Determining which petrological processes build the mantle-crust dunitic transition zone (DTZ) in oceanic spreading settings has a direct impact on our understanding of thermal and chemical transfers on Earth. We report on understated but widespread mineral assemblages present in the DTZ at the top of a mantle diapir (Oman ophiolite), including pargasite, grossular, and pyroxenes of peculiar composition. These minerals are present interstitially between olivines and as inclusions in the disseminated chromite grains, indicating that they are early, high-temperature features. They call for hybridization between the mid-oceanic ridge basalt melts that fed the crustal section and supercritical water saturated with silica. Our synoptic survey (~300 samples collected along 12 cross sections) demonstrates that the DTZ was pervasively infiltrated by such hybrid melts and that the abundance of their crystallization products increases upsection,

On Earth, most of the critical processes happen at the frontiers between envelopes and especially at the Moho between the mantle and the crust. Beneath oceanic spreading centres, the dunitic transition zone (DTZ) appears as a major interface between the upwelling and partially molten peridotitic mantle and the accreting gabbroic lower crust. Better constraints on the processes taking part in the DTZ allows improved understanding of the interactions between silicate melts and hydrated fluids, which act competitively to generate the petrological Moho. Here we combine mineral and whole rock major and trace element data with a structural approach along three cross-sections up to 300 m thick above the fossil Maqsad mantle diapir (Oman ophiolite) in order to understand the vertical organization of the DTZ with depth. Our results highlight that most of the faults or fractures cross-cutting the DTZ were ridge-related and active at an early, high temperature magmatic stage. Chemical variations along the cross-sections define trends with a characteristic vertical scale of few tens *Manuscript EPSL-D-18-00894R3 Click here to view linked References of meters. There is a clear correlation between the chemical variation pattern and the distribution of fault zones, not only for fluid-mobile elements but also for immobile elements such as REE and HFSE. Faults, despite displaying very limited displacements, enhanced both melt migration and extraction up to the crust and deep hydrothermal fluids introduction down to the Moho level. We propose that these faults are a vector for upwelling melt modification by hybridization, with hydrothermal fluids and/or silicic hydrous melts, and crystallization. Infiltration of these melts or fluids in the country rock governs part of the gradational evolutions recorded in composition of both the olivine matrix and interstitial phases away from faults. Finally, these faults likely control the thermal structure of the mantle-crust transition as evidenced by the spatial distribution of the crystallization products from percolating melts, organizing the transition zone into pure dunites to impregnated dunites horizons. In this context, the DTZ appears as a reactive interface that developed by the combination of three primary processes: tectonics, magmatism and deep, high temperature hydrothermal circulations. Accordingly, these features fundamentally contribute to the variable petrological and geochemical organization of the DTZ and possibly of the lower crust below oceanic spreading centers, and may be a clue to interpret part the heterogeneity observed in MORB signatures worldwide.

The Maqsad area in the Oman ophiolite exposes a >300 m thick dunitic mantle-crust transition zone (DTZ) that developed above a mantle diapir. The Maqsad DTZ is primarily f "p " w h scattered chromite and chromite seams) and " p g " which exhibit a significant lithological variability, including various kinds of clinopyroxene-, plagioclase-, orthopyroxene-, amphibole (hornblende/pargasite)bearing dunites. These minerals are interstitial between olivine grains and their variable abundance and distribution suggest that they crystallized from a percolating melt. Generally studied through in-situ mineral characterization, the whole rock composition of dunites is poorly documented. This study reports on whole rock and minerals major and trace element *Manuscript contents on 79 pure to variably impregnated dunites collected systematically along cross sections from the base to the top of the DTZ. In spite of its high degree of depletion, the olivine matrix is selectively enriched in the most incompatible trace elements such as LREE, HFSE, Th, U, Rb and Ba. These data support the view that this enrichment has been acquired early in the magmatic evolution of the DTZ, during the dunitization process itself. The dissolution of orthopyroxene from mantle harzburgites enhanced by the involvement of hydrothermal fluids produced low amounts of melts enriched in silica and in some trace elements that re-equilibrated with the olivine matrix. This pristine signature of the DTZ dunite was eventually variably altered by percolation of melts with a Mid-Ocean Ridge Basalt (MORB) affinity but displaying a wide spectrum of composition attributable to evolution by fractional crystallization and hybridization with the silica enriched, hydrated melts. The olivine matrix has been partially or fully re-equilibrated with these melts, smoothing the early strong concave-upward REE pattern in dunite. The chemical variability in the interstitial minerals bears witness of the percolation of MORB, issued from the mantle decompression melting, variably hybridized with melt batches produced within the DTZ by melt-rock reaction and poorly homogenized before reaching the lower crust. Our results lead to the conclusion that pure and impregnated dunites are end-members that recorded different stages of the same initial igneous processes: pure dunites are residues left after extraction of a percolating melt while impregnated dunites correspond to a stage frozen before complete melt extraction. Therefore dunites trace elements contents allow deciphering the multi-stage processes that led to their formation at the mantle-crust transition zone. Keywords Oman ophiolite; dunitic mantle-crust transition zone; trace elements; melt-rock reactions; melt percolation; refertilization 1995a; Kelemen et al., 1997b). In this way, the DTZ appears to be a reactive interface where melts are focused, transformed and potentially accumulated, then distributed beneath the midocean ridge. Crystallization associated to melt migration through the mantle-crust transition zone accou...

The evolution of the seawater oxygen isotopic composition (δ18O) through geological time remains controversial. Yet, the past δ18Oseawater is key to assess past seawater temperatures, providing insights into past climate change and life evolution. Here we provide a new and unprecedentedly precise δ18O value of −1.33 ± 0.98‰ for the Neoproterozoic bottom seawater supporting a constant oxygen isotope composition through time. We demonstrate that the Aït Ahmane ultramafic unit of the ca. 760 Ma Bou Azzer ophiolite (Morocco) host a fossil black smoker-type hydrothermal system. In this system we analyzed an untapped archive for the ocean oxygen isotopic composition consisting in pure magnetite veins directly precipitated from a Neoproterozoic seawater-derived fluid. Our results suggest that, while δ18Oseawater and submarine hydrothermal processes were likely similar to present day, Neoproterozoic oceans were 15–30 °C warmer on the eve of the Sturtian glaciation and the major life diversification that followed.

A stratiform chromite ore body crops out in the lower part of the dunitic mantle-crust transition zone (DTZ) that developed at the top of a mantle diapir in the Maqsad area in the Oman ophiolite. It is made of layers ranging in thickness from a few mm to a maximum of 3 m, and in modal composition from massive to antinodular and disseminated ore. The ore body is about 50 m thick and its lateral extent does not exceed several hundred meters. The layering dips gently to the southeast, parallel to that of the overlying gabbroic cumulates. The chromite composition is typical of a MORB kindred-moderate XCr (100 × Cr/(Cr + Al) atomic ratio), ranging from 48 to 60, and relatively high TiO 2 content, ranging from about 0.3 to 0.5 wt%-, a characteristic shared by most lithologies issued from the igneous activity of the Maqsad diapir. The silicate matrix is essentially made of slightly serpentinized olivine with minor clinopyroxene and rare pargasitic amphibole, orthopyroxene and garnet. This strongly contrasts with the nature of the mineral inclusions mostly made of the assemblage amphibole-orthopyroxene-mica, enclosed in the chromite grains and represented in abundance all along the ore body whatever the ore grade. The inclusions demonstrate the involvement of a silica-and water-rich melt and/or fluid, in addition to MORB, in the early stages of chromite crystallization. The chemical composition of chromite, silicate matrix, together with the one of silicate inclusions display well-defined evolutions vertically along the stratiform chromitite. At the scale of the ore body, the compositional trends are independent of the ore concentration but the major kinks in these trends are well-correlated with levels of magmatic breccias. This shows that abrupt chemical changes can be attributed to sudden melt +/-fluids injection events followed mainly by melt-fluid-rock interaction and in a lesser extent by quieter evolution by fractional crystallization. At the thin section scale, second order chemical variations, essentially in the Mg# (100 × Mg/(Mg + Fe 2+) atomic ratio) of chromite and Fo of olivine, are clearly attributable to re-equilibration between these two solid phases, possibly in the presence of an interstitial melt/fluid.

A procedure is described for the determination of thirty‐seven minor and trace elements (LILE, REE, HFSE, U, Th, Pb, transition elements and Ga) in ultramafic rocks. After Tm addition and acid sample digestion, compositions were determined both following a direct digestion/dilution method (without element separation) and after a preconcentration procedure using a double coprecipitation process. Four ultramafic reference materials were investigated to test and validate our procedure (UB‐N, MGL‐GAS [GeoPT12], JP‐1 and DTS‐2B). Results obtained following the preconcentration procedure are in good agreement with previously published work on REE, HFSE, U, Th, Pb and some of the transition elements (Sc, Ti, V). This procedure has two major advantages: (a) it avoids any matrix effect resulting from the high Mg content of peridotite, and (b) it allows the preconcentration of a larger trace element set than with previous methods. Other elements (LILE, other transition elements Cr, Mn, Co, Ni, Cu, Zn, as well as Ga) were not fully coprecipitated with the preconcentration method and could only be accurately determined through the direct digestion/dilution method.

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We analyzed high-quality seismic reflection profiles across the ocean-continent transition in the Enderby Basin between the Kerguelen Plateau and the Antarctic margin. There, we observe numerous high-amplitude dipping reflections in the lower oceanic crust which was accreted at a magmatic spreading center as testified by the almost uniform 6.4-7 km thick crust and its unfaulted, flat top basement. The deep reflections are rooting onto the Moho and are dipping both ridgeward and continentward. They occur in dense networks in mature oceanic crust as well as close to the continentward termination of oceanic crust and in the oceancontinent transition zone. The comparison with field observations in the Oman ophiolite suggests that these lower crustal dipping reflectors could correspond to syn-magmatic faults. In Oman, very high temperature (up to syn-magmatic), high temperature (sub-solidus plastic deformation) and low temperature (brittle) deformation coexist along the same fault over distances of a few hundred meters at Moho level. This very high temperature gradient may be explained by the sudden and intense interaction between crystallizing magmas and hydrothermal fluids induced by the episodic nucleation of faults in a context of continuous magmatic spreading. The igneous layering becomes extremely irregular compared to its monotonous sub-horizontal orientation away from the faults which, together with enhanced hydrothermal alteration restricted to the fault zones, might change the physical properties (velocity, density) and increase the reflectivity of syn-magmatic faults. We further speculate that these processes could explain the brightness of the lower crustal dipping reflectors observed in our seismic reflection data. Both the seismic reflection profiles of the Enderby Basin and the Oman ophiolite show evidence for syn-accretion tectonism at depth together with the systematic rotation of originally horizontal lava flows or originally vertical dikes, predating cessation of magmatic activity. This indicates ubiquitous deformation processes within the axial zone of magmatic spreading centers.