The quality of quinoa flour is greatly determined by its non-starch components, mainly protein and lipids. Dry fractionation has an important impact on the composition and physicochemical properties of quinoa flour and grits. Quinoa cv. Titicaca, the most extensively grown in Europe and little studied so far, was used in this work. Hydration, techno-functional, rheological and thermal properties of three quinoa fractions obtained by dry fractionation (fine, medium and coarse) were evaluated and related to their particle size and composition. The medium fraction (~500 μm) was enriched in protein (50%) and lipids (80%) and depleted in starch (30%) with respect to the original grain; while the coarse fraction (~1000 μm) was enriched in starch (7%) and reduced in protein (15%). The fine fraction showed the most similar functional, pasting and rheological properties to the whole grain quinoa flour. The coarse fraction led to the most consistent gels, with the elastic (G') and viscous (G'') moduli being ten and twenty times higher than those found in the other quinoa fractions and the whole grain flour. The degree of retrogradation as well as the formation of the amylose-lipid complex were markedly affected by the particle size and not so by the composition of each fraction. This work allows to conclude that dry fractionation of quinoa grains is a feasible procedure to tailoring the nutritional profile of the flour and its techno-functional and rheological properties.
The impact of acid incorporation (acetic+lactic, 0.5%) into rice starch-based doughs enriched with different proteins (egg albumin, calcium caseinate, pea protein and soy protein isolates) at different doses (0, 5 and 10%) has been investigated on dough viscoelastic and pasting profiles. Oscillatory (stress and frequency sweeps) and creeprecovery tests were used to characterise the fundamental viscoelastic behaviour of the doughs, and thermomechanical assays were performed to assess dough viscometric performance. Supplementation of gluten-free doughs with proteins from vegetal sources led to more structured dough matrices (higher viscoelastic moduli and steady viscosities, and lower tan , instantaneous and retarded elastic compliances) effect being magnified with protein dose. Acid addition decreased these effects. Incorporation of proteins from animal source resulted in different viscoelastic behaviours according to the protein type, dosage and acidification, especially for casein. Acidification conferred lower dough deformation and notably higher steady viscosity and viscoelastic moduli for 5 %-casein-added dough. Protein-acid interaction favoured higher viscosity profiles, particularly for doughs with proteins of vegetable origin and lower dosage. Dough acidification decreased the pasting temperatures and the amylose retrogradation. Acidification of protein-enriched rice-starch doughs allowed manipulation of its viscometric and rheological properties which is of relevant importance in gluten-free bread development.
The microwave radiation thermal treatment of rice flour was studied and its impact on physical and structural characteristic in relation to the initial moisture content (IMC) (20% and 30%) was evaluated. To explain the fundamentals of observed changes the microwave radiation absorption capacity of flour as well as temperature and moisture change during the treatment were evaluated. The flour particle morphological structure as well as crystallinity/amorphous region ratio changed after the treatment. The flour thermal properties also altered revealing IMC significant impact on the gelatinization temperature, that rised up to 3ºC, and the amylopectin retrogradation extent that increased up to a 7% in the most intense microwave-treated flours with respect to the native flour. Lower peak, setback and breakdown viscosities -that decreased with respect to the native flour up to 42%, 34% and 86% respectively-and higher pasting temperatures -that increased up to 10 ºC-were also observed. An exceptional microwave irradiation efficiency resulting in rice flour physical changes in significantly shorter times, 4-8 min, than conventional heat-moisture treatment processes was concluded.
The physical modification of rice flour by heat-moisture treatment assisted by microwave radiation and its effect on the rheological and pasting properties of glutenfree doughs and the physical quality of their resulting breads was investigated. Two levels of flour initial moisture content, 20% (MW-20%) and 30% (MW-30%) and two levels of its addition (30% and 50%) to the dough were evaluated to assess the potential of the physical treatment to modify dough viscoelasticity and bread-making ability. MW-30% treated rice flour showed the most notable results. It provided enhanced dough viscoelasticity vs the control (100% native rice flour), increasing the dough G1' modulus up to 69% and 135% for the treated flour additions of 30% and 50% of MW-30% respectively. The treated flour increased the resistance of doughs to deformation and enhanced their elastic behavior and recovery capacity up to 170% when compared to the control dough. The major effects on pasting parameters were also obtained for the doughs formulated with MW-30% flour at the maximum substitution level (50%). It delayed the pasting temperature, decreased the peak, trough and final viscosities with respect to the control dough. Both MW-treated rice flours (MW-20% and MW-30%) led to breads with higher-specific volume, softer crumb and delayed staling. The MW assisted heat moisture treatment of rice flour seems to be a valuable procedure to improve the viscoelastic behavior and bread-making performance of gluten-free doughs.
The impact of acidification and non-gluten protein fortification (egg-albumin and soy-protein isolate) on thermal transitions of rice, potato and tapioca starches as well as the viscoelastic properties of their gels prepared at two casting temperatures, 90ºC and 120ºC, was investigated. The thermal and rheological behaviour of starches depended on their botanical origin and were significantly influenced by the presence and type of protein added as well as by the pH of the aqueous dispersion. Acidification to pH 4.5 increased the gelatinization temperature of rice starch in the presence of albumin or soy proteins, while reduced it in the case of tapioca starch, regardless of the presence of proteins. Acidification of rice starch dispersions decreased significantly the apparent gelatinization enthalpy; this effect was even greater in the presence of proteins. The addition of proteins brought about a structuring effect on tapioca gels leading to higher viscoelastic moduli and lower tan δ values. In general, acidification led to weaker gel structures, with more pronounced effect for potato starch, most likely related to its higher phosphate content (charge screening). Much weaker gels were obtained at 120ºC compared to those processed at lower temperatures; however, protein incorporation reinforced gel structure, an effect that was not observed in gels formed at 90º, as also revealed by microstructure analysis using confocal scanning laser microscopy. In conclusion, protein addition and pH adjustments of aqueous starch dispersions can provide an effective means to modulate the functional and textural properties of gel-like starch-based gluten-free formulations.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.