In this work, the influence of a wide range anodizing temperature (5–30 °C) on the growth and optical properties of PAA-based distributed Bragg reflector (DBR) was studied. It was demonstrated that above 10 °C both structural and photonic properties of the DBRs strongly deteriorates: the photonic stop bands (PSBs) decay, broaden, and split, which is accompanied by the red shift of the PSBs. However, at 30 °C, new bands in transmission spectra appear including one strong and symmetric peak in the mid-infrared (MIR) spectral region. The PSB in the MIR region is further improved by a small modification of the pulse sequence which smoothen and sharpen the interfaces between consecutive low and high refractive index layers. This is a first report on PAA-based DBR with a good quality PSB in MIR. Moreover, it was shown that in designing good quality DBRs a steady current recovery after subsequent application of high potential (UH) pulses is more important than large contrast between low and high potential pulses (UH-UL contrast). Smaller UH-UL contrast helps to better control the current evolution during pulse anodization. Furthermore, the lower PSB intensity owing to the smaller UH-UL contrast can be partially compensated by the higher anodizing temperature.
This study shows the results of air monitoring in high- and low-occupancy rooms using two combinations of sensors, AeroTrak8220(TSI)/OPC-N3 (AlphaSense, Great Notley, UK) and OPC-N3/PMS5003 (Plantower, Beijing, China), respectively. The tests were conducted in a flat in Warsaw during the restrictions imposed due to the COVID-19 lockdown. The results showed that OPC-N3 underestimates the PN (particle number concentration) by about 2–3 times compared to the AeroTrak8220. Subsequently, the OPC-N3 was compared with another low-cost sensor, the PMS5003. Both devices showed similar efficiency in PN estimation, whereas PM (particulate matter) concentration estimation differed significantly. Moreover, the relationship among the PM1–PM2.5–PM10 readings obtained with the PMS5003 appeared improbably linear regarding the natural indoor conditions. The correlation of PM concentrations obtained with the PMS5003 suggests an oversimplified calculation method of PM. The studies also demonstrated that PM1, PM2.5, and PM10 concentrations in the high- to low-occupancy rooms were about 3, 2, and 1.5 times, respectively. On the other hand, the use of an air purifier considerably reduced the PM concentrations to similar levels in both rooms. All the sensors showed that frying and toast-making were the major sources of particulate matter, about 10 times higher compared to average levels. Considerably lower particle levels were measured in the low-occupancy room.
In this work, the influence of various electrochemical parameters on the production of porous anodic alumina (PAA)-based DBRs (distributed Bragg reflector) during high-temperature-pulse-anodization was studied. It was observed that lowering the temperature from 30 to 27 °C brings about radical changes in the optical performance of the DBRs. The multilayered PAA fabricated at 27 °C did not show optical characteristics typical for DBR. The DBR performance was further tuned at 30 °C. The current recovery (iamax) after application of subsequent UH pulses started to stabilize upon decreasing high (UH) and low (UL) voltage pulses, which was reflected in a smaller difference between initial and final thickness of alternating dH and dL segments (formed under UH and UL, respectively) and a better DBR performance. Shortening UH pulse duration resulted in a progressive shift of photonic stopbands (PSBs) towards the blue part of the spectrum while keeping intensive and symmetric PSBs in the NIR-MIR range. Despite the obvious improvement of the DBR performance by modulation of electrochemical parameters, the problem regarding full control over the homogeneous formation of dH+dL pairs remains. Solving this problem will certainly lead to the production of affordable and efficient PAA-based photonic crystals with tunable photonic properties in the NIR-MIR region.
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