The availability of metamaterials with properties that can be actively tuned is crucial for the future development of various metamaterial-based technologies. Here we show that by using silver nanoparticles equipped with a thermally responsive organic coating a metamaterial is obtained with reversibly switchable properties. The material investigated exhibits dynamic self-assembly resulting from temperature-dependent changes of organic coating shape, which translates to a switchable spatial distribution of the silver nanoparticles. This in turn strongly influences the optical properties of the entire material. The measured optical characteristics of the material are in excellent agreement with theoretical calculations, which allow us to use the latter to predict a dynamically tunable epsilon-near-zero behaviour of the metamaterial. The suggested methodology opens new routes for tunable metamaterials that operate in the visible region and will enable various applications for soft-matter-based optical devices.

We introduce a definition of the electromagnetic chirality of an object and show that it has an upper bound. Reciprocal objects attain the upper bound if and only if they are transparent for all the fields of one polarization handedness (helicity). Additionally, electromagnetic duality symmetry, i.e. helicity preservation upon interaction, turns out to be a necessary condition for reciprocal objects to attain the upper bound. We use these results to provide requirements for the design of such extremal objects. The requirements can be formulated as constraints on the polarizability tensors for dipolar objects or on the material constitutive relations for continuous media. We also outline two applications for objects of maximum electromagnetic chirality: A twofold resonantly enhanced and background free circular dichroism measurement setup, and angle independent helicity filtering glasses. Finally, we use the theoretically obtained requirements to guide the design of a specific structure, which we then analyze numerically and discuss its performance with respect to maximal electromagnetic chirality.

Given an arbitrarily complicated object, it is often difficult to say immediately how it interacts with a specific illumination. Optically small objects, e.g., spheres, can often be modeled as electric dipoles, but which multipole moments are excited for larger particles possessing a much more complicated shape? The T-matrix answers this question, as it contains the entire information about how an object interacts with any electromagnetic illumination. Moreover, a multitude of interesting properties can be derived from the T-matrix such as the scattering cross section for a specific illumination and information about symmetries of the object. Here, we present a method to calculate the T-matrix of an arbitrary object numerically, solely by illuminating it with multiple plane waves and analyzing the scattered fields. Calculating these fields is readily done by widely available tools. The finite element method is particularly advantageous, because it is fast and efficient. We demonstrate the T-matrix calculation at four examples of relevant optical nanostructures currently at the focus of research interest. We show the advantages of the method to obtain useful information, which is hard to access when relying solely on full wave solvers.

Optically active artificial structures have attracted tremendous research attention. Such structures must meet two requirements: Lack of spatial inversion symmetries and, a condition usually not explicitly considered, the structure shall preserve the helicity of light, which implies that there must be a vanishing coupling between the states of opposite polarization handedness among incident and scattered plane waves. Here, we put forward and demonstrate that a unit cell made from chiraly arranged electromagnetically dual scatterers serves exactly this purpose. We prove this by demonstrating optical activity of such unit cell in general scattering directions.

Abstract:We study experimentally and theoretically the electromagnetic field in amplitude and phase behind ball-lenses across a wide range of diameters, ranging from a millimeter scale down to a micrometer. Based on the observation, we study the transition between the refraction and diffraction regime. The former regime is dominated by observables for which it is sufficient to use a ray-optical picture for an explanation, e.g., a cusp catastrophe and caustics. A wave-optical picture, i.e. Mie theory, is required to explain the features, e.g., photonic nanojets, in the latter regime. The vanishing of the cusp catastrophe and the emergence of the photonic nanojet is here understood as the refraction limit. Three different criteria are used to identify the limit: focal length, spot size, and amount of crosspolarization generated in the scattering process. We identify at a wavelength of 642 nm and while considering ordinary glass as the ball-lens material, a diameter of approximately 10 µm as the refraction limit. With our study, we shed new light on the means necessary to describe micro-optical system. This is useful when designing optical devices for imaging or illumination.