The release and transformation of inorganic elements during grate-firing of bran was studied via experiments in a laboratory-scale reactor, analysis of fly ash from a grate-fired plant, and equilibrium modeling. It was found that K, P, S, and to a lesser extent Cl and Na were released to the gas phase during bran combustion. Laboratory-scale experiments showed that S was almost fully vaporized during pyrolysis below 700°C. Sixty to seventy percent of the K and P in bran was released during combustion, in the temperature range 900À1100°C. The release of K and P was presumably attributed to the vaporization of KPO 3 generated from thermal decomposition of inositol phosphates, which were considered to be a major source of P and K in bran. The influence of additives such as CaCO 3 , Ca(OH) 2 , and kaolinite on the release was also investigated. Ca-based additives generally increased the molar ratio of the released K/P, whereas kaolinite showed an opposite effect. Thermodynamic modeling indicated that the fly ash chemistry was sensitive to the molar ratio of the released K/P. When the molar ratio of the released K/P was below 1, KPO 3 and P 4 O 10 (g) were the main stable K and P species at temperatures higher than 500°C. Below 500°C, the KPO 3 and P 4 O 10 (g) may be converted to H 3 PO 4 (l), which may cause severe deposit build-up in the economizers of a grate-fired boiler. By increasing the molar ratio of the released K/P to above 2, the equilibrium distribution of the K and P species was significantly changed and the formation of H 3 PO 4 (l) was not predicted by thermodynamic modeling.

Discharge of waste in general, and food waste, in particular, is considered one of the major environmental problems today, as waste generation increases continuously, reaching values of 32% of all food produced worldwide. There are many different options that can be applied to the management and evaluation of waste treatment, and Anaerobic Digestion seems to be one of the most suitable solutions because of its benefits, including renewable energy generation in form of biogas. Moreover, if FW (food waste) is digested in anaerobic digesters from Waste Water Treatment Plants, a common solution is provided for both residues. Furthermore, co-digestion of food waste and sewage sludge provides benefits in terms of anaerobic process stability enhancing the buffer capacity of ammonia (for example) and biogas formation, which can be increased up to 80% when compared with monodigestion. The present paper reviews food waste anaerobic digestion from its generation, characteristics and different options for its management, and it does focus specifically on the anaerobic digestion and co-digestion process, stages, limiting rates and parameters, utilizing numerous experiences, strictly related to food waste. Pre-treatments are also considered as they are important and innovative for enhancing biogas production and its methane yield. The paper shows an extensive collection of pre-treatments, its basics, improving factors, and numerical data of biogas formation improvements that are related both to substrate modification and to the synergistic effect of co-digestion, which could lead to an increase of methane production from 11% to 180%.

This study presents a complete characterization of the residual materials found in fruit and vegetable markets and their adaptability to be treated by anaerobic digestion with the aim of generating biogas as a new and renewable energy source. It has been determined that these substrates are perfectly suitable to be treated by anaerobic digestion, being rich in simple carbohydrates, with a high content of moisture and solids (total and volatile), which makes it a substrate of easy solubilization and with a great amount of matter directly accessible to the microorganisms responsible for anaerobic degradation. The process develops smoothly, with a slight release of acidic elements, but without impact by the development of the buffer effect by ammonia. In addition, a phenomenon of digestion is observed in two phases, indicating that despite the particulateing of the substrate, it manages to digest the organic matter directly accessible and the inaccessible. In numerical terms, 100 g of residue V produce 913.282 NmL of biogas, of which 289.333 NmL correspond to methane. The disintegration constant is 0.200 days−1, with 16,045% of the substrate degraded. As an innovation, the hydrogen generated in the process has been used as an indicator of the stability and development of the process. Accompanied by a statistical analysis and mathematical adjustments, it is possible to characterize in depth the process and its evolution, determining that the degradation is fast, with a rapid and stable hydrolysis.

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Residues and by-products from vegetables and fruit wholesale markets are suitable for recovery in the form of energy through anaerobic digestion, allowing waste recovery and introducing them into the circular economy. This suitability is due to their composition, structural characteristics, and to the biogas generation process, which is stable and without inhibition. However, it has been observed that the proportion of methane and the level of degradation of the substrate is low. It is decided to study whether the effect of pretreatments on the substrate is beneficial. Freezing, ultrafreezing and lyophilization pretreatments are studied. A characterization of the substrates has been performed, the route of action of pretreatment determined, and the digestion process studied to calculate the generation of biogas, methane, hydrogen and the proportions among these. Also, a complete analysis of the process has been performed by processing the data with mathematical and statistical methods to obtain disintegration constants and levels of degradation. It has been observed that the three pretreatments have positive effects, when increasing the solubility of the substrate, increasing porosity, and improving the accessibility of microorganisms to the substrate. Generation of gases are greatly increased, reaching a methane enrichment of 59.751%. Freezing seems to be the best pretreatment, as it increases the biodegradation level, the speed of the process and the disintegration constant by 306%.

Barley fields reach 1.7 million hectares in Spain, of which 320,000 are used to produce malt, generating 450,000 tons of crop residue from barley intended for malt production. One way to treat this waste in an environmentally sound, energy-sustainable and economically cost-effective manner is anaerobic digestion. The biogas generated can be used as fuel and as a renewable source of energy (providing a solution to the energy supply problem from an environmental point of view). It has been shown that, when treated along with sludge from a Upflow Anaerobic Sludge Blanket (UASB) reactor, the crop malt residue produces about 1604 NmL of biogas per 100 g; with a content in methane of 27.486%. The development of the process has been studied with a novel indicator, hydrogen generation, and it has been determined that the process takes place in two phases. It has been demonstrated that this solution is beginning to be energy-efficient and therefore to produce energy for external uses in regions that have at least 6000 hectares of planted barley. At best, it can be considered, in a given region, the equivalent of a 115 MW power plant. It could supply energy to 10 thousand homes per year. Therefore, it is considered an energy-efficient solution that com-plies with the Sustainable Development Goals #1, #7, #10, #12 and #13. It guarantees access to energy in isolated areas or with supply problems, and results in a 55.4% reduction in emissions of equivalent-CO2 (which equals 38,060 tons of equivalent-CO2 in Spain).

, that the choice between both is predicated on other than purely economic criteria.