Photoionization and photofragmentation studies of formic acid (HCOOH) are performed for the valence shell electron ionization process. The total and partial ion yield of gaseous HCOOH were collected as a function of photon energy in the ultraviolet region, between 11.12 and 19.57 eV. Measurements of the total and partial ion yield of gaseous formic acid molecule are performed with a time-of-flight mass spectrometer at the Synchrotron Light Brazilian Laboratory. Density functional theory and time dependent density functional theory are employed to calculate the ground and excited electronic state energies of neutral and ionic formic acid as well as their fragments and normal vibration modes. The ionization potential energies, the stability of electronic excited states of HCOOH(+), and the energies of opening fragmentation channels are estimated from theoretical-experimental analysis. Additionally, the main formic acid photofragmentation pathways by exposition of photons within that energy range are determined experimentally. These produced ions primarily have the following mass/charge ratios: 46 (HCOOH(+)), 45 (COOH(+)), 29 (HCO(+)), and 18 (H(2)O(+)).
The
photofragmentation dynamics of 1,1,1,2-tetrafluoroethane (R134a) with
photon energies from 12 eV up to 320 eV, surrounding the C 1s edge
is discussed. The ionic moieties were measured in coincidence with
the ejected electrons (PEPICO mode), and detected as a function of
the photon energy. Around the C K core edge, the
fragmentation profiles are examined regarding the site specific excitation
of the CH2FCF3 molecule. In the present case,
site-selectivity is favored by the distinct chemical environments
surrounding both C atoms. NEXAFS spectrum at the C 1s edge simulation
has been obtained at the TDDFT level and excited state geometry optimization
calculations have been performed at the inner-shell multiconfigurational
self-consistent field level. Our observations indicate that the C(H2F) 1s excitation to a highly repulsive potential expels a
fluorine atom leaving the heavier radical fragment C2F3H2* which relaxes to the fundamental state of the
ion C2F3H2
+. On the other
hand, the excitation from the C(F3) 1s carbon to a repulsive
state in the C–C bond, leads to a C–C bond cleavage,
explaining the observed site specific fragmentation.
Propylene oxide, a favorite target of experimental and theoretical studies of circular dichroism, was recently discovered in interstellar space, further amplifying the attention to its role in the current debate on protobiological homochirality. In the present work, a photoelectron-photoion-photoion coincidence technique, using an ion-imaging detector and tunable synchrotron radiation in the 18.0-37.0 eV energy range, permits us (i) to observe six double ionization fragmentation channels, their relative yields being accounted for about two-thirds by the couple (CH, CHO) and one-fifth by (CH, CHO); (ii) to measure thresholds for their openings as a function of photon energy; and (iii) to unravel a pronounced bimodality for a kinetic-energy-released distribution, fingerprint of competitive non-adiabatic mechanisms.
We have performed a theoretical and experimental study of the formamide (HCONH2) photofragmentation and photoionization processes in the gas phase. The experiment was perfomed by using a time-of-flight mass spectrometer using the photoelectron photoion coincidence (PEPICO) technique in the valence region, from photons with energy between 10 and 20 eV. We have obtained both mass and partial ion yield spectra, identified by the mass-to-charge ratio as a function of the photon energy. With this setup, we could ascertain the threshold energy for the production of formamide cation and its cationic fragments. The theoretical analysis of the formamide photofragmentation channels are fulfilled by the density functional theory (DFT) and the time-dependent density functional theory (TDDFT). The theoretical analysis allowed us to estimate, for example, which atoms are lost during the photofragmentation. We have also developed a theoretical-experimental analysis of the main fragments produced in the dissociation: m/q = 45 (HCONH2+), m/q = 44 (CONH2+), m/q = 29 (HCO+), m/q = 17 (NH3+), and m/q = 16 (NH2+).
Competitive fragmentation pathways of acetic acid dimer explored by synchrotron VUV photoionization mass spectrometry and electronic structure calculations
We have performed
an experimental investigation into the interaction
of vacuum-ultraviolet synchrotron radiation with pyridine molecules
in the gas phase. Specifically, a double-ion chamber spectrometer
was used to measure the absolute photoabsorption cross sections and
the photoionization quantum yields from the ionization threshold to
21.5 eV. Moreover, photoionization and neutral-decay cross sections
in absolute scale were derived from these data. In addition, the fragmentation
pattern was investigated as a function of the photon energy by using
a time-of-flight mass spectrometer and the photoelectron-photoion
coincidence technique. Thus, the absolute partial ionization cross
sections for each ionic fragment were obtained. Comparisons are made
with experimental data available in the literature.
The ionization and photofragmentation of molecules in the core region has been widely investigated for monomers and dimers of organic molecules in the gas phase. In this study, we used synchrotron radiation to excite electrons of the oxygen K-edge in an effusive molecular beam of doubly deuterated formic acid. We used time-of-flight mass spectrometry and employed the spectroscopic techniques photoelectron-photoion coincidence and photoelectron photoion-photoion coincidence to obtain spectra of single and double coincidences at different pressures. Our results indicate the presence of ions and ion pairs that have charge-to-mass ratio higher than the monomer DCOOD, as the (DCOOD)·D(+), and pairs (DCO(+), DCO(+)) and (CO(+), DCO(+)). Comparing the spectra obtained for different pressures we can ascertain that these ions are formed by the fragmentation of DCOOD dimers.
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