This paper examines the development of starch‐based plastics for use as biodegradable mulch film. A variety of starch‐based polymers are blended with high performance biodegradable polyester polymers in order to determine the applicability of films to be processed on a film blowing line and to perform well in mulch film field trials. The process of material formulation, film blowing processing and scale‐up and performance properties are highlighted for a successful material. Insights into future developments of starch‐derived biodegradable polymers are given.
The surfaces of continuously cast steel blooms exhibit a variety of surface features and defects, which were investigated to reveal the interactions at the meniscus between the steel shell and interfacial flux layers that caused them. One such defect formed at periodic intervals along the surface of first and second blooms in a sequence. It was characterised by gradually deepening oscillation marks, followed immediately by longitudinal striations or 'glaciation marks'. In severe cases, deep depressions were clearly visible within the glaciated region. These defects were investigated through plant trials and both physical and mathematical modelling. The defects were found to exhibit a characteristic temperature history: temperature troughs that move down the mould at the casting speed. These defects may be monitored in much the same way as sticker breakouts, thereby allowing existing thermocouple based breakout detection systems to be modified to include a quality alarm. This study attributes these defects to high amplitude, low frequency, mould level fluctuations. A mechanism is proposed which ascribes the generation of these defects to the interaction of the meniscus with the slag rim at peaks in the mould level cycle. Installing an improved mould level control system eliminated the defects.
Fluid shear and other mechanical forces play an important role in the normal biophysical, biochemical, and gene regulatory responses of vertebrate tissue that are reflected in the expression of normal cell differentiation, growth, and function. Despite some promising work reported on the application of the quartz crystal microbalance (QCM) to both prokaryote and eukaryote cells over the last decade, QCM has yet to be successfully applied to cells in culture under conditions of flow-induced shear. In this study, high sensitivity QCM in conjunction with fluid modelling was used to monitor the onset of senescence in immortalised human embryonic kidney cells under laminar shear stresses of between 0.04 and 335 dyne/cm(2). The feasibility of this approach as a means of quantification and characterisation of cell physiological response and adhesion are explored and discussed.
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