We study the model proposed by Ziff, Gulari, and Barshad to mimic the oxidation of carbon monoxide (CO) in the presence of fixed impurities distributed over the catalytic surface. Our focus is on the continuous phase transition between the active phase, where occurs the production of carbon dioxide (CO2), and the inactive phase, where all the non inert sites become filled with oxygen molecules. We employ Monte Carlo simulations to calculate the different ratios between moments of the order parameter at the critical point, as well as, we determine the critical exponents β and ν⊥ as a function of the concentration of impurities. We show that the presence of impurities over the catalytic surface changes the critical behavior of the system. The critical exponents depend on the concentration of impurities and the model does not belong to the directed percolation universality class.

We study a competitive reaction model between two monomers A and B on a linear lattice. We assume that monomer A can react with a nearest-neighbor monomer A or B , but reactions between monomers of type B are prohibited. We include in our model lateral interactions between monomers as well as the effects of temperature of the catalyst. The model is considered in the adsorption controlled limit, where the reaction rate is infinitely larger than the adsorption rate of the monomers. We employ site and pair mean-field approximations as well as static Monte Carlo simulations. We determine the phase diagram of the model in the plane y_{A} versus temperature, where y_{A} is the probability that a monomer of the type A arrives at the surface. This phase diagram shows regions of active and absorbing states separated by a line of continuous phase transitions. Despite the absorbing state of the model to be strongly dependent on temperature, we show that the static critical exponents of the model belong to the same universality class of the directed percolation.

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We determine the critical behavior of a reactive model with many absorbing configurations. Monomers A and B land on the sites of a linear lattice and can react depending on the state of their nearest-neighbor sites. The probability of a reaction depends on temperature of the catalyst as well as on the energy coupling between pairs of nearest-neighbor monomers. We employ Monte Carlo simulations to calculate the moments of the order parameter of the model as a function of temperature. Some ratios between pairs of moments are independent of temperature and are in the same universality class of the contact process. We also find the dynamical critical exponents of the model and we show that they are in the directed percolation universality class whatever the values of temperature.

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We study a model of heterogeneous catalysis with competitive reactions between two monomers A and B. We assume that reactions are dependent on temperature and follow an anti-Arrhenius mechanism. In this model, a monomer A can react with a nearest neighbor monomer A or B, however, reactions between monomers of type B are not allowed. We assume attractive interactions between nearest neighbor monomers as well as between monomers and the catalyst. Through mean-field calculations, at the level of site and pair approximations, and extensive Monte Carlo simulations, we determine the phase diagram of the model in the plane y(A) versus temperature, where y(A) is the probability that a monomer A reaches the catalyst. The model exhibits absorbing and active phases separated by lines of continuous phase transitions. We calculate the static, dynamic, and spreading exponents of the model, and despite the absorbing state be represented by many different microscopic configurations, the model belongs to the directed percolation universality class in two dimensions. Both reaction mechanisms, Arrhenius and anti-Arrhenius, give the same set of critical exponents and do not change the nature of the universality class of the catalytic models.

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RESUMO. Neste trabalho investigaremos as equações de difusão, usualmente aplicadas na descrição da difusão anômala, que empregam derivadas fracionárias tanto na variável temporal quanto na variável espacial. Em particular, para essas equações obteremos soluções exatas levando em conta uma condição inicial genérica e formularemos uma teoria de perturbação para o estudo de situações mais complexas. Também verificaremos que as derivadas fracionárias, quando aplicadas na parte temporal, possibilitam-nos o estudo de um processo de difusão anômala com o segundo momento finito, i.e.,, correspondendo aos casos, sub e superdifusivo, respectivamente). Em contraste, com a derivada fracionária aplicada na variável espacial que resulta em uma difusão anômala cujo segundo momento não é finito. Complementando o cenário acima, empregaremos o formalismo de caminhantes aleatórios para explorar as implicações obtidas por usar derivadas fracionárias na equação de difusão.Palavras-chave: difusão anômala, equação de difusão, distribuições de Lévy.ABSTRACT. Anomalous diffusion and fractional diffusion equations. In this work we investigate the anomalous diffusion equations, usually applied to describe the anomalous diffusion, which employ fractional derivatives for the time or the spatial variables. In particular, we obtain exact solutions by taking a generic initial condition into account and developing a perturbation theory to investigate complex situations. We also verify that the fractional derivatives, when applied to the time variable, lead us to a anomalous diffusion with second moment finite, i.e., , corresponding to sub and superdifusive behavior, respectively). By way of contrast, the fractional derivative applied to the spatial variable results in a anomalous diffusion where the second moment is not finite. These equations generalize the usual diffusion equation in order to incorporate several situations. We also employ the continuous time random walking formalism to investigate the implications obtained by using fractional derivatives in the diffusion equation.