We demonstrate an improvement by more than 1 order of magnitude of the figure of merit (FoM) of plasmonic nanoparticle sensors by means of the diffractive coupling of localized surface plasmon resonances. The coupling in arrays of nanoparticles leads to Fano resonances with narrow line widths known as surface lattice resonances, which are very suitable for the sensitive detection of small changes in the refractive index of the surroundings. We focus on the sensitivity to the bulk refractive index and find that the sensor FoM scales solely with the frequency difference between the surface lattice resonance and the diffracted order grazing to the surface of the array. This result, which can be extended to other systems with coupled resonances, enables the design of plasmonic sensors with a high FoM over broad spectral ranges with unprecedented accuracy.

Periodic arrays of metallic nanoparticles may sustain Surface Lattice Resonances (SLRs), which are collective resonances associated with the diffractive coupling of Localized Surface Plasmon Resonances (LSPRs). By investigating a series of arrays with varying number of particles, we traced the evolution of SLRs to its origins. Polarization resolved extinction spectra of arrays formed by a few nanoparticles were measured, and found to be in very good agreement with calculations based on a coupled dipole model. Finite size effects on the optical properties of the arrays are observed, and our results provide insight into the characteristic length scales for collective plasmonic effects: for arrays smaller than 5 x 5 particles, the Q-factors of SLRs are lower than those of LSPRs; for arrays larger than 20 x 20 particles, the Q-factors of SLRs saturate at a much larger value than those of LSPRs; in between, the Q-factors of SLRs are an increasing function of the number of particles in the array.Comment: 4 figure

We demonstrate that a periodic lattice of detuned resonators can suppress the THz extinction at the central resonant frequency, leading to an enhanced transparency due to diffraction. The system consists of metallic rods of two different sizes, each of them supporting a strong half-wavelength (λ/2) resonance, which are spatially displaced 0 M. C. Schaafsma and A. Bhattacharya contributed equally to this work. 1 within the unit cell of the lattice. Using a coupled dipole model we show that the Diffraction Enhanced Transparency (DET) window has its origin in the interference between two surface lattice resonances, arising from the diffractively enhanced radiative coupling of the λ/2 resonances in the lattice. Group-index measurements show that the THz field is strongly delayed by more than four orders of magnitude at the transparency window. Since DET does not involve the near-field coupling of resonators, the fabrication tolerance to imperfections is expected to be very high. This remarkable response renders these systems as very interesting components for THz communication.