The morphology and properties of heavily eroded soils found in chernozems in the upland landscape of the Proszowice Plateau (southern part of Poland) was presented. The issue of classification of these soils was also discussed. Taking into account the terrain context, it should have been assumed that these soils were formed as a result of strong erosion (truncation) of chernozems. These (post-chernozem) soils were relatively young, in which only the development of humus horizon can be documented. However, the accumulation of humus was hampered by constantly intense erosion processes. Evidence of the occurrence of the illuviation process as well as formation of cambic horizon is not visible macroscopically and microscopically. These soils are often classified as weakly developed soils though despite the poor development of the soil profile, they are characterized by potentially high productivity, which results both from the properties of their parent material (texture, porosity) and from their youthfulness (carbonate content both in fine earths and in nodules, high pH in whole profile). Therefore, the name proposed in Polish Soil Classification, 6th edition (‘pararędzina’) seems to be justified. These soils would be classified as Entisols according to USDA Soil Taxonomy and as Regosols according to WRB.
The goal of this work is to evaluate the hop stems, a byproduct of hop cones production, as a potential source of cellulose. Hop stems contain up to 29% of cellulose. The cellulose isolation was conducted through the thermochemical treatment. After high-speed blending, the cellulose was characterized by 67% of crystallinity degree obtained from X-ray diffraction and median diameter of 6.7 nm obtained from atomic force microscopy imaging. The high-intensity ultrasonication (HIUS) was applied to reach further disintegration of cellulose fibers. The longer HIUS treatment resulted in decrease in crystallinity degree even up to 60% and decrease in the fiber diameter up to 4 nm. The Fourier transform infrared spectroscopy (FTIR) spectra showed that HIUS treatment led to changes in intermolecular hydrogen bonds. The stability of cellulose dispersions versus length of HIUS treatment was monitored over 14 days with back dynamic light scattering and laser Doppler electrophoresis methods. Obtained results are evidence that the hop stems are a potential source of cellulose and that it is possible to obtain stable dispersions after HIUS treatment. This was the first time that the properties of hop cellulose have been described so extensively and in detail after the use of HIUS treatment.
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