The eucritic meteorites are basaltic rocks that originate from the upper part of the crust of some small bodies as exemplified possibly by asteroid 4-Vesta. A few eucrites appear to have been modified by different degrees of a late stage alteration process that caused significant variations in mineralogy. Three distinct alteration stages are identified: (1) Fe-enrichment along the cracks that cross cut the pyroxene crystals ("Fe-metasomatism"); secondary olivine and minute amounts of troilite are found only occasionally in cracks at this stage; (2) deposits of Fe-rich olivine (Fa 64-86 ) and minor amounts of troilite are frequent inside the cracks; sporadic secondary Ca-rich plagioclase (An 97-98 ) is associated with the fayalitic olivine; (3) at this stage, the Fe-enrichment of the pyroxene is accompanied by a marked Al-depletion; moreover, secondary Ca-rich plagioclase is more frequent and partly fills some cracks or rims of the primary plagioclase crystals. The composition of the secondary phases on one hand, the lack of incompatible trace element enrichment in the metasomatized pyroxenes on the other hand, rule out a silicate melt as the metasomatic agent. Although no hydrous phase has been yet identified in the studied samples, aqueous fluids are plausible candidates for explaining the deposits of ferroan olivine and anorthitic plagioclase inside the fractures of the studied unequilibrated eucrites.
[1] A regional survey of alkaline springs in Oman and Ligurian ophiolites shows that the alkaline water compositions significantly vary from one ophiolite to the other and within the same ophiolite. The firstorder correlation between the Na (and K) and Cl concentrations points to fluid compositions only partly due to evaporation. The scatter around the evaporation line implies that Na and Cl may not be conservative during the alteration of the ultramafic rocks. Mg is almost entirely depleted at pH > 10.5 as a result of serpentine formation within the ultramafic body and of brucite (and minor hydrotalcite) precipitation at the springs. Ca accumulates in the high-pH fluids and is consumed by Ca-carbonate formation at the springs, by mixing with river waters or by the CO 2 supply from the atmosphere. Thermodynamic calculations show that brucite saturation is reached at pH values around 10.5 which triggers major changes in the water composition. The waters evolve from a quartz-saturated low-pH continental environment to a brucitedominated high-pH serpentinizing system at low temperature. The highest water salinities are found in springs located along the basal thrust plane of the ophiolite. The highest Al concentrations are found in some springs located on the crustal side of the mantle/crust boundary. This poses the question of the hydrologic pathways and of the role of the mineralogical composition of the altered formations.
Three-quarters of the ocean crust formed at fast-spreading ridges is composed of plutonic rocks whose mineral assemblages, textures and compositions record the history of melt transport and crystallization between the mantle and the seafloor.Despite the significance of these rocks, sampling them in situ is extremely challenging due to the overlying dikes and lavas. This means that our models for
[1] We conducted a comprehensive field, petrographic, and microprobe study of the dykes and porous flow channels cropping out in the Oman harzburgites. The 36 rock types we recognized among of about 1000 samples can be grouped in two main magma suites contrasted in terms of structural and textural characteristics, modal composition, order of crystallization, and phase chemistry. One suite (troctolites, olivine gabbros, opx-poor gabbronorites, and rare oxyde gabbros) derives from MORB-like melts. The other suite (pyroxenites, opx-rich gabbronorites, diorites, and tonalite-trondhjemites) derives from melts richer in silica and water than MORBs and ultradepleted in incompatible elements. Dykes and porous flow channels from the MORB suite are restricted to a few areas, covering only 25% of the mantle section. This is an unexpected result as the deep Oman crust is made essentially of cumulates from MORB-like melts. Their composition, texture, and relations with the host harzburgites point to high mantle temperatures at the time of crystallization (likely above 1100°C, up to 1200°C for part of them), i.e., conditions close to the ''asthenosphere/lithosphere'' boundary. The largest outcrop of mantle harzburgites enclosing MORB like dykes is a 80 km long and 10 km wide corridor, parallel to the strike of the sheeted dyke complex and centered on an area where a former mantle upwelling has been unambiguously defined (the Maqsad ''diapir''). A few other occurrences of mantle cumulates from the MORB suite are smaller than the Maqsad area and have a lesser abundance of troctolites (i.e., of high-temperature cumulates). We interpret the troctolite zones of Oman as the witnesses of former diapirs frozen at various stages of their development. Dykes belonging to the depleted suite are the most common in Oman harzburgites. Their structural and textural characteristics show that they crystallized in a mantle colder than the melt (likely in the range 600°C to 1100°C). A possible origin for the parent melts of this suite is in situ partial melting of the shallow and partly hydrated lithosphere residual after MORB extraction. Our data support the view that feeding magma chambers with MORBs is a focused (and likely episodic) process involving the rise of hot mantle to the base of the crust through a lithospheric lid accreted during a previous diapiric event. They suggest also that the shallow mantle beneath spreading centers is a place of important petrologic processes, some of them predicted on the basis of MORB composition (e.g., fractionation inside melt conduits) and other ones unexpected (e.g., remelting of the depleted lithosphere).
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