The Neoproterozoic Araçuaí-West Congo (A-WC) orogen is one of many Brasiliano/Pan-African orogens that developed during the assembly of West Gondwana. This orogen was split apart in Mesozoic time, due to opening of the South Atlantic-the Araçuaí orogen now underlies eastern Brazil, whereas the West Congo belt fringes central Africa's Atlantic coast. Significantly, at the time it formed, the A-WC orogen was bounded on the west, north, and east by the São Francisco-Congo craton, a crustal block that had the shape of a lopsided, upside-down 'U'. Thus, the orogen was "partially confined" during tectonism, in that it occupied an enclave surrounded on three sides by cratonic crust. Formation of the A-WC orogen resulted in kinematically complex deformation, substantial crustal shortening, and production of a large volume of magma. How such features could develop in this particular setting has long been a mystery. Our field studies in the Araçuaí orogen, together with published data on the West Congo belt, characterize the kinematic picture of the A-WC orogen, and lead to a tectonic model that addresses its evolution. In our model, the A-WC orogen formed in response to closure of the Macaúbas basin. This basin was underlain by oceanic crust in the south, but tapered northward into a continental rift which terminated against the cratonic bridge linking the eastern and western arms of the São Francisco-Congo craton. Closure occurred when the western arm (now the São Francisco craton) rotated counterclockwise towards the eastern arm (now the Congo craton). This closure may have been driven by collision of the Paranapanema, Amazonian, and Kalahari cratons against the external margins of the São Francisco-Congo craton, rather than by slab-pull associated with subduction of the Macaúbas basin's floor. Thus, the process of forming the A-WC orogen resembled the process of crushing of a nut between two arms of a nutcracker. Such "nutcracker tectonics" led to a series of kinematically distinct deformation stages. Initially, internal portions of the orogen flowed northwards. Then, substantial crustal thickening occurred in the orogen's interior, and the deformation front migrated outwards, producing thrust belts that overlapped the internal margins of the craton. With continued closure, space in the enclave became restricted and the orogen's interior underwent lateral escape to the south. Late-stage extensional collapse triggered both production of late-to post-collisional granites and exhumation of high-grade rocks from mid-crustal levels.
The Araçuaí orogen extends from the eastern edge of the São Francisco craton to the Atlantic margin, in southeastern Brazil. Orogenic igneous rocks, formed from c. 630 to c. 480 Ma, cover one third of this huge area, building up the Eastern Brazilian Pegmatite Province and the most important dimension stone province of Brazil. G1 supersuite (630-585 Ma) mainly consists of tonalite to granodiorite, with mafic to dioritic facies and enclaves, representing a continental calc-alkaline magmatic arc. G2 supersuite mostly includes S-type granites formed during the syn-collisional stage (585-560 Ma), from relatively shallow two-mica granites and related gem-rich pegmatites to deep garnet-biotite granites that are the site of yellow dimension stone deposits. The typical G3 rocks (545-525 Ma) are non-foliated garnet-cordierite leucogranites, making up autochthonous patches and veins. At the post-collisional stage (530-480 Ma), G4 and G5 supersuites were generated. The S-type G4 supersuite mostly consists of garnet-bearing two-mica leucogranites that are the source of many pegmatites mined for tourmalines and many other gems, lithium (spodumene) ore and industrial feldspar. G5 supersuite, consisting of high-K-Fe calc-alkaline to alkaline granitic and/or charnockitic to dioritic/noritic intrusions, is the source of aquamarine-topaz-rich pegmatites but mainly of a large dimension stone production.
The Araçuaí–West Congo orogen encompasses orogenic domains located to the SE of the São Francisco Craton in Brazil, and to the SW of the Congo Craton in Africa. From the opening of the precursor basin to the last orogenic processes, the evolution of the orogen lasted from the very beginning of the Neoproterozoic up to the Cambrian–Ordovician boundary. After the spreading of the South Atlantic Ocean in Cretaceous time, the Araçuaí–West Congo orogen was split into two quite different but complementary counterparts. The Brazilian side (Araçuaí orogen) inherited two thirds of the whole orogenic edifice, including all the Neoproterozoic ophiolite slivers, the entire magmatic arc and syn-collisional to post-collisional magmatism, and the suture zone. The African counterpart (West Congo Belt), a fold–thrust belt free of Neoproterozoic ophiolite and Pan-African orogenic magmatism, inherited the thick pile of bimodal volcanic rocks of the Early Tonian rift stage, implying that the precursor basin was an asymmetrical rift with the thermal–magmatic axis located in the West Congo Belt. Both counterparts of the Araçuaí–West Congo orogen include Neoproterozoic glaciogenic deposits, allowing tentative lithostratigraphic correlations, but identification of the ice ages remains uncertain because the lack of sufficient well-constrained geochronological data.
h i g h l i g h t sWe have analysed the mineral sturmanite. Formula Ca 6 (Fe, Al, Mn) 2 (SO 4 ) 2 (B(OH) 4 )(OH) 12 Á26H 2 O. The mineral is unusual as it contains both sulphate and hydroxyborate anions. Chemical analysis shows a homogeneous phase, composed by Ca, Fe, Mn, S, Al and Si. Bands attributed to sulphate and hydroxyborate anions are identified.
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