Polyaniline-assisted deposition of PbS is carried out on antimony tin oxide (ATO) glass for ATO/PANI/PbS composite formation. The deposition of PbS was carried out inside and outside the polymer chains using the ionic adsorption deposition process. Various analyses were conducted to confirm the chemical structure and morphological, optical, and electrical properties of the resulting composite. TEM and SEM analyses demonstrated the spherical shape of PbS particles inside and outside the PANI network with more dark or white color, respectively. Moreover, the ImageJ program confirmed the composite formation. The XRD characterization showed the shifts in the PANI peaks after the composite formation with the appearance of a new additional peak related to PbS nanoparticles. The optical analyses were massively enhanced after the composite formation with more broadening in the Vis region at 630 nm, in which there was more enhancement in the bandgap that reached 1.5 eV. The electrode application in the H2 generation process was carried out from wastewater (sewage water, third treatment) without any additional sacrificing agent. The electrode responded well to light, where the current density ( J ph ) changed from 10-6 to 0.13 mA.cm-2 under dark and light, respectively. The electrode had high reproducibility and stability. The numbers of generated H2 moles were 0.1 mmol/cm2.h. The produced Δ H ∗ and Δ S ∗ were 7.3 kJ/mol and 273.4 J/mol.K, respectively. Finally, the mechanism explains the H2 generation reaction using three-electrode cell.
This study is very promising for providing a renewable enrgy (H2 gas fuel) under the elctrochemical splitting of the wastwater (sewage water). This study has double benefits: hydrogen generation and contaminations removel. This study is carried out on sewage water, third stage treated, from Beni-Suef city, Egypt. Antimony tin oxide (ATO)/polyaniline (PANI)/PbI2 photoelectrode is prepared through the in situ oxidative polymerization of PANI on ATO, then PANI is used as an assistant for PbI2 deposition using the ionic adsorption deposition method. The chemical structural, morphological, electrical, and optical properties of the composite are confirmed using different analytical tools such as X-ray diffreaction (XRD), scanning electron microscope (SEM), transmision electron microscope (TEM), Fourier-transform infrared spectroscopy (FTIR), and UV-Vis spectroscopy. The prepared PbI2 inside the composite has a crystal size of 33 nm (according to the peak at 12.8°) through the XRD analyses device. SEM and TEM confirm the hexagonal PbI2 sheets embedded on the PANI nanopores surface. Moreover, the bandgap values are enhanced very much after the composite formation, in which the bandgap values for PANI and PANI/PbI2 are 3 and 2.51 eV, respectively. The application of ATO/PANI/PbI2 nanocomposite electrode for sewage splitting and H2 generation is carried out through a three-electrode cell. The measurements carreid out using the electrocehical worksattion under th Xenon lamp (100 mW.cm−2). The produced current density (Jph) is 0.095 mA.cm−2 at 100 mW.cm−2 light illumination. The photoelectrode has high reproducibility and stability, in which and the number of H2 moles is 6 µmole.h−1.cm−1. The photoelectrode response to different monochromatic light, in which the produced Jph decreases from 0.077 to 0.072 mA.cm−2 with decreasing of the wavelengths from 390 to 636 nm, respectively. These values confirms the high response of the ATO/PANI/PbI2 nanocomposite electrode for the light illuminaton and hydrogen genration under broad light region. The thermodynamic parameters: activation energy (Ea), enthalpy (ΔH*), and entropy (ΔS*) values are 7.33 kJ/mol, −4.7 kJ/mol, and 203.3 J/mol.K, respectively. The small values of ΔS* relted to the high sesnivity of the prepared elctrode for the water splitting and then the hydrogen gneration. Finally, a theoretical study was mentioned for calculation geometry, electrochemical, and thermochemistry properties of the polyaniline/PbI2 nanocomposite as compared with that for the polyaniline.
Polyaniline (PANI) and PANI/Ag2O/Ag composites I and II were prepared under different AgNO3 oxidant concentrations using the oxidative photopolymerization method. The chemical structure and optical, electrical, and morphological properties were determined for the prepared nanocomposite. The PANI/Ag2O/Ag composite II has the optimum optical properties, in which the bandgaps of PANI, composite I, and composite II are 3.02, 1.71, and 1.68 eV, respectively, with the morphology of a bunch of grape-like shapes with average particles sizes of 25 nm. Under the optimum optical properties, glass/PANI/Ag2O/Ag composite II electrode is used for hydrogen generation from sewage water. The measurements are carried out from a three-electrode cell under a xenon lamp. The effects of light wavelengths and temperature on the produced current density ( J ph ) are mentioned. Under the applied voltage (at 30°C), the current density values ( J ph ) increase from 0.003 to 0.012 mA.cm-2 in dark and light, respectively. While increasing the temperature, J ph values increase to 0.032 mAcm-2 at 60°C. The thermodynamic parameters are calculated, in which the activation energy ( E a ), enthalpy ( Δ H ∗ ), and entropy ( Δ S ∗ ) values are 27.1 kJ·mol-1, 24.5 J mol-1, and 140.5 J K-1 mol-1, respectively. Finally, a simple mechanism for the produced hydrogen generation rate is mentioned. The prepared electrode is a very cheap (1$ for 12 ∗ 12 c m 2 ) electrode.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
hi@scite.ai
10624 S. Eastern Ave., Ste. A-614
Henderson, NV 89052, USA
Copyright © 2024 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.