Recent advances in in situ transmission electron microscopy (TEM) techniques have provided unprecedented knowledge of chemical reactions from a microscopic viewpoint. To introduce volatile liquids, in which chemical reactions take place, use of sophisticated tailor-made fluid cells is a usual method. Herein, a very simple method is presented, which takes advantage of nonvolatile ionic liquids without any fluid cell. This method is successfully employed to investigate the essential steps in the generation of gold nanoparticles as well as the growth kinetics of individual particles. The ionic liquids that we select do not exhibit any anomalous effects on the reaction process as compared with recent in situ TEM studies using conventional solvents. Thus, obtained TEM movies largely support not only classical theory of nanoparticle generation but also some nonconventional phenomena that have been expected recently by some researchers. More noteworthy is the clear observation of lattice fringes by high-resolution TEM even in the ionic liquid media, providing intriguing information correlating coalescence with crystal states. The relaxation of nanoparticle shape and crystal structure after the coalescence is investigated in detail. The effect of crystal orientation upon coalescence is also analyzed and discussed.
Muscling in: The nonvolatility of a room‐temperature ionic liquid (RTIL)–PVdF–HFP composite‐material‐based artificial muscle, prepared in this study, enabled the measurement of in situ electrochemical energy dispersive X‐ray (EDX) spectroscopy of the device. A bending model that strongly depends on the ionic transport number is proposed from the in situ EDX analysis.
Abstract— In this paper, we report on the development of an advanced level‐adaptive overdrive (ALAO) method applicable to full‐HD LC TVs, which makes it possible not only to reduce the gray‐level response time to less than one fourth, but also to improve the S/N ratio for still images by 10 dB; and further to reduce the circuit cost for the LAO method to almost half that of the prior LAO circuit. We have applied the ALAO method to a full‐HD LC front projector with 1.84 Mpixels and a screen size larger than 100 in., and we obtained high‐quality full‐HD moving images.
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