In Fig. 3 and its inset the vertical scales should be reduced by a factor of 4. This plotting error affects only the figure. All relevant quantities in the text and in the table are correct as published. We regret the oversight.The corrected version of Fig. 3 is reproduced here. This correction does not affect any results or conclusions of the published paper.FIG. 3. Inclusive ÿ ; K spectrum on Si at K 6 2 . The curves are the calculated spectra for the repulsive (solid) and shallow (dashed) -nucleus potentials, fitted to the measured spectrum. A value of the scaling factor and 2 per degree of freedom are shown for each fitting.

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A synthesis of 1,1-disubstituted 1,2,3,4-tetrahydroisoquinolines (6) was achieved in a highly efficient manner via Pictet-Spengler reaction of arylethylamines (1) and acyclic and cyclic ketones (2) using titanium (IV) isopropoxide and acetic-formic anhydride. The cyclization of the in situ formed acyliminium ion (4) to N-formyl 1,2,3,4-tetrahydroisoquinoline (5) was greatly facilitated by using trifluoroacetic acid as an additional reagent. The Pictet-Spengler reaction was carried out by one pot procedure, providing a convenient and effective method for preparing various 1,2,3,4-tetrahydroisoquinolines.

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