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The end of the Neoproterozoic is punctuated by glacial deposition, but the chronology of these deposits is hindered presently by the paucity of geochronological data. Here, we present new radiometric dating for the basal Sete Lagoas cap carbonate deposits that overlie glacial units in the São Francisco craton. Six samples from aragonite‐pseudomorph crystal‐rich facies, showing pristine textures and constant 87Sr/86Sr ratios around 0.7075, yielded a Pb–Pb isochron age of 740 ± 22 Ma, which is interpreted as the depositional age for these remarkably preserved rocks. This age can be used to infer a low‐to‐moderate palaeolatitude of 20–30° for carbonate (and glacial) deposition. In addition, as it overlaps the ages obtained for the oldest Neoproterozoic glacial successions, our result reinforces the idea of a long‐standing ‘Sturtian’ interval, suggesting that this event represents either different discrete glaciations or a protracted event encompassing almost 80 Ma.

The Araçuaí–West Congo orogen encompasses orogenic domains located to the SE of the São Francisco Craton in Brazil, and to the SW of the Congo Craton in Africa. From the opening of the precursor basin to the last orogenic processes, the evolution of the orogen lasted from the very beginning of the Neoproterozoic up to the Cambrian–Ordovician boundary. After the spreading of the South Atlantic Ocean in Cretaceous time, the Araçuaí–West Congo orogen was split into two quite different but complementary counterparts. The Brazilian side (Araçuaí orogen) inherited two thirds of the whole orogenic edifice, including all the Neoproterozoic ophiolite slivers, the entire magmatic arc and syn-collisional to post-collisional magmatism, and the suture zone. The African counterpart (West Congo Belt), a fold–thrust belt free of Neoproterozoic ophiolite and Pan-African orogenic magmatism, inherited the thick pile of bimodal volcanic rocks of the Early Tonian rift stage, implying that the precursor basin was an asymmetrical rift with the thermal–magmatic axis located in the West Congo Belt. Both counterparts of the Araçuaí–West Congo orogen include Neoproterozoic glaciogenic deposits, allowing tentative lithostratigraphic correlations, but identification of the ice ages remains uncertain because the lack of sufficient well-constrained geochronological data.

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