake to vary spatially and temporally. Slip on intersecting faults unequivocally means that there will be motion perpendicular to the average fault plane. Modern earthquakes displaying non‐double‐couple components to focal mechanism solutions and spatially varying rake, slip, and anomalous stress drop may be explained by rupture across fault networks that are too close (spatially and temporally) to be resolved seismically as separate events.

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Laboratory experiments on serpentinite suggest that extreme dynamic weakening at earthquake slip rates is accompanied by amorphisation, dehydration and possible melting. However, hypotheses arising from experiments remain untested in nature, because earthquake ruptures have not previously been recognised in serpentinite shear zones. Here we document the progressive formation of high-temperature reaction products that formed by coseismic amorphisation and dehydration in a plate boundary-scale serpentinite shear zone. The highest-temperature products are aggregates of nanocrystalline olivine and enstatite, indicating minimum peak coseismic temperatures of ca. 925 ± 60 °C. Modelling suggests that frictional heating during earthquakes of magnitude 2.7–4 can satisfy the petrological constraints on the coseismic temperature profile, assuming that coseismic fluid storage capacity and permeability are increased by the development of reaction-enhanced porosity. Our results indicate that earthquake ruptures can propagate through serpentinite shear zones, and that the signatures of transient frictional heating can be preserved in the fault rock record.

Abstract. Deciphering the internal structural and composition of large serpentinite-dominated shear zones will lead to an improved understanding of the rheology of the lithosphere in a range of tectonic settings. The Livingstone Fault in New Zealand is a > 1000 km long terrane-bounding structure that separates the basal portions (peridotite; serpentinised peridotite; metagabbros) of the Dun Mountain Ophiolite Belt from quartzofeldspathic schists of the Caples or Aspiring Terranes. Field and microstructural observations from eleven localities along a strike length of c. 140 km show that the Livingstone Fault is a steeply-dipping, serpentinite-dominated shear zone tens to several hundreds of metres wide. The bulk shear zone has a pervasive scaly fabric that wraps around fractured and faulted pods of massive serpentinite, rodingite and partially metasomatised quartzofeldspathic schist up to a few tens of metres long. S-C fabrics and lineations in the shear zone consistently indicate a steep Caples-side-up (i.e. east-side-up) shear sense, with significant local dispersion in kinematics where the shear zone fabrics wrap around pods. The scaly fabric is dominated (> 98 vol %) by fine-grained (≪ 10 μm) fibrous chrysotile and lizardite/polygonal serpentine, but infrequent (