The first hybrid phototransistors are reported where the performance of a network of photoactive CH3NH3PbI3 nanowires is enhanced by CVD‐grown monolayer graphene. These devices show responsivities as high as ≈2.6 × 106 A W−1 in the visible range, showing potential as room‐temperature single‐electron detectors.

Mechanically-induced wood welding, without any adhesive, is shown here to rapidly yield wood joints satisfying the relevent requirements for structural application. The mechanism of mechanically-induced vibrational wood fusion welding is shown to be due mostly to the melting and owing of some amorphous, cells-interconnecting polymer material in the structure of wood, mainly lignin, but also hemicelluloses. This causes partial detachment, the 'unglueing' of long wood cells, wood bres, and the formation of a bre entanglement network in the matrix of molten material which then solidi es. Thus, a wood cells/ bre entanglement network composite having a molten lignin polymer matrix is formed. During the welding period some of the detached wood bres which are no longer held by the interconnecting material are pushed out of the joint as excess bres. Crosslinking chemical reactions also have shown to occur. The most likely one of these identi ed by NMR appears to be a cross-linking reaction of lignin with carbohydrate-derived furfural. The presence of these reactions has been identi ed by CP-MAS 13 C-NMR. These reactions, however, are relatively minor contributors during the very short welding period. Their contribution increases after welding has nished, which explains why long holding times under pressure after the end of welding contribute strongly to obtaining a good bond.

An efficient synthetic approach to construct a fully substituted benzo[1,2-b:4,5-b']difuran (BDF) 2a via base-catalyzed double annulations is presented. Compound 2a can readily undergo Suzuki, Heck, and Sonogashira coupling reactions to afford in good yields a manifold of extended pi-conjugated BDF derivatives, e.g., with pyridine termini (4-6) and with different spacers. These are highly luminescent materials that undergo two reversible one-electron oxidations. Remarkably, their photophysical and electrochemical properties can be largely tuned by methylation or protonation. Consequently, they can function as pH-dependent fluorescence switches. Finally, the observed electronic properties are explained on the basis of density functional theory.

Cartilage regeneration based on isolated and culture-expanded chondrocytes has been studied in various in vitro models, but the quality varies with respect to the morphology and the physiology of the synthesized tissues. The aim of our study was to promote in vitro chondrogenesis of human articular chondrocytes using a novel three-dimensional (3-D) cultivation system in combination with the chondrogenic differentiation factors transforming growth factor beta 2 (TGF-β2) and L-ascorbic acid. Articular chondrocytes isolated from six elderly patients were expanded in monolayer culture. A single-cell suspension of the dedifferentiated chondrocytes was then added to agar-coated dishes without using any scaffold material, in the presence, or absence of TGF-β2 and/or L-ascorbic acid. Three-dimensional cartilage-like constructs, called single spheroids, and microtissues consisting of several spheroids fused together, named as fusions, were formed. Generated tissues were mainly characterized using histological and immunohistochemical techniques. The morphology of the in vitro tissues shared some similarities to native hyaline cartilage in regard to differentiated S100-positive chondrocytes within a cartilaginous matrix, with strong collagen type II expression and increased synthesis of proteoglycans. Finally, our innovative scaffold-free fusion culture technique supported enhanced chondrogenesis of human articular chondrocytes in vitro. These 3-D hyaline cartilage-like microtissues will be useful for in vitro studies of cartilage differentiation and regeneration, enabling optimization of functional tissue engineering and possibly contributing to the development of new approaches to treat traumatic cartilage defects or osteoarthritis.

Wood grain orientation differences in the two surfaces to be bonded yield bondlines of different strength in no-adhesives wood welding. Longitudinal wood grain bonding of tangential and radial wood sections yields an approximately 10% difference in strength results of the joint. Cross-grain (±90°) bonding yields instead a much lower strength result, roughly half that observed for pieces bonded with the grain parallel to each other. These differences can be explained by the very marked effect that homogeneity of fibre orientation is known to have on fibre–matrix composites. Oak yields lower results than beech and maple and is more sensitive to welding conditions. Differences in both anatomical and wood constituent composition can account for this difference in performance. Contrary to the other wood species, oak always presents joint bondlines where little or no increase in density at the interface is noticed. This explains its somewhat lower strength results. This is based on the different mode of bonding predominant in this species, while the other species present two different modes of bonding. Thus, two types of bondlines are observed by scanning electron microscopy (SEM): (i) bondlines where entangled fibre–matrix composites are formed at the interface and (ii) bondlines in which direct welding of the cell walls occurs, just by fused intercellular material or cell surface material. In this latter case the cells remain flat, without an entangled fibre–matrix composite being formed. This is the almost exclusively predominant case for oak. Both cases and even hybrid cases between the two have also been observed in beech.

Mechanically-induced wood flow welding, without any adhesive, is here shown to rapidly yield wood joints satisfying the relevant requirements for structural application. The mechanism of mechanically-induced vibrational wood flow welding is shown to be due mostly to the melting and flowing of the amorphous polymer materials interconnecting wood cells, mainly lignin, but also some hemicelluloses. This causes the partial detachment of long wood cells and wood fibres and the formation of an entanglement network in a matrix of melted material which then solidifies. Thus, it forms a wood cell/fibre entanglement network composite having a molten lignin polymer matrix. During the welding period, some of the detached wood fibres no longer held by the interconnecting material are pushed out of the joint as excess fibre. Cross-linking chemical reactions of lignin and of carbohydrate-derived furfural also occur. Their presence has been identified by CP-MAS 13 C NMR. These reactions are, however, relatively minor contributors during the very short welding period. Their contribution increases after welding has finished, explaining why relatively longer holding times under pressure after the end of welding contribute strongly to obtaining a good bond.

High temperature passivating contacts for c-Si based solar cells are intensively studied because of their potential in boosting solar cell efficiency while being compatible with industrial processes at high temperatures. In this work, the hydrogenation mechanism of fired passivating contacts (FPC) based on c-Si/SiOx/nc-SiCx(p) stacks was investigated. More specifically, the correlation between passivation and local re-distribution of hydrogen resulting from the application of different types of interfacial oxides (SiOx) and post-hydrogenation processes were analyzed. To do so, the applied processing sequence was interrupted at different stages in order to characterize the samples. To assess the hydrogen content, deuterium was introduced (alongside/instead of hydrogen) and secondary ion mass spectroscopy (SIMS) was used for depth profiling. Combining these results with lifetime measurements, the key role played by hydrogen in the passivation of defects at the c-Si/SiOx interface is discussed. The SIMS profiles show that hydrogen almost completely effuses out of the SiCx(p) during firing, but can be reintroduced by hydrogenation via forming gas anneal (FGA) or by release from a hydrogen containing layer such as SiNx:H. A pile-up of H at the c-Si/SiOx interface was observed and identified as a key element in the FPC's passivation mechanism. Moreover, the samples hydrogenated with SiNx:H exhibited higher H content compared to those treated by FGA, resulting in higher iVOC values. Further investigations revealed that the doping of the SiCx layer does not affect the amount of interfacial defects passivated by the hydrogenation process presented in this work. Eventually, an effect of the oxide's nature on passivation quality is evidenced. iVOC values of up to 706 mV and 720 mV were reached with FPC test structures using chemical and UV-O3 tunneling oxides, respectively, and up to 739 mV using a reference passivation sample featuring a ~25 nm thick thermal oxide.

The design and synthesis of a novel linear thioether-based ligand subunit with a tetraphenylmethane core used in the stabilisation of gold nanoparticles (AuNPs) are presented. Mono-, tri, penta- and heptamers of the ligand have been synthesised and used to stabilise AuNPs by enwrapping. With the exception of the monomer, all ligands provide reliable long-term stability and redispersibility for the coated nanoparticles in common organic solvents. Despite variation of the oligomer length, all stable particles were of the same size within error tolerance (1.16±0.32 nm for the trimer, 1.15±0.30 nm for the pentamer, 1.17±0.34 nm for the heptamer), as investigated by transmission electron microscopy (TEM). These findings suggest that not only the number of sulfur atoms in the ligand, but also its bulkiness play a crucial role in stabilising the AuNPs. These findings are supported by thermogravimetric analysis (TGA), showing that AuNPs stabilised by the penta- or heptamer are passivated by a single ligand. Thermal stability measurements suggest a correlation between ligand coverage and thermal stability, further supporting these findings.