This work aimed to develop a facile and broadly applicable method for fabricating multistimuli responsive triple-shape memory polymers (SMPs). Hence, herein the SMPs were prepared through the simple physical blending of two commercially available biopolymers, poly(lactic acid) (PLA) and poly(vinyl acetate) (PVAc), in the presence of robust and conductive graphene nanoplatelets. Interestingly, atomic force microscopy observations and thermal analyses revealed that the presence of nanofillers led to phase separation and appearance of two well-separated transition temperatures in the blend of these two miscible polymers. Consequently, shape memory results showed that the unfilled blend of PLA/PVAc with a single thermal transition can only show moderate heat triggered dual-shape memory behavior. While, PLA/PVAc/graphene nanocomposite blends demonstrated excellent thermally and electrically actuated triple-shape memory effects besides their remarkable dual-shape memory behavior. In addition, electrical conductivity of the blend was enhanced by ∼14 orders of magnitude in the presence of graphene. More interestingly, electroactive shape recovery experiments exhibited that depending on the applied voltage, temporary shapes in each region of sample can be either individually or simultaneously recovered.
The conventional covalently cross-linked double network (DN) hydrogels with high stiffness often show low toughness and self-healing property due to the irreversible bond breakages in their networks. Therefore, scarcity of hydrogels that possess simultaneous features of stiffness, toughness, and autonomous self-healing properties at the same time remains a great challenge and seriously limits their biomedical applications. While, many natural materials acquire these features from their dynamic sacrificial bonds. Inspired by biomaterials, herein we propose a novel strategy to design stiff, tough and self-healing DN gels by substitution of both covalently cross-linked networks with strong, dynamic hydrogen bond cross-linked networks. The prepared fully physically cross-linked DN gels composed of strong agar biopolymer gel as the first network and tough polyvinyl alcohol (PVA) biopolymer gel as the second network. The DN gels demonstrated multiple-energy dissipating mechanisms with a high modulus up to 2200kPa, toughness up to 2111kJm, and ability to self-heal quickly and autonomously with regaining 67% of original strength only after 10min. The developed DN gels will open a new avenue to hydrogel research and holds high potential for diverse biomedical applications, such as scaffold, cartilage, tendon and muscle.
Here strong electroactive shape memory nanocomposites were prepared by incorporating graphene nanoplatelets into poly(vinyl acetate) (PVAc) through the simple solvent mixing method. TEM and XRD revealed that well exfoliated graphene nanoplatelets formed a continuous network throughout the matrix with a large amount of interconnectedness. Dynamic mechanical analysis showed that the inclusion of graphene significantly improves both glassy and rubbery moduli of the matrix. Furthermore, the prepared nanocomposites demonstrated a marked electrical conductivity up to 24.7 S m −1 and thereby surprisingly rapid electrical actuation behaviour exhibiting a 100% recovery ratio in 2.5 s. Moreover, PVAc and its nanocomposites displayed scratch self-healing capability. This work demonstrates that the PVAc/graphene nanocomposites with high modulus and excellent electroactive shape memory performance can be a promising material in many applications such as sensors and fast deployable and actuating devices.
Self-healability performanceThe self-healability of PVAc and its nanocomposite (PVAc/Gr4.5) was qualitatively evaluated by optical microscope observations. Polym Int 2017; 66: 665-671
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